REVISION DATE: 06.08.2010 1/ 5 SAFETY DATA SHEET HTH Tablets 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING PRODUCT NAME CAS-No. EU INDEX NO. EC No. SUPPLIER HTH Tablets 7778-54-3 017-012-00-7 231-908-7 Univar Aquarius House 6 Midpoint Business Park Thornbury Bradford BD3 7AY +44 1274 267300 +44 1274 267306 [email protected] KA425P, KA4253 Calcium Hypochlorite briquettes, Easiflo, HTH Easiflo BRIQUETTE, HTH Calcium hypochlorite tablets Water Treatment, +44 1274 267346 +441865 407333 11828 PRODUCT NO. SYNONYMS, TRADE NAMES APPLICATION Emergency Contact Number (Office Hours) Emergency Contact Number (Outside Office Hours) SDS No. 2 HAZARDS IDENTIFICATION Contact with combustible material may cause fire. Harmful if swallowed. Causes burns. Very toxic to aquatic organisms. Contact with acids liberates toxic gas. CLASSIFICATION (1999/45) Xn;R22. C;R34. O;R8. N;R50. R31. 3 COMPOSITION/INFORMATION ON INGREDIENTS Name EC No. CAS-No. Content Classification (67/548) CALCIUM CHLORIDE Calcium Hydroxide CALCIUM HYPOCHLORITE 233-140-8 215-137-3 231-908-7 10043-52-4 1305-62-0 7778-54-3 1-5% 1-5% 50-100% Xi;R36 Xi;R38,R41. O;R8 C;R34 Xn;R22 R31 N;R50 The Full Text for all R-Phrases are Displayed in Section 16 EU INDEX NO. EC No. CAS-No. 017-012-00-7 231-908-7 7778-54-3 4 FIRST-AID MEASURES INHALATION Move into fresh air and keep at rest. Get medical attention. Get medical attention if any discomfort continues. 7 HANDLING AND STORAGE USAGE PRECAUTIONS Read and follow manufacturer's recommendations. SKIN CONTACT Remove contaminated clothing immediately and wash skin with soap and water.REVISION DATE: 06. Collect spillage in containers. Flush contaminated area with plenty of water.2010 INGESTION 2/ 5 HTH Tablets Provide rest. STORAGE PRECAUTIONS Keep containers tightly closed. Immediately rinse mouth and drink plenty of water (200-300 ml). STORAGE CLASS Oxidiser storage. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION PROTECTIVE EQUIPMENT ENGINEERING MEASURES Provide adequate ventilation. UNUSUAL FIRE & EXPLOSION HAZARDS 558 Strongly oxidising (fire-intensifying) substance. SPILL CLEAN UP METHODS Collect powder using special dust vacuum cleaner with particle filter or carefully sweep into closed container. Avoid spilling. 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS Follow precautions for safe handling described in this safety data sheet. Provide adequate ventilation. Continue to rinse. Get medical attention. Observe occupational exposure limits and minimize the risk of inhalation of dust. Keep in original container. ENVIRONMENTAL PRECAUTIONS Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the Environmental Agency or other appropriate regulatory body. seal securely and deliver for disposal according to local regulations. SPECIFIC HAZARDS Chlorine. skin and eye contact. Do not induce vomiting. Plastic lined steel drum. PROTECTIVE MEASURES IN FIRE Self contained breathing apparatus and full protective clothing must be worn in case of fire. Provide good ventilation. suitable respiratory protection must be provided. EYE CONTACT Immediately flush with plenty of water for up to 15 minutes. Dust filter P2 (for fine dust). RESPIRATORY EQUIPMENT If ventilation is insufficient. Store in closed original container at temperatures between 0°C and 30°C. warmth and fresh air. corrosive. . Suitable containers: polyethylene. 5 FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA Water. Avoid contact with skin and eyes.08. Get medical attention immediately. Hydrogen chloride (HCl). Remove any contact lenses and open eyes wide apart. CONDITIONS TO AVOID Avoid heat.180 pH-VALUE. 11 TOXICOLOGICAL INFORMATION TOXIC DOSE 1 . Wear rubber footwear. MEDICAL SYMPTOMS Pulmonary oedema. Avoid excessive heat for prolonged periods of time. who can inform about the breakthrough time of the glove material. frothy sputum. Neoprene. EYE PROTECTION Goggles/face shield are recommended. Acids. LC 50. SKIN CONTACT Irritating to skin. . HEALTH WARNINGS Severe pulmonary irritant. FISH mg/l 0. drink or smoke. The most suitable glove must be chosen in consultation with the gloves supplier.REVISION DATE: 06. Causes burns.08. Strong oxidising substances. May spread in the aquatic environment. Strong alkalis. 12 ECOLOGICAL INFORMATION ECOTOXICITY The product contains a substance which is very toxic to aquatic organisms. Polyvinyl chloride (PVC).LD 50 INHALATION 850 mg/kg (oral rat) Vapours may irritate throat and respiratory system and cause coughing. 96 Hrs. MATERIALS TO AVOID Flammable/combustible material. smoking and using the toilet. oesophagus and stomach.2010 HAND PROTECTION 3/ 5 HTH Tablets Use protective gloves.3 20 170 . When using do not eat.11.5 . HAZARDOUS DECOMPOSITION PRODUCTS Chlorine. DILUTED SOLUTION 10. Causes burns. INGESTION Harmful if swallowed. EYE CONTACT May cause severe irritation to eyes. HYGIENE MEASURES Wash at the end of each work shift and before eating.0 @ 1% 10 STABILITY AND REACTIVITY STABILITY Stable under normal temperature conditions and recommended use. 1. flames and other sources of ignition.088 MOBILITY The product is partly soluble in water. Change work clothing daily if there is any possibility of contamination. May cause chemical eye burns. 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE COLOUR ODOUR SOLUBILITY RELATIVE DENSITY DECOMPOSITION TEMPERATURE (°C) Pellets White Characteristic Slightly soluble in water. OTHER PROTECTION Wear rubber apron. May cause chemical burns in mouth. (ADR) HAZCHEM CODE RID PACK GROUP IMDG CLASS UN NO. Do not empty into drains.REVISION DATE: 06. Harmful if swallowed. Do not puncture or incinerate even when empty. ROAD ADR CLASS NO. RID CLASS NO. AIR CLASS III Class 5. 14 TRANSPORT INFORMATION UK ROAD CLASS PROPER SHIPPING NAME UN NO. SAFETY PHRASES S1/2 S26 S29 . ADR PACK GROUP HAZARD No. Causes burns. rinse immediately with plenty of water and seek medical advice.1 1748 III 5. DRY or CALCIUM HYPOCHLORITE MIXTURE.1 III 50 1W III 5. (E) 5. Disposal to licensed waste disposal site in accordance with the local Waste Disposal Authority.1 CALCIUM HYPOCHLORITE. Keep locked up and out of the reach of children.1 1748 III UK ROAD PACK GR. ADR CLASS TUNNEL RESTRICTION CODE ADR LABEL NO. WATER HAZARD CLASSIFICATION WGK 2 13 DISPOSAL CONSIDERATIONS GENERAL INFORMATION Waste is classified as hazardous waste. DISPOSAL METHODS Dispose of waste and residues in accordance with local authority requirements. Very toxic to aquatic organisms.2010 ACUTE FISH TOXICITY 4/ 5 HTH Tablets Very toxic to aquatic organisms.1: Oxidising substances.1 15 REGULATORY INFORMATION LABELLING Corrosive Harmful Oxidising CONTAINS RISK PHRASES Dangerous for the environment CALCIUM HYPOCHLORITE R8 R22 R31 R34 R50 Contact with combustible material may cause fire. 5.1 5. DRY 1748 5.08. Contact with acids liberates toxic gas. AIR AIR PACK GR. SEA IMDG PACK GR. UN NO. In case of contact with eyes. APPROVED CODE OF PRACTICE Safety Data Sheets for Substances and Preparations.REVISION DATE: 06. Avoid release to the environment. Risk of serious damage to eyes.08. REVISION DATE 06. NO.2010 Jitendra Panchal Causes burns. STATUTORY INSTRUMENTS Chemicals (Hazard Information and Packaging) Regulations. 16 OTHER INFORMATION REVISION COMMENTS NOTE: Lines within the margin indicate significant changes from the previous revision. DATE SIGNATURE RISK PHRASES IN FULL 06.2010 S36/37/39 S45 S61 EU DIRECTIVES 5/ 5 HTH Tablets Wear suitable protective clothing. Harmful if swallowed. Very toxic to aquatic organisms.08. SDS GENERATED SDS NO.08. Irritating to eyes. Refer to special instructions/safety data sheets. seek medical advice immediately (show label where possible). gloves and eye/face protection. Classification and Labelling of Substances and Preparations Dangerous for Supply. SAFETY DATA SHEET STATUS 01 11828 Approved. Dangerous Preparations Directive 1999/45/EC. In case of accident or if you feel unwell. GUIDANCE NOTES CHIP for everyone HSG(108). Irritating to skin. R34 R31 R8 R22 R36 R38 R41 R50 ./REPL. Contact with acids liberates toxic gas.2010 REV. Contact with combustible material may cause fire.
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