Shell Turbo Oil T 46Safety Data Sheet Shell Turbo Oil T 46 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING Product Code Infosafe No. Issued Date Product Type/Use 001A9783 ACH3Q AU/eng/C 30/06/2005 Turbine oil. Other Names Name Shell Turbo Oil T 46 Supplier Code 140000001969 Telephone Numbers Emergency Tel. 1800 651 818 Telephone/Fax Number Tel: 03 9666 5444 Fax: 03 8823 4800 Shell Company of Australia Ltd. Level 2, 8 Redfern Road, Hawthorn East, Victoria 3123 (ABN 46 004 610 459) AUSTRALIA 2. COMPOSITION/INFORMATION ON INGREDIENTS Preparation Description Highly refined mineral oils and additives. The highly refined mineral oil contains <3% (w/w) DMSO-extract, according to IP346. Name Nphenyl1-naphthylamine CAS EINECS Proportion Hazard R Phrase 90-30-2 201-983-0 0.1-0.24 % Xi, N R43, R50/53 Other Information See Section 16 'Other Information' for full text of each relevant Risk Phrase. 3. HAZARDS IDENTIFICATION Hazards Identification NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. Hazard classification according to the criteria of NOHSC. Dangerous goods classification according to the Australia Dangerous Goods Code. Human Health Hazards No specific hazards under normal use conditions. Prolonged or repeated exposure may give rise to dermatitis. Used oil may contain harmful impurities. Version No. 1.1 30/06/2005 Page 1 of 7 1. Eye Flush eye with copious quantities of water. injection of product under the skin can occur. Neoprene or nitrile rubber gloves. Unsuitable Extinguishing Media Water in jet. High pressure injection injuries require prompt surgical intervention and possibly steroid therapy. Carbon dioxide. Wash out mouth with water and obtain medical attention. Use of halon extinguishers should be avoided for environmental reasons. earth.Shell Turbo Oil T 46 Safety Hazards Not classified as flammable.1 30/06/2005 Page 2 of 7 . obtain medical attention. or other appropriate barriers. Inhalation Remove to fresh air. the casualty should be sent immediately to a hospital. May cause an allergic skin reaction in sensitive individuals. Environmental Hazards Not classified as dangerous to the environment. 6. ditches or rivers by using sand. Do not wait for symptoms to develop. Wear safety glasses or full face shield if splashes are likely to occur. Wear rubber knee length safety boots and PVC Jacket and Trousers. Inform local authorities if this cannot be prevented. If persistent irritation occurs. Advice to Doctor Treat symptomatically. If rapid recovery does not occur. 5. obtain medical attention. Skin Remove contaminated clothing and wash affected skin with soap and water. Protective Equipment Proper protective equipment including breathing apparatus must be worn when approaching a fire in a confined space. to minimise tissue damage and loss of function. Extinguishing Media Foam and dry chemical powder. 4. Dermatitis may result from prolonged or repeated exposure. Wear PVC. If high pressure injuries occur. When using high pressure equipment. including carbon monoxide and unidentified organic and inorganic compounds. Ingestion Do not induce vomiting. If persistent irritation occurs. ACCIDENTAL RELEASE MEASURES Personal Precautions Avoid contact with skin and eyes. Version No. obtain medical attention. sand or earth may be used for small fires only. but will burn. Environmental Precautions Prevent from spreading or entering into drains. Aspiration into the lungs may result in chemical pneumonitis. FIRE FIGHTING MEASURES Specific Hazards Combustion is likely to give rise to a complex mixture of airborne solid and liquid particulates and gases. FIRST AID MEASURES Symptoms and Effects Not expected to give rise to an acute hazard under normal conditions of use. clearly marked container for disposal in accordance with local regulations. Reclaim liquid directly or in an absorbent. well-ventilated place. mists or aerosols. paper and other materials that are used to absorb spills present a fire hazard. Unsuitable Materials For containers or container linings. Storage Temperatures 0ºC Minimum. a respirator fitted with an organic vapour cartridge combined with a particulate pre-filter should be used. Hand Protection PVC or nitrile rubber gloves. Use properly labelled and closeable containers. Dispose of as for small spills. avoid PVC. If oil mist cannot be controlled. Cloth. 8. use mild steel or high density polyethylene. HANDLING AND STORAGE Handling Use local exhaust ventilation if there is risk of inhalation of vapours.1 30/06/2005 Page 3 of 7 . EXPOSURE CONTROLS. Avoid their accumulation by disposing of them safely and immediately. safety footwear should be worn and proper handling equipment should be used. mists or aerosols. When handling product in drums. earth or other containment material.3rd Edition Exposure Controls Use local exhaust ventilation if there is a risk of inhalation of vapours. Version No. 7. Eye Protection Wear safety glasses or full face shield if splashes are likely to occur.Shell Turbo Oil T 46 Clean-up Methods . Respiratory Protection Not normally required. 50ºC Maximum. In addition to any specific recommendations given for controls of risks to health. 1. mineral NOHSC:1003 NOHSC:1003 NOHSC:1003 Exposure Duration TWA STEL Exposure Limit Units 5 10 mg/m3 mg/m3 Notes Adopted National Exposure Standards for Atmospheric Contaminants in the Occupational Environment [NOHSC:1003(1995)] . Clean-up Methods . Sweep up and remove to a suitable. heat sources. an assessment of risks must be made to help determine controls appropriate to local circumstances. eyes and clothing . Avoid breathing vapour. Other Information Polyethylene containers should not be exposed to high temperatures because of possible risk of distortion. dry. Prevent spillages. spray or mists. Storage Keep in a cool.Small Spillages Absorb liquid with sand or earth. safety and the environment. Avoid prolonged or repeated contact with skin. Recommended Materials For containers or container linings.Large Spillages Prevent from spreading by making a barrier with sand. PERSONAL PROTECTION Exposure Limits Substance Regulations Oil mist. Avoid direct sunlight. and strong oxidizing agents. 9. Launder overalls and undergarments regularly. Information given is based on a knowledge of the components and the toxicology of similar products. Hazardous Decomposition Products Hazardous decomposition products are not expected to form during normal storage. Version No. Liquid at ambient temperature. -12ºC.Oral LD50 expected to be > 2000 mg/kg.5 Pa at 20°C. Environmental Exposure Controls Minimise release to the environment. 1. 1%(V/V). 46 mm2/s at 40°C. Negligible. Expected to be above 320ºC.1 30/06/2005 Page 4 of 7 . Data not available. Acute Toxicity . 11. Log Pow expected to be greater than 6. Greater than 1.Lower Auto-Ignition Temperature Kinematic Viscosity Evaporation Rate Vapour Density (Air=1) Partition co-efficient. Materials to Avoid Strong oxidizing agents. Overalls and shoes with oil resistant soles should be worn.Shell Turbo Oil T 46 Body Protection Minimise all forms of skin contact. Characteristic mineral oil. TOXICOLOGICAL INFORMATION Basis for Assessment Toxicological data have not been determined specifically for this product. Data not available.Dermal LD50 expected to be > 2000 mg/kg. Expected to be above 280°C. STABILITY AND REACTIVITY Stability Stable. 220ºC (COC). Expected to be less than 0. An environmental assessment must be made to ensure compliance with local environmental legislation. 10%(V/V). Data not available. 10.Upper Flammable Limits . PHYSICAL AND CHEMICAL PROPERTIES Colour Physical State Odour pH Value Vapour Pressure Initial Boiling Point Solubility in Water Density Flash Point Flammable Limits . Conditions to Avoid Extremes of temperature and direct sunlight. n-octanol/water Pour Point Amber. Acute Toxicity . Version No. Respiratory Irritation If mists are inhaled. but the product contains components that may persist in the environment. Other Adverse Effects Not expected to have ozone depletion potential. If it enters soil. May cause physical fouling of aquatic organisms. Eye Irritation Expected to be slightly irritating. Other components are not known to be associated with carcinogenic effects. it will adsorb to soil particles and will not be mobile. Carcinogenicity Product is based on mineral oils of types shown to be non-carcinogenic in animal skin-painting studies. Used oils may contain harmful impurities that have accumulated during use. Other Information Prolonged and/or repeated contact with this product can result in defatting of the skin. Information given is based on a knowledge of the components and the ecotoxicology of similar products. Major constituents are expected to be inherently biodegradable. Reproductive Toxicity Not considered to be toxic to reproduction. LL/EL50 >100 mg/l. (LL/EL50 expressed as the nominal amount of product required to prepare aqueous test extract). The concentration of such impurities will depend on use and they may present risks to health and the environment on disposal. 12. 1. Floats on water. photochemical ozone creation potential or global warming potential. Bioaccumulation Contains components with the potential to bioaccumulate. especially under conditions of poor personal hygiene. Mutagenicity Not considered to be a mutagenic hazard. ECOLOGICAL INFORMATION Basis for Assessment Ecotoxicological data have not been determined specifically for this product. particularly at elevated temperatures. ALL used oil should be handled with caution and skin contact avoided as far as possible. Mineral oil is not expected to cause any chronic effects to aquatic organisms at concentrations less than 1 mg/l. slight irritation of the respiratory tract may occur.Shell Turbo Oil T 46 Acute Toxicity . Product is expected to be practically non-toxic to aquatic organisms. Ecotoxicity Poorly soluble mixture. This can lead to irritation and possibly dermatitis. Skin Sensitisation Not expected to be a skin sensitizer. Skin contact should be minimised. Persistence / Degradability Not expected to be readily biodegradable. Mobility Liquid under most environmental conditions. Skin Irritation Expected to be slightly irritating.Inhalation Not considered to be an inhalation hazard under normal conditions of use. High pressure injection of product into the skin may lead to local necrosis if the product is not surgically removed.1 30/06/2005 Page 5 of 7 . The competence of the contractor to deal satisfactorily with this type of product should be established beforehand. Standard Uniform Scheduling of Drugs and Poisons. National Legislation National Code of Practice for the Preparation of Material Safety Data Sheets [NOHSC:2011] List of Designated Hazardous Substances [NOHSC:10005]. 1. 14. Adopted National Exposure Standards for Atmospheric Contaminants in the Occupational Environment [NOHSC:1003]. TRANSPORT INFORMATION Transport Information Not dangerous for transport under ADG. ADG UN Class None Allocated ADG Packing Group None Allocated ADG Hazchem Code None Allocated IMDG Hazard Class None Allocated IMDG Packing Group None Allocated 15. Version No. Approved Criteria for Classifying Hazardous Substances [NOHSC:1008]. May produce an allergic reaction. All components listed or polymer exempt. by a recognised collector or contractor.Shell Turbo Oil T 46 Product is a mixture of non-volatile components. IMO and IATA/ICAO regulations. DISPOSAL CONSIDERATIONS Waste Disposal Recycle or dispose of in accordance with prevailing regulations. Product Disposal As for waste disposal. Not classified. Not classified. water or environment with the waste product. Packaging & Labelling Contains N-phenyl-1-naphthylamine. Safety data sheet available for professional user on request. REGULATORY INFORMATION EC Symbols EC Risk Phrase EC Safety Phrase EINECS None. Do not pollute the soil. AICS (Australia) All components listed. which are not expected to be released to air in any significant quantities. Australian Dangerous Goods Code.1 30/06/2005 Page 6 of 7 . Container Disposal Recycle or dispose of in accordance with the legislation in force with a recognised collector or contractor. 13. may cause long-term adverse effects in the aquatic environment. AS/NZS 1715 Selection.. OTHER INFORMATION References For detailed advice on Personal Protective equipment. R50/53 Very toxic to aquatic organisms. refer to the following Australian Standards :HB 9 (Handbook 9) Manual of industrial personal protection. Technical Contact Numbers (03) 9666 5444.Shell Turbo Oil T 46 16.. use and maintenance of respiratory protective devices.. 1. Poisons Schedule NS.1 30/06/2005 Page 7 of 7 . . Further Information This information is based on our current knowledge and is intended to describe the product for the purposes of health. List of R Phrases in Section 2 R43 May cause sensitization by skin contact. AS/NZS 1337 Eye protectors for industrial applications. Restrictions This product must not be used in applications other than recommended without first seeking the advice of the SHELL technical department.. It does not constitute a guarantee for any specific property of the product. End Of SDS . safety and environmental requirements only. Version No. AS/NZS 1716 Respiratory protective devices.