Material Safety Data SheetShell Malleus Grease GL 95 MSDS# 67560E Version 5.0 Effective Date 09/08/2008 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 1. MATERIAL AND COMPANY IDENTIFICATION Material Name Uses : : Shell Malleus Grease GL 95 Automotive and industrial grease. Manufacturer/Supplier : MSDS Request : SOPUS Products PO Box 4427 Houston, TX 77210-4427 USA 877-276-7285 Emergency Telephone Number : 877-242-7400 Spill Information : 877-504-9351 Health Information 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Identity Molybdenum disulphide Carbon black Graphite CAS No. 1317-33-5 1333-86-4 7782-42-5 Concentration 5.00 - 10.00 % 5.00 - 10.00 % 5.00 - 10.00 % Highly refined mineral oil. The highly refined mineral oil contains <3% (w/w) DMSO-extract, according to IP346. 3. HAZARDS IDENTIFICATION Emergency Overview Black. Viscous liquid. Slight hydrocarbon. High-pressure injection under the skin may cause serious damage including local necrosis. Not classified as flammable but will burn. Not classified as dangerous for the environment. Appearance and Odour Health Hazards Safety Hazards Environmental Hazards Health Hazards Health Hazards Inhalation Skin Contact : : : : : Not expected to be a health hazard when used under normal conditions. : Under normal conditions of use, this is not expected to be a primary route of exposure. : Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. : May cause slight irritation to eyes. : Low toxicity if swallowed. : High-pressure injection under the skin may cause serious damage including local necrosis. Used grease may contain harmful impurities. : Local necrosis is evidenced by delayed onset of pain and tissue 1/9 Eye Contact Ingestion Other Information Signs and Symptoms Print Date 09/09/2008 MSDS_US : Under normal conditions of use or in a foreseeable emergency. FIRE FIGHTING MEASURES Clear fire area of all non-emergency personnel.1200. obtain medical attention. If persistent irritation occurs. Flush exposed area with water and follow by washing with soap if available. Flush eye with copious quantities of water. FIRST AID MEASURES General Information Inhalation Skin Contact : : : Not expected to be a health hazard when used under normal conditions. No treatment necessary under normal conditions of use. however. to minimise tissue damage and loss of function. In general no treatment is necessary unless large quantities are swallowed. 29 CFR 1910. If persistent irritation occurs. the casualty should be sent immediately to a hospital.Material Safety Data Sheet Shell Malleus Grease GL 95 MSDS# 67560E Version 5. 4. injection of product under the skin can occur. get medical advice. Oil acne/folliculitis signs and symptoms may include formation of black pustules and spots on the skin of exposed areas. Remove contaminated clothing. obtain medical advice. obtain medical attention. debridement and evacuation of foreign material should be performed under general anaesthetics. If symptoms persist. If high pressure injuries occur. : Pre-existing medical conditions of the following organ(s) or organ system(s) may be aggravated by exposure to this material: Skin. Because entry wounds are small and do not reflect the seriousness of the underlying damage. Obtain medical attention even in the absence of apparent wounds. vasospasm and ischaemia. Prompt surgical decompression. Do not wait for symptoms to develop. 29 CFR 1910. Treat symptomatically. Local anaesthetics or hot soaks should be avoided because they can contribute to swelling. High pressure injection injuries require prompt surgical intervention and possibly steroid therapy. When using high pressure equipment. this product does not meet the definition of a hazardous chemical when evaluated according to the OSHA Hazard Communication Standard. Eye Contact Ingestion Advice to Physician : : : 5. Ingestion may result in nausea. vomiting and/or diarrhoea. : Not classified as dangerous for the environment.0 Effective Date 09/08/2008 According to OSHA Hazard Communication Standard. surgical exploration to determine the extent of involvement may be necessary.10 %(V)(based on mineral oil) : > 320 °C / 608 °F 2/9 Print Date 09/09/2008 MSDS_US .1200 Aggravated Medical Condition Environmental Hazards Additional Information damage a few hours following injection. Flash point Upper / lower Flammability or Explosion limits Auto ignition temperature : : > 180 °C / 356 °F (COC) Typical 1 . and wide exploration is essential. Keep container tightly closed and in a cool. well-ventilated place. Handling : Storage : Recommended Materials Unsuitable Materials Additional Information : : : 8. sand or earth may be used for small fires only. Clean Up Methods : 7.50 °C / 32 . Avoid inhaling vapour and/or mists. storage and disposal of this material. Properly dispose of any contaminated rags or cleaning materials in order to prevent fires. Storage Temperature: 0 . When handling product in drums. Dry chemical powder. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Material Source Type ppm 3/9 Print Date 09/09/2008 MSDS_US mg/m3 Notation .1200 Specific Hazards : Suitable Extinguishing Media Unsuitable Extinguishing Media Protective Equipment for Firefighters : : : Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Polyethylene containers should not be exposed to high temperatures because of possible risk of distortion.Material Safety Data Sheet Shell Malleus Grease GL 95 MSDS# 67560E Version 5. For guidance on selection of personal protective equipment see Chapter 8 of this Material Safety Data Sheet. 29 CFR 1910.122 °F For containers or container linings. mists or aerosols. or other appropriate barriers. Use appropriate containment to avoid environmental contamination. Protective measures : Avoid contact with skin and eyes. Prevent from spreading or entering drains. use mild steel or high density polyethylene. See Chapter 13 for information on disposal. Avoid prolonged or repeated contact with skin. carbon dioxide. Shovel into a suitable clearly marked container for disposal or reclamation in accordance with local regulations. earth. Observe all relevant local and international regulations. Carbon monoxide. water spray or fog. safety footwear should be worn and proper handling equipment should be used. Use the information in this data sheet as input to a risk assessment of local circumstances to help determine appropriate controls for safe handling. ditches or rivers by using sand. Unidentified organic and inorganic compounds. HANDLING AND STORAGE General Precautions : Use local exhaust ventilation if there is risk of inhalation of vapours. Do not use water in a jet. Proper protective equipment including breathing apparatus must be worn when approaching a fire in a confined space.0 Effective Date 09/08/2008 According to OSHA Hazard Communication Standard. Use properly labelled and closeable containers. ACCIDENTAL RELEASE MEASURES Avoid contact with spilled or released material. Foam. 6. PVC. 5 mg/m3 3. Where material is heated.Material Safety Data Sheet Shell Malleus Grease GL 95 MSDS# 67560E Version 5. mineral Oil mist.) 10 mg/m3 as Mo ACGIH 3 mg/m3 as Mo OSHA Z1 15 mg/m3 as Mo OSHA Z1A 10 mg/m3 as Mo ACGIH OSHA Z1 OSHA Z1A ACGIH OSHA Z1A OSHA Z1 OSHA Z1 3.) 5 mg/m3 10 mg/m3 ACGIH TWA(Respira ble fraction.5 mg/m3 as Mo OSHA Z1 5 mg/m3 as Mo OSHA Z1A TWA 5 mg/m3 as Mo ACGIH TWA(Inhalabl e fraction.5 mg/m3 3. generation of mists and dusts is unlikely to occur. Select controls based on a risk assessment of local circumstances.) PEL 0.) PEL(Total dust.5 mg/m3 5 mg/m3 15 mg/m3 Additional Information : Due to the product's semi-solid consistency. sprayed or mist formed.1200 Oil mist.) TWA(Respira ble dust.) TWA(Total dust.) TWA PEL TWA TWA(Respira ble fraction.) STEL(Mist. 29 CFR 1910.) PEL(Total dust. mineral Molybdenu m disulphide Molybdenu m disulphide Molybdenu m disulphide Molybdenu m disulphide Molybdenu m disulphide Molybdenu m disulphide Molybdenu m disulphide Carbon black Carbon black Carbon black Graphite Graphite Graphite Graphite ACGIH ACGIH TWA(Mist.0 Effective Date 09/08/2008 According to OSHA Hazard Communication Standard. Exposure Controls : The level of protection and types of controls necessary will vary depending upon potential exposure conditions.) PEL(Respira ble fraction.5 mg/m3 2 mg/m3 2. there is greater potential for airborne 4/9 Print Date 09/09/2008 MSDS_US . Appropriate measures include: Adequate ventilation to control airborne concentrations.) TWA(Respira ble fraction. After using gloves. PHYSICAL AND CHEMICAL PROPERTIES Appearance Odour pH Initial Boiling Point and Boiling Range Dropping point Flash point Upper / lower Flammability or Explosion limits Auto-ignition temperature : : : : Black.0 Effective Date 09/08/2008 According to OSHA Hazard Communication Standard. An environmental assessment must be made to ensure compliance with local environmental legislation. Contaminated gloves should be replaced. Wear safety glasses or full face shield if splashes are likely to occur. Monitoring of the concentration of substances in the breathing zone of workers or in the general workplace may be required to confirm compliance with an OEL and adequacy of exposure controls. Select a filter suitable for combined particulate/organic gases and vapours [boiling point >65 °C (149 °F)]. Check with respiratory protective equipment suppliers. glove thickness. 29 CFR 1910. Skin protection not ordinarily required beyond standard issue work clothes. hands should be washed and dried thoroughly. Gloves must only be worn on clean hands. Not applicable.g. Minimise release to the environment. Personal hygiene is a key element of effective hand care. neoprene or nitrile rubber gloves. e. select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation.10 %(V) (based on mineral oil) : > 320 °C / 608 °F 5/9 Print Date 09/09/2008 MSDS_US . Viscous liquid. Check with PPE suppliers. No respiratory protection is ordinarily required under normal conditions of use. Always seek advice from glove suppliers. chemical resistance of glove material. Personal protective equipment (PPE) should meet recommended national standards. In accordance with good industrial hygiene practices. If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health. 9.g. Where hand contact with the product may occur the use of gloves approved to relevant standards (e. Slight hydrocarbon. select an appropriate combination of mask and filter. dexterity. Application of a non-perfumed moisturizer is recommended. Suitability and durability of a glove is dependent on usage.Material Safety Data Sheet Shell Malleus Grease GL 95 MSDS# 67560E Version 5. US: F739) made from the following materials may provide suitable chemical protection: PVC.1200 Personal Protective Equipment Respiratory Protection : : Hand Protection : Eye Protection Protective Clothing Monitoring Methods : : : Environmental Exposure Controls : concentrations to be generated. frequency and duration of contact. precautions should be taken to avoid breathing of material. Where air-filtering respirators are suitable. For some substances biological monitoring may also be appropriate. Data not available : Data not available : > 180 °C / 356 °F (COC) : Typical 1 . Europe: EN374. TOXICOLOGICAL INFORMATION Basis for Assessment Acute Oral Toxicity Acute Dermal Toxicity Acute Inhalation Toxicity Skin Irritation : : : : : Information given is based on data on the components and the toxicology of similar products.Material Safety Data Sheet Shell Malleus Grease GL 95 MSDS# 67560E Version 5. Strong oxidising agents. IARC 2B: Possible carcinogen. Extremes of temperature and direct sunlight. Carcinogenicity Classification ACGIH Group A3: Confirmed animal carcinogen with unknown relevance to humans.076 kg/m3 at 15 °C / 59 °F Negligible. : > 1 (estimated value(s)) : Data not available 10. Inhalation of vapours or mists may cause irritation. STABILITY AND REACTIVITY Stability Conditions to Avoid Materials to Avoid Hazardous Decomposition Products : : : : Stable. Rat Expected to be of low toxicity: LD50 > 5000 mg/kg . Product contains mineral oils of types shown to be noncarcinogenic in animal skin-painting studies. Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. > 6 (based on information on similar products) : Not applicable. The concentration of such harmful impurities will depend on use and they may present risks to health and the environment on disposal. 11. ALL used grease 6/9 Print Date 09/09/2008 MSDS_US Eye Irritation Respiratory Irritation Sensitisation Repeated Dose Toxicity Mutagenicity Carcinogenicity : : : : : : Material Molybdenum disulphide Carbon black Carbon black Reproductive and Developmental Toxicity Additional Information : : : : : : . Expected to be of low toxicity: LD50 > 5000 mg/kg . Expected to be slightly irritating.1200 Vapour pressure Density Water solubility n-octanol/water partition coefficient (log Pow) Kinematic viscosity Vapour density (air=1) Evaporation rate (nBuAc=1) : : : : < 0. Not considered a mutagenic hazard. Not expected to be a hazard. Rabbit Not considered to be an inhalation hazard under normal conditions of use. Expected to be slightly irritating. Hazardous decomposition products are not expected to form during normal storage. Highly refined mineral oils are not classified as carcinogenic by the International Agency for Research on Cancer (IARC). 29 CFR 1910. Not expected to be a skin sensitiser. Not expected to be a hazard.0 Effective Date 09/08/2008 According to OSHA Hazard Communication Standard.5 Pa at 20 °C / 68 °F (estimated value(s)) Typical 1. Other components are not known to be associated with carcinogenic effects. ACGIH Group A4: Not classifiable as a human carcinogen. Used grease may contain harmful impurities that have accumulated during use. and local laws and regulations. Major constituents are expected to be inherently biodegradable. photochemical ozone creation potential or global warming potential. 29 CFR 1910. Do not dispose into the environment. preferably to a recognised collector or contractor. 12. Mineral oil is not expected to cause any chronic effects to aquatic organisms at concentrations less than 1 mg/l. which are not expected to be released to air in any significant quantities. Floats on water. IMDG 7/9 Print Date 09/09/2008 MSDS_US . May cause physical fouling of aquatic organisms. The competence of the collector or contractor should be established beforehand. it will adsorb to soil particles and will not be mobile. Disposal should be in accordance with applicable regional. Dispose in accordance with prevailing regulations.0 Effective Date 09/08/2008 According to OSHA Hazard Communication Standard.1200 should be handled with caution and skin contact avoided as far as possible. Information given is based on a knowledge of the components and the ecotoxicology of similar products. High pressure injection of product into the skin may lead to local necrosis if the product is not surgically removed. Acute Toxicity : Poorly soluble mixture. Product is a mixture of non-volatile components. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste classification and disposal methods in compliance with applicable regulations. Mobility : Persistence/degradability : Bioaccumulation Other Adverse Effects : : 13.Material Safety Data Sheet Shell Malleus Grease GL 95 MSDS# 67560E Version 5. Expected to be practically non toxic: LL/EL/IL50 > 100 mg/l (to aquatic organisms) (LL/EL50 expressed as the nominal amount of product required to prepare aqueous test extract). DISPOSAL CONSIDERATIONS Material Disposal : Recover or recycle if possible. Container Disposal : Local Legislation : 14. in drains or in water courses. national. Not expected to have ozone depletion potential. ECOLOGICAL INFORMATION Ecotoxicological data have not been determined specifically for this product. If it enters soil. Semi-solid under most environmental conditions. Contains components with the potential to bioaccumulate. but the product contains components that may persist in the environment. Expected to be not readily biodegradable. TRANSPORT INFORMATION US Department of Transportation Classification (49CFR) This material is not subject to DOT regulations under 49 CFR Parts 171-180. State Regulatory Status California Safe Drinking Water and Toxic Enforcement Act (Proposition 65) This product contains a chemical known to the State of California to cause cancer. SARA Hazard Categories (311/312) No SARA 311/312 Hazards. 16. Listed. All components listed.0 Effective Date 09/08/2008 According to OSHA Hazard Communication Standard. Federal Regulatory Status Notification Status EINECS TSCA DSL All components listed or polymer exempt. New Jersey Right-To-Know Chemical List Molybdenum disulphide (1317-33-5) Carbon black (1333-86-4) Listed. REGULATORY INFORMATION The regulatory information is not intended to be comprehensive.0 09/08/2008 8/9 Print Date 09/09/2008 MSDS_US . Fire. IATA (Country variations may apply) This material is not classified as dangerous under IATA regulations. OTHER INFORMATION NFPA Rating (Health. Listed. 29 CFR 1910. 0 5.Material Safety Data Sheet Shell Malleus Grease GL 95 MSDS# 67560E Version 5. Reactivity) MSDS Version Number MSDS Effective Date : : : 0. 1. 15. Other regulations may apply to this material. Pennsylvannia Right-To-Know Chemical List Carbon black (1333-86-4) Graphite (7782-42-5) Listed. All components listed.1200 This material is not classified as dangerous under IMDG regulations. 1200 MSDS Revisions MSDS Regulation MSDS Distribution : : : A vertical bar (|) in the left margin indicates an amendment from the previous version.0 Effective Date 09/08/2008 According to OSHA Hazard Communication Standard. 29 CFR 1910. The content and format of this MSDS is in accordance with the OSHA Hazard Communication Standard. 29 CFR 1910. No warranty or guarantee is expressed or implied regarding the accuracy of these data or the results to be obtained from the use of the product.Material Safety Data Sheet Shell Malleus Grease GL 95 MSDS# 67560E Version 5.1200. The information in this document should be made available to all who may handle the product. safety and environmental requirements only. The information contained herein is based on our current knowledge of the underlying data and is intended to describe the product for the purpose of health. Disclaimer : 9/9 Print Date 09/09/2008 MSDS_US .