Refinery Gas Analysis

PerkinElmer ArnelTurnkey GC Systems Petrochemical & Natural Gas Applications Introduction The measurement of semivolatile and volatile compounds in petrochemical feeds, processes and products can be easily accomplished with turnkey analyzers and systems designed to meet accepted standard methods. PerkinElmer has a long-standing relationship with Arnel™, a market leader in customized chromatography solutions, to provide, install, and support a full range of guaranteed analyzers, systems and accessories. This Applications booklet summarizes the features and benefits of individual Clarus™ Arnel GC analyzers that are available for a variety of petrochemical laboratory and process applications, from hydrogen to asphalt analysis. More details and specifications are available for each model by obtaining the referenced companion literature for each product. Almost 100 turnkey analyzers are presented, ensuring that consultation with a PerkinElmer representative will deliver the analyzer that will meet your needs. Tables 1, 2 and 3 below show industry-standard methods compliance for standard model Refinery Gas Analyzers (RGA), Natural Gas Analyzers (NGA) and Trace Sulfur Analyzer Systems. Other standard model analyzers for light gas, chlorine, transformer oil gas, LPG and simulated distillation through detailed hydrocarbon analyses that are compliant with ASTM and various industry standard methods are also summarized in this applications booklet. Table 1. Methods Compliance for RGA Systems PerkinElmer Arnel RGA Model 1001 1101 1201 1301 1015, 1016 1115, 1116 1215, 1216 1315, 1316 ASTM Method D1945, D1946, D2597 D1945, D1946, D2597 D1945, D1946, D2597 D1945, D1946, D2597 D1945, D1946, D2597 D1945, D1946, D2597 D1945, D1946, D2597 D1945, D1946, D2597 UOP Method 539 539 539 539 539, 709 539, 709 539, 709 539, 709 Table 2. Methods Compliance for NGA Systems PerkinElmer Arnel NGA Model 2001, 2101 2201, 2301 2002, 2102, 2202, 2302 2003, 2103, 2203, 2303 2206, 2306 2008 2108 2208 2009, 2109, 2209 2000, 2100, 2200, 2300, 2006, 2106 2010, 2110, 2210 ASTM Methods D1945, D1946, D2597 D1945 D1945 D1945, D1946 None D1946 D1946 D1946 D1946 D1945, D1946 D1945, D1946 D1945 GPA Methods 2261 2177, 2261 2261 2261 2165, 2177, 2186 2286 2286 2165, 2186, 2286 2286 None None 2261 ISO Methods 6568, 6974-5 6568, 6974-5 6974-5 None None 6975 6974E, 6974-3, 6975 6974E, 6974-3, 6975 6975 None None 6974-5 IP Methods None None None None None 345 345 345 345 None None None Table 3. Methods Compliance for Sulfur Analyzer Systems PerkinElmer Arnel Sulfur Analyzer Model 4025, 4026, 4027, 4028, 4029, 4227, 4229, 4425, 4428, 4429, 4629 ASTM Methods D5504, D5623, D6021 1 Table of Contents Refinery Gas Analyzers Model 1001…………………………………………………………………………………….….5 Model 1015………………………………………………………………………………….…….6 Model 1016………………………………………………………………………………….…….7 Model 1101……………………………………………………………………………….……….8 Model 1115……………………………………………………………………………….……….9 Model 1116………………………………………………………………………………………10 Model 1201……………………………………………………………………………………....11 Model 1215.......................................................................................................................12 Model 1216.......................................................................................................................13 Model 1301.......................................................................................................................14 Model 1315.......................................................................................................................15 Model 1316.......................................................................................................................16 Natural Gas Analyzers Model 2000......................................................................................................................18 Model 2001......................................................................................................................19 Model 2002......................................................................................................................20 Model 2003......................................................................................................................21 Model 2006………………………………………………………………………………...……22 Model 2008......................................................................................................................23 Model 2009......................................................................................................................24 Model 2010......................................................................................................................25 Model 2100......................................................................................................................26 Model 2101......................................................................................................................27 Model 2102......................................................................................................................28 Model 2103......................................................................................................................29 Model 2106......................................................................................................................30 Model 2108......................................................................................................................31 Model 2109......................................................................................................................32 Model 2110......................................................................................................................33 Model 2200………………………………………………………………………………………34 Model 2201………………………………………………………………………………………35 Model 2202………………………………………………………………………………………36 Model 2203………………………………………………………………………………………37 Model 2206………………………………………………………………………………………38 Model 2208………………………………………………………………………………………39 Model 2209………………………………………………………………………………………40 Model 2210………………………………………………………………………………………41 Model 2300………………………………………………………………………………………42 Model 2301………………………………………………………………………………...…….43 Model 2302.......................................................................................................................44 Model 2303.......................................................................................................................45 Model 2306.......................................................................................................................46 Model 2310.......................................................................................................................47 Simulated Distillation Software and Software Enhancements Model 3012.......................................................................................................................49 Model 3013.......................................................................................................................50 Model 3062.......................................................................................................................51 2 .............................................................................................75 Model 4019………………………………………………………………………………………..............................79 Model 4023………………………………………………………………………………………............................................88 Model 4086………………………………………………………………………………………..........................67 Model 4009………………………………………………………………………………………..74 Model 4018………………………………………………………………………………………........................63 Model 4004………………………………………………………………………………………...............57 Model 4227.........Trace Sulfur Analyzers Model 4025..................................................................65 Model 4006………………………………………………………………………………………....................................... chlorine.........62 Model 4002………………………………………………………………………………………...........................72 Model 4016……………………………………………………………………………………….56 Model 4029....................................55 Model 4028..........82 Model 4034………………………………………………………………………………………...................................60 Model 4429...53 Model 4026................................................60 Model 4428...................................73 Model 4017……………………………………………………………………………………….....83 Model 4036………………………………………………………………………………………........................................... transformer oil gas............................................62 Model 4003……………………………………………………………………………………….....82 Model 4033………………………………………………………………………………………..............................77 Model 4021……………………………………………………………………………………….........................................................................................78 Model 4022……………………………………………………………………………………….........66 Model 4007……………………………………………………………………………………….....................................60 Other Analyzers (For light gas.............71 Model 4015……………………………………………………………………………………….....................54 Model 4027.........69 Model 4012………………………………………………………………………………………........ LPG and simulated distillation through detailed hydrocarbon analyses) Model 4001………………………………………………………………………………………........................................................60 Model 4629......................69 Model 4013………………………………………………………………………………………....................68 Model 4011……………………………………………………………………………………….............................63 Model 4082……………………………………………………………………………………….............85 Model 4080………………………………………………………………………………………...87 Model 4083……………………………………………………………………………………….86 Model 4081………………………………………………………………………………………..........70 Model 4014………………………………………………………………………………………..............................58 Model 4229..............81 Model 4032………………………………………………………………………………………..........................................68 Model 4010………………………………………………………………………………………..............................................................................................80 Model 4024………………………………………………………………………………………..........................................67 Model 4008………………………………………………………………………………………...........................84 Model 4037………………………………………………………………………………………....................59 Model 4425.....89 C5=: Pentenes C6+: C6 hydrocarbons and higher 3 ...........82 Model 4035………………………………………………………………………………………..................76 Model 4020………………………………………………………………………………………...........64 Model 4005………………………………………………………………………………………............... Refinery Gas Analyzers Refine Model 1001 Model 1015 Model 1016 Model 1101 Model 1115 Model 1116 Model 1201 Model 1215 Model 1216 Model 1301 Model 1315 Model 1316 Refinery Gas Analyzers . N2. no degradation from H2O. C6+. lowest-cost refinery/light hydrocarbon gas analysis solution Single channel/single thermal conductivity detector (TCD) Rugged packed columns. DIN 51872-4 Types of sample analyzed: Gas Compounds separated: H2. NH3 or other common contaminants Limited hydrogen detection range (see Model 1101 for full range capability) 35 .1 to 10%.0.01 to 100% except the C5=. C5=.01 to 40% Application note reference number with technical details: D-6620 Major Features and Benefits • • • • • • Simple.0. H2O. C1 through C5. H2O. ASTM D2597. CO. CO2.1 to 25%.0. NH3 composite peak . NH3 composite peak Guaranteed detection ranges/concentration levels: H2 . ASTM D1946.40 minute analysis time (see Model 1015 for faster analysis time) Plumbed in sulfur-resistant materials to enhance H2S detection Typical Chromatogram 5 . C6+. O2. H2S. all other components . UOP 539-73.Refinery Gas Analyzer Model 1001 Refinery Gas Analyzers Analyzer Description Published methods met: ASTM D1945. H2S . UOP 539-73.1 to 10%.TCD 6 Channel two . 15-minute analysis time Dual channel/thermal conductivity detector and flame ionization detector (TCD/FID) Rugged packed columns. CO2. C6+ composite peak Guaranteed detection ranges/concentration levels: H2 . CO.Ethylene Propylene i-Butane n-Butane Propadiene t-Butene-2 c-Butene-2 1-Butene 1. H2S. CO2. C6+ composite peak . C5=. CO.0.02 to 100%.001 to 100% on FID. N2. DIN 51872-4 Types of sample analyzed: Gas Compounds separated: H2. UOP 709. O2. ASTM D1946.0. NH3 or other common contaminants Limited hydrogen detection range (see Model 1115 for full range capability) Critical 1-butene/isobutylene separation Includes Model 3062 Software. C1 through C5 .C6+ Channel one . H2S .0.FID i-Pentane 15 Minutes Acetylene n-Pentane .01 to 100% Application note reference number with technical details: D-6621 Major Features and Benefits • • • • • • • Rapid. O2. C1 through C5. ASTM D2597. C1 and C2 hydrocarbons on TCD . C5=.002 to 40%. no degradation from H2O.0.Refinery Gas Analyzer Model 1015 Analyzer Description Published methods met: ASTM D1945. N2.3-Butadiene C5=. which contains a merge program to combine multichannel data into one report Plumbed in sulfur-resistant materials to enhance H2S detection Typical Chromatograms Propane Methane Ethane. H2O. NH3 composite peak Guaranteed detection ranges/concentration levels: H2 . UOP 709. Air Ethane. ASTM D1946. which contains a merge program to combine multichannel data into one report Plumbed in sulfur-resistant materials to enhance H2S detection Typical Chromatograms Methane. UOP 539-73. ASTM D2597. NH3 composite peak .02 to 100%.TCD n-Pentane i-Pentane 15 Minutes Butene-1 CO2 . H2S . CO2.01 to 100% Application note reference number with technical details: D-6621 Major Features and Benefits • • • • • • • Rapid. N2.3-Butadiene i-Butylene Channel one . C1 through C5.0. C5=. C6+. DIN 51872-4 Types of sample analyzed: Gas Compounds separated: H2.2 to 40%. H2O.1 to 10%.0. all other components . C6+.Refinery Gas Analyzer Model 1016 Analyzer Description Published methods met: ASTM D1945. C5=. H2S. Ethylene C5=. H2O.TCD 7 Channel two .0. no degradation from H2O. 15-minute analysis time Dual channel/dual thermal conductivity detector (TCD/TCD) Rugged packed columns. O2. NH3 Propane H2S i-Butane Propadiene n-Butane Acetylene Propylene t-Butene-2 c-Butene-2 1. NH3 or other common contaminants Limited hydrogen detection range (see Model 1116 for full range capability) Critical butane-1/isobutylene separation Includes Model 3062 Software. CO. C6+. NH3 or other common contaminants 35 . C5=. N2. H2S. CO. no degradation from H2O. H2O.Refinery Gas Analyzer Model 1101 Analyzer Description Published methods met: ASTM D1945. D-6653 Major Features and Benefits • • • • • • Full-range hydrogen detection using separate channel with nitrogen carrier gas Dual channel/dual thermal conductivity detector (TCD/TCD) Includes Model 3062 Software.0. UOP 539-73.40 minute analysis time (see Model 1015 for faster analysis time) Plumbed in sulfur-resistant materials to enhance H2S detection Typical Chromatogram 8 . which contains a merge program to combine multichannel data into one report Rugged packed columns. CO2. C1 through C5. O2. ASTM D1946. H2.01 to 100% except the C5=. all other components . NH3 composite peak .1 to 25%.0. NH3 composite peak Guaranteed detection ranges/concentration levels: H2S . C6+. DIN 51872-4 Types of sample analyzed: Gas Compounds separated: He. ASTM D2597. UOP 539-86. C6+.01 to 40% Application note reference number with technical details: D-6620. D-6651. H2O.0. 15-minute analysis time Full-range hydrogen detection using separate channel with nitrogen carrier gas Three channel/dual thermal conductivity detector and flame ionization detector (TCD/TCD/FID) Rugged packed columns.0.01 to 100% Application note reference number with technical details: D-6621. CO2.Refinery Gas Analyzer Model 1115 Analyzer Description Published methods met: ASTM D1945. O2. ASTM D2597. D-6653 Major Features and Benefits • • • • • • • Rapid. C1 through C5. CO. H2S.FID 9 i-Pentane Oxygen H2S 15 Minutes Acetylene n-Pentane Ethylene Ethane CO2 . N2.Ethylene Propane Propylene i-Butane n-Butane Propadiene t-Butene-2 c-Butene-2 1-Butene Methane 1. He. UOP 539-73. N2. C5=. DIN 51872-4 Types of sample analyzed: Gas Compounds separated: He. C6+ composite peak Guaranteed detection ranges/concentration levels: H2S .C6+ Acetylene 15 Minutes Channel one and two . ASTM D1946. CO. O2.002 to 40%. no degradation from H2O. C5=. C1. H2. NH3 or other common contaminants Critical 1-butene/isobutylene separation Includes Model 3062 Software. C1 through C5 .001 to 100% on FID. H2. CO2. UOP 709. which contains a merge program to combine multichannel data into one report Plumbed in sulfur-resistant materials to enhance H2S detection Typical Chromatograms Hydrogen Nitrogen Methane Ethane.02 to 100%.TCD/TCD (electronically combined into one output ) CO Channel three .3-Butadiene C5=.0.0. C6+ composite peak . D-6651. C2 hydrocarbons on TCD . UOP 539-86.0. 0. H2O. UOP 539-86. D-6653 Major Features and Benefits • • • • • • • Rapid. UOP 539-73. C1 through C5. UOP 709. CO. C5=. ASTM D1946.2 to 40%. H2O.Refinery Gas Analyzer Model 1116 Analyzer Description Published methods met: ASTM D1945.0.TCD 10 n-Pentane i-Pentane Oxygen CO 15 Minutes CO2 Acetylene H2S Butene-1 Ethylene CO2 . all other components .3-Butadiene Ethane Methane i-Butylene 15 Minutes Channel one and two .0. D-6651. 15-minute analysis time Full-range hydrogen detection using separate channel with nitrogen carrier gas Three channel/three thermal conductivity detector (TCD/TCD/TCD) Rugged packed columns. Air Propane H2S i-Butane Propadiene n-Butane Acetylene Propylene t-Butene-2 c-Butene-2 1. no degradation from H2O. C5=. ASTM D2597. C6+. N2.02 to 100%. H2S. C6+. H2O. NH3 composite peak Guaranteed detection ranges/concentration levels: H2S . CO2. NH3 Methane. NH3 or other common contaminants Critical 1-butene (butene-1)/isobutylene separation Includes Model 3062 Software. O2. Ethylene C5=.01 to 100% Application note reference number with technical details: D-6621. H2. which contains a merge program to combine multichannel data into one report Plumbed in sulfur-resistant materials to enhance H2S detection Typical Chromatograms Hydrogen Nitrogen Ethane. DIN 51872-4 Types of sample analyzed: Gas Compounds separated: He.TCD/TCD (electronically combined into one output) Channel three . C6+. NH3 composite peak . plus a vaporization zone for proper liquid sample injection Single channel/single thermal conductivity detector (TCD) Rugged packed columns. all other components . D-6653 Major Features and Benefits • • • • • • • Added liquid-sampling capability to Model 1001 Includes sample-loop purge feature that prevents contamination when changing sample types. a secondary filter and back pressure regulation for proper liquid sample introduction. H2O. DIN 51872-4 Types of sample analyzed: Gas.Refinery Gas Analyzer Model 1201 Analyzer Description Published methods met: ASTM D1945. ASTM D2597. pressurized liquid Compounds separated: H2. H2O. D-6652.1 to 10%. UOP 539-73. C6+. no degradation from H2O.0. C5=. liquid. H2S. NH3 composite peak Guaranteed detection ranges/concentration levels: H2 . C1 through C5. H2S .01 to 100% except the C5=. C6+. NH3 composite peak .01 to 40% Application note reference number with technical details: D-6620. CO.1 to 25%. ASTM D1946.40 minute analysis time (see Model 1015 for faster analysis time) Plumbed in sulfur-resistant materials to enhance H2S detection Typical Chromatogram 11 . N2. NH3 or other common contaminants Limited hydrogen detection range (see Model 1101 for full-range capability) 35 . O2.0. CO2.0. 3-Butadiene C5=. N2. UOP 709.0. N2.0. C1 through C5 . D-6653 Major Features and Benefits • • • • • • • • • Rapid.0. CO2. ASTM D2597. C6+ composite peak .01 to 100% Application note reference number with technical details: D-6621. DIN 51872-4 Types of sample analyzed: Gas. ASTM D1946. no degradation from H2O. C2s on TCD .001 to 100% on FID.TCD 12 Channel two . C1 through C5.002 to 40%. which contains a merge program to combine multichannel data into one report Plumbed in sulfur-resistant materials to enhance H2S detection Typical Chromatograms Propane Methane Ethane. C5=. UOP 539-73.Refinery Gas Analyzer Model 1215 Analyzer Description Published methods met: ASTM D1945. H2S . CO2.1 to 10%. O2. NH3 or other common contaminants Limited hydrogen detection range (see Model 1315 for full-range capability) Critical 1-butene/isobutylene separation Includes Model 3062 Software. H2S.FID i-Pentane 15 Minutes n-Pentane Acetylene .Ethylene Propylene i-Butane n-Butane Propadiene t-Butene-2 c-Butene-2 1-Butene 1. plus a vaporization zone for proper liquid sample injection Dual channel/thermal conductivity detector and flame ionization detector (TCD/FID) Rugged packed columns. CO. D-6652. O2.02 to 100%.0. a secondary filter and back pressure regulation for proper liquid sample introduction. C6+ composite peak Guaranteed detection ranges/concentration levels: H2 . 15-minute analysis time Added liquid-sampling capability to FID channel of Model 1015 Includes sample-loop purge feature that prevents contamination when changing sample types. C5=. CO.C6+ Channel one . liquid. pressurized liquid Compounds separated: H2. C1. C5=.0.0.1 to 10%. DIN 51872-4 Types of sample analyzed: Gas. H2O. Air Ethane. C1 through C5.01 to 100% Application note reference number with technical details: D-6621. 15-minute analysis time Added liquid-sampling capability to hydrocarbon channel of Model 1016 Includes sample-loop purge feature that prevents contamination when changing sample types. no degradation from H2O. D-6653 Major Features and Benefits • • • • • • • • • Rapid.TCD n-Pentane i-Pentane 15 Minutes Butene-1 CO2 . CO. UOP 709. all other components .02 to 100%. H2O.2 to 40%. N2. Ethylene C5=. O2. C6+. C6+.TCD 13 Channel two . NH3 composite peak Guaranteed detection ranges/concentration levels: H2 . liquid. plus a vaporization zone for proper liquid sample injection Dual channel/dual thermal conductivity detector (TCD/TCD) Rugged packed columns. D-6652.3-Butadiene i-Butylene Channel one . C6+. NH3 or other common contaminants Limited hydrogen detection range (see Model 1316 for full-range capability) Critical butene – 1/isobutylene separation Includes Model 3062 Software. ASTM D2597.0. C5=. which contains a merge program to combine multichannel data into one report Plumbed in sulfur-resistant materials to enhance H2S detection Typical Chromatograms Methane.Refinery Gas Analyzer Model 1216 Analyzer Description Published methods met: ASTM D1945. UOP 539-73. NH3 Propane H2S i-Butane Propadiene n-Butane Acetylene Propylene t-Butene-2 c-Butene-2 1. NH3 composite peak . H2O. pressurized liquid Compounds separated: H2. CO2. ASTM D1946. H2S. a secondary filter and back pressure regulation for proper liquid sample introduction. H2S . H2O. CO. D-6651.01 to 40% Application note reference number with technical details: D-6620. D-6653 Major Features and Benefits • • • • • • • • Full-range hydrogen detection using separate channel with nitrogen carrier gas Added liquid-sampling capability to Model 1101 Includes sample-loop purge feature that prevents contamination when changing sample types. ASTM D1946.01 to 100% except the C5=. a secondary filter and back pressure regulation for proper liquid sample introduction.0.1 to 25%.0. no degradation from H2O. which contains a merge program to combine multichannel data into one report Rugged packed columns. H2O. pressurized liquid Compounds separated: He. NH3 or other common contaminants 35 . liquid. DIN 51872-4 Types of sample analyzed: Gas. all other components . plus a vaporization zone for proper liquid sample injection Dual channel/dual thermal conductivity detector (TCD/TCD) Includes Model 3062 Software.Refinery Gas Analyzer Model 1301 Analyzer Description Published methods met: ASTM D1945. H2. UOP 539-86. CO2. UOP 539-73. C5=. C6+. ASTM D2597. NH3 composite peak . C1 through C5. N2. H2S.40 minute analysis time (see Model 1015 for faster analysis time) Plumbed in sulfur-resistant materials to enhance H2S detection Typical Chromatogram 14 . O2. D-6652. C6+.0. NH3 composite peak Guaranteed detection ranges/concentration levels: H2S . C5=. DIN 51872-4 Types of sample analyzed: Gas. H2S. D-6651. which contains a merge program to combine multichannel data into one report Plumbed in sulfur-resistant materials to enhance H2S detection Typical Chromatograms Propane Methane Ethane. C6+ composite peak Guaranteed detection ranges/concentration levels: H2S . C5=. ASTM D2597.FID i-Pentane Oxygen H2S 15 Minutes Acetylene n-Pentane Ethylene Ethane CO2 .0.3-Butadiene C5=. pressurized liquid Compounds separated: He.Refinery Gas Analyzer Model 1315 Analyzer Description Published methods met: ASTM D1945. D-6653 Major Features and Benefits • • • • • • • • • Rapid.01 to 100% Application note reference number with technical details: D-6621. ASTM D1946. O2. D-6652. plus a vaporization zone for proper liquid sample injection Rugged packed columns. CO. CO2.TCD/TCD (electronically combined into one output) 15 Channel three . CO. C6+ composite peak .0.02 to 100%. C1 through C5 .0. C1 and C2 hydrocarbons on TCD .Ethylene Hydrogen Nitrogen Propylene i-Butane n-Butane Propadiene t-Butene-2 c-Butene-2 1-Butene Methane 1. UOP 539-86.0. H2. liquid. 15-minute analysis time Full-range hydrogen detection using separate channel with nitrogen carrier gas Three channel / dual thermal conductivity detector and flame ionization detector (TCD/TCD/FID) Added liquid-sampling capability to FID channel of Model 1115 Includes sample-loop purge feature that prevents contamination when changing sample types. He. UOP 709.001 to 100% on FID. no degradation from H2O. O2.002 to 40%. NH3 or other common contaminants Critical 1-butene/isobutylene separation Includes Model 3062 Software. H2. N2. UOP 539-73. CO2. a secondary filter and back pressure regulation for proper liquid sample introduction. C1 through C5. N2.C6+ Acetylene 15 Minutes CO Channel one and two . 0. C6+. no degradation from H2O. UOP 539-73. C1 through C5. ASTM D1946. H2O.TCD n-Pentane i-Pentane Oxygen CO 15 Minutes CO2 Acetylene H2S Butene-1 Ethylene CO2 . NH3 Propane H2S i-Butane Propadiene n-Butane Acetylene Propylene Hydrogen Nitrogen t-Butene-2 c-Butene-2 1. ASTM D2597. C5=. plus a vaporization zone for proper liquid sample injection Rugged packed columns.2 to 40%. CO2. UOP 539-86.0.TCD/TCD (electronically combined into one output ) 16 Channel three . CO.01 to 100% Application note reference number with technical details: D-6621. which contains a merge program to combine multichannel data into one report Plumbed in sulfur-resistant materials to enhance H2S detection Typical Chromatograms Methane. N2.Refinery Gas Analyzer Model 1316 Analyzer Description Published methods met: ASTM D1945. C5=. C6+. UOP 709. O2. D-6651.02 to 100%. D-6652. all other components . NH3 or other common contaminants Critical butane-1/isobutylene separation Includes Model 3062 Software. NH3 composite peak . Ethylene C5=. liquid. D-6653 Major Features and Benefits • • • • • • • • • Rapid. H2S. pressurized liquid Compounds separated: He.3-Butadiene Ethane Methane i-Butylene 15 Minutes Channel one and two . NH3 composite peak Guaranteed detection ranges/concentration levels: H2S . C6+. DIN 51872-4 Types of sample analyzed: Gas. 15-minute analysis time Full-range hydrogen detection using separate channel with nitrogen carrier gas Three channel/three thermal conductivity detector (TCD/TCD/TCD) Added liquid-sampling capability to FID channel of Model 1116 Includes sample-loop purge feature that prevents contamination when changing sample types. H2O. a secondary filter and back pressure regulation for proper liquid sample introduction.0. H2O. Air Ethane. H2. Natural Gas Analyzers Natural Model 2000 Model 2001 Model 2002 Model 2003 Model 2006 Model 2008 Model 2009 Model 2010 Model 2100 Model 2101 Model 2102 Model 2103 Model 2106 Model 2108 Model 2109 Model 2110 Model 2200 Model 2201 Model 2202 Model 2203 Model 2206 Model 2208 Model 2209 Model 2210 Model 2300 Model 2301 Model 2302 Model 2303 Model 2306 Model 2310 Natural Gas Analyzers . 005 to 100%.0.Pentane i . no interference from air or CO2 Designed so that the lowest boiling C6 (2. Natural gas does not contain light hydrocarbon unsaturates.005 to 10% Application note reference number with technical details: D-6622. LPG samples can not be analyzed on this analyzer without modification. low-cost solution Single channel/single FID Only hydrocarbons detected and measured.Butane i . Typical Chromatogram Methane Ethane Propane n .2-dimethylbutane) is included in the backflush. no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • This analyzer is for natural gas. See Model 4036 or Model 4037. C6+ . which meets ASTM D2163 methodology for LPG.Butane 2 4 6 8 Time (min) 10 12 14 All compounds measured by FID 18 n . D-6623 Major Features and Benefits • • • • Simple. C6+ composite Guaranteed detection ranges/concentration levels: All components except C6+ .Pentane C6+ .0. • Rugged packed columns.Natural Gas Analyzer Model 2000 Analyzer Description Published methods met: ASTM D1945 (precision statement only) Types of sample analyzed: Gas Compounds separated: C1 through C5. Butane 0 2 4 6 8 Time (min) 10 12 19 n .0.2-dimethylbutane) is included in the backflush.01 to 20%.0. no degradation from common contaminants Model 3062 Software available containing template for heating value calculation and other sample specifications Plumbed in sulfur-resistant materials to enhance H2S detection This analyzer is for natural gas. which meets ASTM D2163 methodology for LPG analysis Typical Chromatogram Methane Ethane O2/N2 Propane C6+ n . ISO 6568.01 to 10% Application note reference number with technical details: D-6622. H2S. C1 through C5 .Natural Gas Analyzer Model 2001 Analyzer Description Published methods met: ASTM D1945. CO2. ISO 6974-5. H2S . N2 composite. DIN 51872-5 Types of sample analyzed: Gas Compounds separated: O2. C1 through C5.Pentane CO2 H2S .Butane i . N2 composite and CO2 – 0.1 to 25%. C6+ composite Guaranteed detection ranges/concentration levels: O2. LPG samples can not be analyzed on this analyzer without modification. GPA 2261. low-cost solution Single channel/single thermal conductivity detector (TCD) No separation and measurement of O2 and N2 individually Designed so that the lowest boiling C6 (2. See Model 4036 or Model 4037.01 to 100%. D-6624 Major Features and Benefits • • • • • • • • Simple. C6+ composite . Rugged packed columns. Natural gas does not contain light hydrocarbon unsaturates.0.Pentane 14 i . C6+ composite . Typical Chromatogram Methane Propane O2 / N 2 n . LPG samples can not be analyzed on this analyzer without modification. C6+ composite Guaranteed detection ranges/concentration levels: Ar – 0.0. See Model 4036 or Model 4037. N2 composite.2-dimethylbutane) is included in the backflush. C1 through C5. H2S.Pentane i . Application note reference number with technical details: D-6622. Rugged packed columns. GPA 2261.0.01 to 100%. ISO 6974-5.Natural Gas Analyzer Model 2002 Analyzer Description Published methods met: ASTM D1945. CO2. O2. no degradation from common contaminants Model 3062 Software available containing template for heating value calculation and other sample specifications Plumbed in sulfur-resistant materials to enhance H2S detection This analyzer is for natural gas. which meets ASTM D2163 methodology for LPG analysis.Butane n .1 to 5%. D-6625 Major Features and Benefits • • • • • • • • Baseline separation of O2.Pentane C6+ H2S Argon 10 Time (min) 20 CO2 20 Ethane . H2S .01 to 10%. DIN 51872-5 Types of sample analyzed: Gas Compounds separated: Ar. N2 composite and methane. Natural gas does not contain light hydrocarbon unsaturates.Butane i .0. all other components . argon measurement Single channel/single thermal conductivity detector (TCD) No separation and measurement of O2 and N2 individually Designed so that the lowest boiling C6 (2.01 to 4%. ASTM D1946.2-dimethylbutane) is included in the backflush. C6+ composite Guaranteed detection ranges/concentration levels: O2 and C6+ composite . LPG samples can not be analyzed on this analyzer without modification. Application note reference number with technical details: D-6622. CO2 and C1 through C5 . N2. GPA 2261. N2 – 0. H2S.0. which meets ASTM D2163 methodology for LPG analysis. See Model 4036 or Model 4037. D-6626 Major Features and Benefits • • • • • • • Single channel/single thermal conductivity detector (TCD) Separation and measurement of O2 and N2 individually Designed so that the lowest boiling C6 (2. DIN 51872-5 Types of sample analyzed: Gas Compounds separated: O2.01 to 10%. H2S . Natural gas does not contain light hydrocarbon unsaturates.0. C1 through C5.1 to 5%. Typical Chromatogram Nitrogen C6+ Propane n-Butane Ethane i-Butane n-Pentane i-Pentane H2S 2 4 6 8 Time (min) 10 CO2 12 Oxygen 14 21 Methane . CO2.01 to 100%.Natural Gas Analyzer Model 2003 Analyzer Description Published methods met: ASTM D1945. no degradation from common contaminants Model 3062 Software available containing template for heating value calculation and other sample specifications Plumbed in sulfur-resistant materials to enhance H2S detection This analyzer is for natural gas.0. Rugged packed columns.01 to 20%. C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2. extended hydrocarbon analysis to C10 Model 3062 Software available containing template for heating value calculation and other sample specifications Plumbed in sulfur-resistant materials to enhance H2S detection This analyzer is for natural gas. Natural gas does not contain light hydrocarbon unsaturates. which meets ASTM D2163 methodology for LPG analysis. N2 composite and CO2 – 0.TCD 22 Channel two .Pentane CO2 0 2 4 6 8 Time (min) 10 12 14 10 Time (min) 20 Channel one . LPG samples can not be analyzed on this analyzer without modification.FID Decane H2S n-Butylbenzene Propane Butanes C6+ . D-6627 Major Features and Benefits • • • • • • • • Capillary channel added to Model 2001 Dual channel/thermal conductivity detector (TCD). Typical Chromatograms Methane Pentanes p-Xylene Octane Heptane Hexane O2/N2 Ethane n-Propylbenzene n .01 to 10%.Natural Gas Analyzer Model 2006 Analyzer Description Published methods met: None Types of sample analyzed: Gas Compounds separated: O2.0.Butane n .0.005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622.01 to 100%. N2 composite. H2S .2-dimethylbutane) is included in the backflush on TCD channel.Butane i . CO2. See Model 4036 or Model 4037. C1 through C5 .0. C6+ composite . Packed and capillary columns.Pentane i . Channel two (FID): C4 to C10 .1 to 25%.0.01 to 20%. flame ionization detector (FID) No separation and measurement of O2 and N2 individually Designed so that the lowest boiling C6 (2. C1 through C10. H2S. extended hydrocarbon analysis to C10 Model 3062 Software available containing template for heating value calculation and other sample specifications Plumbed in sulfur-resistant materials to enhance H2S detection This analyzer is for natural gas. CO2 and C1 through C5 .01 to 20%.1 to 5%. ISO 6975 Types of sample analyzed: Gas Compounds separated: O2. N2. D-6628 Major Features and Benefits • • • • • • • • Capillary channel added to Model 2003 Dual channel/thermal conductivity detector (TCD).0. Typical Chromatograms Nitrogen Methane Pentanes Octane p-Xylene Hexane Heptane n-Propylbenzene Propane Ethane n-Butane i-Butane n-Pentane i-Pentane H2S CO2 10 2 4 6 8 Time (min) 10 12 14 20 Time (min) Channel one . which meets ASTM D2163 methodology for LPG analysis.2-dimethylbutane) is included in the backflush on TCD channel.01 to 10%.0. H2S. LPG samples can not be analyzed on this analyzer without modification. N2 – 0. H2S .TCD Channel two .0. flame ionization detector (FID) Separation and measurement of O2 and N2 individually Designed so that the lowest boiling C6 (2. Packed and capillary columns. IP 345.Natural Gas Analyzer Model 2008 Analyzer Description Published methods met: ASTM D1946. C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2 and C6+ composite 0. GPA 2286. C1 through C10. See Model 4036 or Model 4037.01 to 100% Channel two (FID): C4 to C10 .FID 23 Decane Oxygen n-Butylbenzene C6+ Butanes . CO2.005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622. Natural gas does not contain light hydrocarbon unsaturates. FID 24 Decane n-Butylbenzene Butanes . CO2 and C1 through C4 .01 to 20%. N2. H2S . flame ionization detector (FID) Separation and measurement of O2 and N2 individually Packed and capillary columns. LPG samples can not be analyzed on this analyzer without modification.1 to 5%. See Model 4036 or Model 4037. IP 345.0.TCD Channel two . C1 through C10 Guaranteed detection ranges/concentration levels: Channel one (TCD): O2 . Natural gas does not contain light hydrocarbon unsaturates. N2 – 0.01 to 100% Channel two (FID): C4 to C10 . Typical Chromatograms Pentanes Octane p-Xylene Hexane Heptane n-Propylbenzene 10 Time (min) 20 Channel one . extended hydrocarbon analysis to C10 Model 3062 Software available containing template for heating value calculation and other sample specifications Plumbed in sulfur-resistant materials to enhance H2S detection This analyzer is for natural gas.005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622.Natural Gas Analyzer Model 2009 Analyzer Description Published methods met: ASTM D1946. GPA 2286. H2S. CO2. ISO 6975 Types of sample analyzed: Gas Compounds separated: O2.01 to 10%.0. D-6629 Major Features and Benefits • • • • • • • “Fast Model 2008” – C4 + compounds backflushed to vent on TCD channel Dual channel/thermal conductivity detector (TCD).0.0. which meets ASTM D2163 methodology for LPG analysis. H2S. GPA 2261.0. ISO 6974-5 Types of sample analyzed: Gas Compounds separated: O2. He. CO2. LPG samples can not be analyzed on this analyzer without modification.0.01 to 20%.Natural Gas Analyzer Model 2010 Analyzer Description Published methods met: ASTM D1945.01 to 100%.001 to 100% Application note reference number with technical details: D-6622. N2 composite. Typical Chromatogram Methane Ethane Air Carbon Dioxide Propane N-Butane i-Butane TCD channel – C6+ backflushed to FID 25 n-Pentane I-Pentane H2S . no degradation from common contaminants Model 3062 Software available containing template for heating value calculation and other sample specifications Plumbed in sulfur-resistant materials to enhance H2S detection This analyzer is for natural gas. C1 through C5. N2 composite and CO2 – 0. D-6630 Major Features and Benefits • • • • • • • • • Model 2001 with C6+ backflush to FID channel (no water interference/better sensitivity) Full-range hydrogen detection using separate channel with nitrogen carrier gas Three channel (TCD/TCD/FID) No separation and measurement of O2 and N2 individually Designed so that the lowest boiling C6 (2. Rugged packed columns. H2S .0.1 to 25% Channel two (FID): C6+ composite . C1 through C5 . See Model 4036 or Model 4037.2-dimethylbutane) is included in the backflush. H2. Natural gas does not contain light hydrocarbon unsaturates. C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2. which meets ASTM D2163 methodology for LPG analysis. which meets ASTM D2163 methodology for LPG analysis. Natural gas does not contain light hydrocarbon unsaturates. C6+ composite Guaranteed detection ranges/concentration levels: He. no interference from air or CO2 Designed so that the lowest boiling C6 (2. C1 through C5.005 to 10% Application note reference number with technical details: D-6622. Typical Chromatogram H2 measured by TCD and the remaining compounds measured by FID 26 .005 to 100%. LPG samples can not be analyzed on this analyzer without modification. H2.0.Natural Gas Analyzer Model 2100 Analyzer Description Published methods met: ASTM D1945 (precision statement only) Types of sample analyzed: Gas Compounds separated: He.01 to 100%. plus merge and custom report formatting This analyzer is for natural gas. C6+ .0. H2 – 0. Rugged packed columns. no degradation from common contaminants Model 3062 Software included containing template for heating value calculation and other sample specifications. flame ionization detector (TCD/FID) Hydrocarbons detected and measured.2-dimethylbutane) is included in the backflush. D-6623. D-6651 Major Features and Benefits • • • • • • • Full-range hydrogen detection using separate channel with nitrogen carrier gas Dual channel/thermal conductivity detector. See Model 4036 or Model 4037. all other components except C6+ composite . LPG samples can not be analyzed on this analyzer without modification.Natural Gas Analyzer Model 2101 Analyzer Description Published methods met: ASTM D1945. N2 composite and CO2 – 0.01 to 10% Application note reference number with technical details: D-6622. See Model 4036 or Model 4037. N2 composite.0.2-dimethylbutane) is included in the backflush. no degradation from common contaminants Model 3062 Software available containing template for heating value calculation and other sample specifications Plumbed in sulfur-resistant materials to enhance H2S detection This analyzer is for natural gas. Natural gas does not contain light hydrocarbon unsaturates. D-6624.01 to 100%. GPA 2261.1 to 25%. 27 .01 to 20%. H2. C1 through C5 – 0. ISO 6568. H2S . which meets ASTM D2163 methodology for LPG analysis. CO2.0. ISO 6974-5. H2. Rugged packed columns. C6+ composite Guaranteed detection ranges/concentration levels: He. H2S. DIN 51872-5 Types of sample analyzed: Gas Compounds separated: He. O2. D-6651 Major Features and Benefits • • • • • • • • Full-range hydrogen detection using separate channel with nitrogen carrier gas Dual channel/dual thermal conductivity detector (TCD/TCD) No separation and measurement of O2 and N2 individually Designed so that the lowest boiling C6 (2. O2. Typical Chromatogram H2 measured in one TCD utilizing a nitrogen carrier gas and the remaining compounds measured in a second TCD utilizing a helium carrier gas. C1 through C5. C6+ composite . H2. GPA 2261. CO2.01 to 10%. which meets ASTM D2163 methodology for LPG analysis. H2S.2-dimethylbutane) is included in the backflush. C6+ composite Guaranteed detection ranges/concentration levels: Ar – 0. argon measurement Full-range hydrogen detection using separate channel with nitrogen carrier gas Dual channel/dual thermal conductivity detector (TCD/TCD) No separation and measurement of O2 and N2 individually Designed so that the lowest boiling C6 (2.Natural Gas Analyzer Model 2102 Analyzer Description Published methods met: ASTM D1945. all other components . Natural gas does not contain light hydrocarbon unsaturates. DIN 51872-5 Types of sample analyzed: Gas Compounds separated: He. N2 composite and methane. ISO 6974-5. 28 . D-6651 Major Features and Benefits • • • • • • • • • Baseline separation of O2. Application note reference number with technical details: D-6622. no degradation from common contaminants Model 3062 Software available containing template for heating value calculation and other sample specifications Plumbed in sulfur-resistant materials to enhance H2S detection This analyzer is for natural gas.01 to 4%. N2 composite.0. H2S . C1 through C5. O2. D-6625. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037.0. Ar. C6+ composite .01 to 100%.0. Rugged packed columns. Typical Chromatogram H2 measured in one TCD utilizing a nitrogen carrier gas and the remaining compounds measured in a second TCD utilizing a helium carrier gas.1 to 5%. C6+ composite Guaranteed detection ranges/concentration levels: O2 and C6+ composite . H2S . O2.01 to 20%.Natural Gas Analyzer Model 2103 Analyzer Description Published methods met: ASTM D1945. N2. CO2 and C1 through C5 . Application note reference number with technical details: D-6622.0. which meets ASTM D2163 methodology for LPG analysis.0. D-6626. H2S.1 to 5%. ASTM D1946. C1 through C5. no degradation from common contaminants Model 3062 Software available containing template for heating value calculation and other sample specifications Plumbed in sulfur-resistant materials to enhance H2S detection This analyzer is for natural gas. GPA 2261. Typical Chromatogram H2 measured in one TCD utilizing a nitrogen carrier gas and the remaining compounds measured in a second TCD utilizing a helium carrier gas. CO2. N2 – 0.01 to 100%.01 to 10%.2-dimethylbutane) is included in the backflush. DIN 51872-5 Types of sample analyzed: Gas Compounds separated: He.0. H2. LPG samples can not be analyzed on this analyzer without modification. H2. D-6651 Major Features and Benefits • • • • • • • • Full-range hydrogen detection using separate channel with nitrogen carrier gas Dual channel/dual thermal conductivity detector (TCD/TCD) Separation and measurement of O2 and N2 individually Designed so that the lowest boiling C6 (2. He. Rugged packed columns. Natural gas does not contain light hydrocarbon unsaturates. 29 . See Model 4036 or Model 4037. 01 to 100%. C1 through C10. H2. C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2.0. C6+ composite 0. N2 composite and CO2 – 0.01 to 20%. D-6627.0.01 to 10%. Channel two (FID): C4 to C10 .Natural Gas Analyzer Model 2106 Analyzer Description Published methods met: None Types of sample analyzed: Gas Compounds separated: He. which meets ASTM D2163 methodology for LPG analysis. H2. LPG samples can not be analyzed on this analyzer without modification. D-6651 Major Features and Benefits • • • • • • • • • Capillary channel added to Model 2101 Full-range hydrogen detection using separate channel with nitrogen carrier gas Three channel/ two thermal conductivity detector. N2 composite. Typical Chromatograms Pentanes p-Xylene Octane Heptane Hexane n-Propylbenzene 10 Time (min) 20 Channel one and two – TCD/TCD 30 Channel two . See Model 4036 or Model 4037. extended hydrocarbon analysis to C10 Model 3062 Software available containing template for heating value calculation and other sample specifications Plumbed in sulfur-resistant materials to enhance H2S detection This analyzer is for natural gas.0.2-dimethylbutane) is included in the backflush on TCD channel. O2. flame ionization detector (TCD/TCD/FID) No separation and measurement of O2 and N2 individually Designed so that the lowest boiling C6 (2.005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622. C1 through C5 . H2S . Packed and capillary columns. CO2.1 to 25%. Natural gas does not contain light hydrocarbon unsaturates. He. H2S.FID Decane n-Butylbenzene Butanes . Packed and capillary columns. extended hydrocarbon analysis to C10 Model 3062 Software available containing template for heating value calculation and other sample specifications Plumbed in sulfur-resistant materials to enhance H2S detection This analyzer is for natural gas. IP 345.1 to 5%.01 to 20%.0.0. CO2 and C1 through C5 . O2 and C6+ composite . D-6651 Major Features and Benefits • • • • • • • • • Capillary channel added to Model 2103 Full-range hydrogen detection using separate channel with nitrogen carrier gas Three channel (TCD/TCD/FID) Separation and measurement of O2 and N2 individually Designed so that the lowest boiling C6 (2. O2. D-6628. See Model 4036 or Model 4037.0. C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): He.FID 31 Decane n-Butylbenzene Butanes .0. GPA 2286. N2 – 0. ISO 6974E. H2.Natural Gas Analyzer Model 2108 Analyzer Description Published methods met: ASTM D1946. LPG samples can not be analyzed on this analyzer without modification. ISO 6974-3. H2. CO2. H2S . which meets ASTM D2163 methodology for LPG analysis.TCD Channel three . N2.01 to 100% Channel two (FID): C4 to C10 .01 to 10%. H2S. ISO 6975 Types of sample analyzed: Gas Compounds separated: He.2-dimethylbutane) is included in the backflush on TCD channel. Typical Chromatograms Pentanes p-Xylene Octane Hexane Heptane n-Propylbenzene 10 Time (min) 20 Channel one and two .005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622. Natural gas does not contain light hydrocarbon unsaturates. C1 through C10. D-6629.FID 32 Decane n-Butylbenzene Butanes . N2. N2 – 0. LPG samples can not be analyzed on this analyzer without modification. CO2 and C1 through C4 .01 to 100% Channel two (FID): C4 to C10 . extended hydrocarbon analysis to C10 Model 3062 Software available containing template for heating value calculation and other sample specifications Plumbed in sulfur-resistant materials to enhance H2S detection This analyzer is for natural gas.0. C1 through C10 Guaranteed detection ranges/concentration levels: Channel one (TCD): O2 . See Model 4036 or Model 4037. O2. Typical Chromatograms Pentanes Octane p-Xylene Hexane Heptane n-Propylbenzene 10 Time (min) 20 Channel one and two – TCD/TCD Channel two . H2. H2. H2S . He. ISO 6975 Types of sample analyzed: Gas Compounds separated: He.0.1 to 5%. Natural gas does not contain light hydrocarbon unsaturates. GPA 2286. CO2.01 to 20%.005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622. H2S.0.01 to 10%. D-6651 Major Features and Benefits • • • • • • • • “Fast Model 2008” – C4 + compounds backflushed to vent on main TCD channel Full-range hydrogen detection using separate channel with nitrogen carrier gas Three channel (TCD/TCD/FID) Separation and measurement of O2 and N2 individually Packed and capillary columns. which meets ASTM D2163 methodology for LPG analysis.0.Natural Gas Analyzer Model 2109 Analyzer Description Published methods met: ASTM D1946. IP 345. 0. C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2. C1 through C5.01 to 20%. ISO 6974-5 Types of sample analyzed: Gas Compounds separated: He. H2S. Typical Chromatogram Methane Ethane Air Carbon Dioxide Propane N-Butane i-Butane He. N2 composite. See Model 4036 or Model 4037. D-6651 Major Features and Benefits • • • • • • • • • Model 2101 with C6+ backflush to FID channel (no water interference/better sensitivity) Full-range hydrogen detection using separate channel with nitrogen carrier gas Three channel (TCD/TCD/FID) No separation and measurement of O2 and N2 individually Designed so that the lowest boiling C6 (2. CO2. N2 composite and CO2 – 0. O2. H2. GPA 2261. no degradation from common contaminants Model 3062 Software available containing template for heating value calculation and other sample specifications Plumbed in sulfur-resistant materials to enhance H2S detection This analyzer is for natural gas. C6+ backflushed to FID.01 to 100%. LPG samples can not be analyzed on this analyzer without modification. all other compounds measured using TCD with Helium carrier gas. which meets ASTM D2163 methodology for LPG analysis. He. D-6630.2-dimethylbutane) is included in the backflush.0.0. Natural gas does not contain light hydrocarbon unsaturates. H2S .Natural Gas Analyzer Model 2110 Analyzer Description Published methods met: ASTM D1945. H2. C1 through C5 . H2 measured by TCD using Nitrogen carrier gas.001 to 100% Application note reference number with technical details: D-6622.1 to 25% Channel two (FID): C6+ composite . Rugged packed columns. 33 n-Pentane I-Pentane H2S . 005 to 100%.Butane 2 4 6 8 Time (min) 10 12 14 All compounds measured by FID 34 n . Typical Chromatogram Methane Ethane Propane n . plus a vaporization zone for proper liquid sample injection Only hydrocarbons detected and measured.Pentane C6+ .Pentane i . liquid. no degradation from common contaminants Model 3062 Software available containing template for heating value calculation and other sample specifications This analyzer is for natural gas. a secondary filter and back pressure regulation for proper liquid sample introduction. no interference from air or CO2 Designed so that the lowest boiling C6 (2.Butane i . D-6623. Natural gas does not contain light hydrocarbon unsaturates. C6+ .2-dimethylbutane) is included in the backflush.0. pressurized liquid Compounds separated: C1 through C5.Natural Gas Analyzer Model 2200 Analyzer Description Published methods met: ASTM D1945 (precision statement only) Types of sample analyzed: Gas. See Model 4036 or Model 4037. C6+ composite Guaranteed detection ranges/concentration levels: All components except C6+ .005 to 10% Application note reference number with technical details: D-6622. LPG samples can not be analyzed on this analyzer without modification. which meets ASTM D2163 methodology for LPG analysis. Rugged packed columns. D-6652 Major Features and Benefits • • • • • • • Added liquid-sampling capability to Model 2000 Includes sample-loop purge feature that prevents contamination when changing sample types.0. H2S.1 to 25%. pressurized liquid Compounds separated: O2. a secondary filter and back pressure regulation for proper liquid sample introduction.Butane 0 2 4 6 8 Time (min) 10 12 35 n .01 to 20%.Pentane 14 i .Pentane CO2 H2S . LPG samples can not be analyzed on this analyzer without modification. liquid.2-dimethylbutane) is included in the backflush. ISO 6568. GPA 2261. C1 through C5 . See Model 4036 or Model 4037. H2S . C6+ composite . DIN 51872-5 Types of sample analyzed: Gas. Typical Chromatogram Methane Ethane O2/N2 Propane C6+ n . GPA 2177. CO2.01 to 100%. D-6624. no degradation from common contaminants Model 3062 Software available containing template for heating value calculation and other sample specifications Plumbed in sulfur-resistant materials to enhance H2S detection This analyzer is for natural gas. C6+ composite Guaranteed detection ranges/concentration levels: O2. N2 composite and CO2 – 0. Rugged packed columns.Natural Gas Analyzer Model 2201 Analyzer Description Published methods met: ASTM D1945. C1 through C5. D-6652 Major Features and Benefits • • • • • • • • • Added liquid-sampling capability to Model 2001 Includes sample-loop purge feature that prevents contamination when changing sample types. which meets ASTM D2163 methodology for LPG analysis.0. plus a vaporization zone for proper liquid sample injection Single channel/single TCD No separation and measurement of O2 and N2 individually Designed so that the lowest boiling C6 (2.0. Natural gas does not contain light hydrocarbon unsaturates. N2 composite. ISO 6974-5.Butane i .01 to 10% Application note reference number with technical details: D-6622.0. DIN 51872-5 Types of sample analyzed: Gas.0. H2S.0.01 to 4%. plus a vaporization zone for proper liquid sample injection No separation and measurement of O2 and N2 individually Designed so that the lowest boiling C6 (2. LPG samples can not be analyzed on this analyzer without modification. C1 through C5. C6+ composite Guaranteed detection ranges/concentration levels: Ar – 0.2-dimethylbutane) is included in the backflush. all other components .Natural Gas Analyzer Model 2202 Analyzer Description Published methods met: ASTM D1945.Pentane C6+ H2S Argon 10 Time (min) 36 CO2 20 Ethane .Butane n .01 to 100%.01 to 10%.0. Rugged packed columns. H2S . Application note reference number with technical details: D-6622. which meets ASTM D2163 methodology for LPG analysis. a secondary filter and back pressure regulation for proper liquid sample introduction. CO2. See Model 4036 or Model 4037. liquid. Typical Chromatogram O2 / N2 Propane Methane n . ISO 6974-5. D-6652 Major Features and Benefits • • • • • • • • • • Baseline separation of O2. Natural gas does not contain light hydrocarbon unsaturates. GPA 2261. C6+ composite .Butane i . N2 composite and methane. argon measurement Added liquid-sampling capability to Model 2002 Single channel/single thermal conductivity detector (TCD) Includes sample-loop purge feature that prevents contamination when changing sample types. D-6625.1 to 5%. pressurized liquid Compounds separated: Ar. no degradation from common contaminants Model 3062 Software available containing template for heating value calculation and other sample specifications Plumbed in sulfur-resistant materials to enhance H2S detection This analyzer is for natural gas. O2.Pentane i . N2 composite. 2-dimethylbutane) is included in the backflush.0. Natural gas does not contain light hydrocarbon unsaturates.0.0. H2S . LPG samples can not be analyzed on this analyzer without modification. C6+ composite Guaranteed detection ranges/concentration levels: O2 and C6+ composite . which meets ASTM D2163 methodology for LPG analysis. C1 through C5. See Model 4036 or Model 4037.Natural Gas Analyzer Model 2203 Analyzer Description Published methods met: ASTM D1945. DIN 51872-5 Types of sample analyzed: Gas. CO2.01 to 20%. H2S. N2. GPA 2261.01 to 100%. pressurized liquid Compounds separated: O2. Rugged packed columns. a secondary filter and back pressure regulation for proper liquid sample introduction. D-6626. ASTM D1946. N2 – 0.01 to 10%. liquid. plus a vaporization zone for proper liquid sample injection Designed so that the lowest boiling C6 (2. D-6652 Major Features and Benefits • • • • • • • • • Single channel/single thermal conductivity detector (TCD) Separation and measurement of O2 and N2 individually Added liquid-sampling capability to Model 2003 Includes sample-loop purge feature that prevents contamination when changing sample types. Typical Chromatogram Nitrogen C6+ Propane n-Butane Ethane i-Butane n-Pentane i-Pentane H 2S 2 4 6 8 Time (min) 10 CO2 12 Oxygen 14 37 Methane . no degradation from common contaminants Model 3062 Software available containing template for heating value calculation and other sample specifications Plumbed in sulfur-resistant materials to enhance H2S detection This analyzer is for natural gas. Application note reference number with technical details: D-6622. CO2 and C1 through C5 .1 to 5%. Pentane i . C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2. Channel two (FID): C4 to C10 . which meets ASTM D2163 methodology for LPG analysis.0. N2 composite and CO2 – 0.2-dimethylbutane) is included in the backflush on TCD channel.01 to 100%. extended hydrocarbon analysis to C10 Model 3062 Software available containing template for heating value calculation and other sample specifications Plumbed in sulfur-resistant materials to enhance H2S detection This analyzer is for natural gas. C1 through C10. C6+ composite . D-6627.TCD 38 Channel two . CO2. pressurized liquid Compounds separated: O2.01 to 10%.Butane n . a secondary filter and back pressure regulation for proper liquid sample introduction. H2S . D-6652 Major Features and Benefits • • • • • • • • • • Capillary channel added to Model 2001 Added liquid sampling capability to Model 2006 Dual channel/thermal conductivity detector (TCD). See Model 4036 or Model 4037.FID Decane n-Butylbenzene Propane C6+ H2S Butanes . Natural gas does not contain light hydrocarbon unsaturates. liquid. H2S.1 to 25%.Pentane CO2 0 2 4 6 8 Time (min) 10 12 14 10 Time (min) 20 Channel one . N2 composite. LPG samples can not be analyzed on this analyzer without modification. C1 through C5 .01 to 20%.0.Natural Gas Analyzer Model 2206 Analyzer Description Published methods met: None Types of sample analyzed: Gas.0. plus a vaporization zone for proper liquid sample injection No separation and measurement of O2 and N2 individually Designed so that the lowest boiling C6 (2.005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622.0. flame ionization detector (FID) Includes sample-loop purge feature that prevents contamination when changing sample types.Butane i . Typical Chromatograms Methane Pentanes O2/N2 Ethane Octane p-Xylene Hexane Heptane n-Propylbenzene n . Packed and capillary columns. CO2 and C1 through C5 . Typical Chromatograms Nitrogen Methane Hexane Heptane Pentanes Octane p-Xylene n-Propylbenzene Propane Ethane n-Butane Oxygen i-Butane n-Pentane i-Pentane H2S CO2 2 4 6 8 Time (min) 10 12 14 10 Time (min) 20 Channel one .0.01 to 20%. D-6652 Major Features and Benefits • • • • • • • • • • Capillary channel added to Model 2003 Added liquid-sampling capability to Model 2008 Dual channel/thermal conductivity detector (TCD). H2S . a secondary filter and back pressure regulation for proper liquid sample introduction. CO2.1 to 5%. N2. GPA 2165. ISO 6975 Types of sample analyzed: Gas. liquid. LPG samples can not be analyzed on this analyzer without modification. pressurized liquid Compounds separated: O2. flame ionization detector (FID) Includes sample-loop purge feature that prevents contamination when changing sample types. D-6628. C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2 and C6+ composite 0. See Model 4036 or Model 4037. plus a vaporization zone for proper liquid sample injection Separation and measurement of O2 and N2 individually Designed so that the lowest boiling C6 (2.Natural Gas Analyzer Model 2208 Analyzer Description Published methods met: ASTM D1946. Natural gas does not contain light hydrocarbon unsaturates. Packed and capillary columns.01 to 100% Channel two (FID): C4 to C10 . which meets ASTM D2163 methodology for LPG analysis. extended hydrocarbon analysis to C10 Model 3062 Software available containing template for heating value calculation and other sample specifications Plumbed in sulfur-resistant materials to enhance H2S detection This analyzer is for natural gas.TCD 39 Channel two . C1 through C10. GPA 2286. GPA 2186.0.FID Decane n-Butylbenzene C6+ Butanes .0.01 to 10%. H2S. IP 345. N2 – 0.005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622.2-dimethylbutane) is included in the backflush on TCD channel. a secondary filter and back pressure regulation for proper liquid sample introduction. CO2 and C1 through C4 .0.005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622.0. flame ionization detector (FID) Includes sample-loop purge feature that prevents contamination when changing sample types.0. extended hydrocarbon analysis to C10 Model 3062 Software available containing template for heating value calculation and other sample specifications Plumbed in sulfur-resistant materials to enhance H2S detection This analyzer is for natural gas. C1 through C10 Guaranteed detection ranges/concentration levels: Channel one (TCD): O2 . which meets ASTM D2163 methodology for LPG analysis.1 to 5%.Natural Gas Analyzer Model 2209 Analyzer Description Published methods met: ASTM D1946. CO2. LPG samples can not be analyzed on this analyzer without modification. liquid. ISO 6975 Types of sample analyzed: Gas. D-6652 Major Features and Benefits • • • • • • • • • “Fast Model 2008” – C4 + compounds backflushed to vent on TCD channel Added liquid-sampling capability to Model 2009 Dual channel/thermal conductivity detector (TCD).FID 40 Decane n-Butylbenzene Butanes . H2S. IP 345. H2S .01 to 100% Channel two (FID): C4 to C10 .01 to 10%. plus a vaporization zone for proper liquid sample injection Separation and measurement of O2 and N2 individually Packed and capillary columns.0. GPA 2286. Natural gas does not contain light hydrocarbon unsaturates. See Model 4036 or Model 4037. D-6629. N2.01 to 20%. pressurized liquid Compounds separated: O2. N2 – 0. Typical Chromatograms Pentanes p-Xylene Octane Hexane Heptane n-Propylbenzene 10 Time (min) 20 Channel one – TCD Channel two . N2 composite. N2 composite and CO2 – 0.0. CO2. C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2.01 to 100%. liquid. D-6652 Major Features and Benefits • • • • • • • • • • Model 2201 with C6+ backflush to FID channel (no water interference. which meets ASTM D2163 methodology for LPG analysis. See Model 4036 or Model 4037.0. ISO 6974-5 Types of sample analyzed: Gas. Channel two (FID): C6+ composite . Natural gas does not contain light hydrocarbon unsaturates. H2S . a secondary filter and back pressure regulation for proper liquid sample introduction.01 to 20%. no degradation from common contaminants Model 3062 Software available containing template for heating value calculation and other sample specifications Plumbed in sulfur-resistant materials to enhance H2S detection This analyzer is for natural gas. D-6630.001 to 100% Application note reference number with technical details: D-6622. H2S.0. C1 through C5. LPG samples can not be analyzed on this analyzer without modification. C1 through C5 .Natural Gas Analyzer Model 2210 Analyzer Description Published methods met: ASTM D1945. flame ionization detector (FID) Includes sample-loop purge feature that prevents contamination when changing sample types. pressurized liquid Compounds separated: O2. better sensitivity) Added liquid-sampling capability to Model 2010 Dual channel/thermal conductivity detector (TCD). plus a vaporization zone for proper liquid sample injection No separation and measurement of O2 and N2 individually Designed so that the lowest boiling C6 (2.1 to 25%. Typical Chromatogram TCD channel – C6+ backflushed to FID 41 .2-dimethylbutane) is included in the backflush. GPA 2261. Rugged packed columns. liquid. D-6652 Major Features and Benefits • • • • • • • • • Full-range hydrogen detection using separate channel with nitrogen carrier gas Added liquid-sampling capability on FID channel of Model 2100 Includes sample-loop purge feature that prevents contamination when changing sample types.2-dimethylbutane) is included in the backflush. Typical Chromatogram H2 measured by TCD and the remaining compounds measured by FID 42 . H2. C6+ . plus a vaporization zone for proper liquid sample injection Dual channel/thermal conductivity detector. pressurized liquid Compounds separated: He. H2 – 0. flame ionization detector (TCD/FID) Hydrocarbons detected and measured. Rugged packed columns. C6+ composite Guaranteed detection ranges/concentration levels: He.01 to 100%. all other components except C6+ .005 to 100%. which meets ASTM D2163 methodology for LPG analysis. no degradation from common contaminants Model 3062 Software included containing template for heating value calculation and other sample specifications.Natural Gas Analyzer Model 2300 Analyzer Description Published methods met: ASTM D1945 (precision statement only) Types of sample analyzed: Gas. C1 through C5.0. See Model 4036 or Model 4037. Natural gas does not contain light hydrocarbon unsaturates. D-6651. LPG samples can not be analyzed on this analyzer without modification.005 to 10% Application note reference number with technical details: D-6622.0. a secondary filter and back pressure regulation for proper liquid sample introduction. no interference from air or CO2 Designed so that the lowest boiling C6 (2. plus merge and custom report formatting This analyzer is for natural gas. D-6623. H2S. H2. ISO 6974-5. O2. pressurized liquid Compounds separated: He. LPG samples can not be analyzed on this analyzer without modification. H2. CO2. which meets ASTM D2163 methodology for LPG analysis.01 to 10% Application note reference number with technical details: D-6622. liquid. plus a vaporization zone for proper liquid sample injection Dual channel/dual thermal conductivity detector (TCD/TCD) No separation and measurement of O2 and N2 individually Designed so that the lowest boiling C6 (2. C1 through C5.0. N2 composite and CO2 – 0.2-dimethylbutane) is included in the backflush. GPA 2261. C1 through C5 . D-6652 Major Features and Benefits • • • • • • • • • • Full-range hydrogen detection using separate channel with nitrogen carrier gas Added liquid-sampling capability to Model 2101 Includes sample-loop purge feature that prevents contamination when changing sample types. GPA 2177.1 to 25%. a secondary filter and back pressure regulation for proper liquid sample introduction. Rugged packed columns. DIN 51872-5 Types of sample analyzed: Gas.01 to 100%.0. O2.Natural Gas Analyzer Model 2301 Analyzer Description Published methods met: ASTM D1945. H2S .0. See Model 4036 or Model 4037. N2 composite. D-6624. C6+ composite .01 to 20%. Typical Chromatogram H2 measured in one TCD utilizing a nitrogen carrier gas and the remaining compounds measured in a second TCD utilizing a helium carrier gas. D-6651. 43 . C6+ composite Guaranteed detection ranges/concentration levels: He. ISO 6568. Natural gas does not contain light hydrocarbon unsaturates. no degradation from common contaminants Model 3062 Software available containing template for heating value calculation and other sample specifications Plumbed in sulfur-resistant materials to enhance H2S detection This analyzer is for natural gas. pressurized liquid Compounds separated: He. a secondary filter and back pressure regulation for proper liquid sample introduction.1 to 5%. Typical Chromatogram H2 measured in one TCD utilizing a nitrogen carrier gas and the remaining compounds measured in a second TCD utilizing a helium carrier gas. argon measurement Full-range hydrogen detection using separate channel with nitrogen carrier gas Added liquid-sampling capability to Model 2102 Dual channel/dual thermal conductivity detector (TCD/TCD) Includes sample-loop purge feature that prevents contamination when changing sample types.0. C6+ composite . plus a vaporization zone for proper liquid sample injection No separation and measurement of O2 and N2 individually Designed so that the lowest boiling C6 (2. D-6652 Major Features and Benefits • • • • • • • • • • • Baseline separation of O2. Ar. C1 through C5. See Model 4036 or Model 4037. N2 composite. N2 composite and methane. Natural gas does not contain light hydrocarbon unsaturates. 44 . H2S . CO2.01 to 100%. ISO 6974-5.01 to 10%. no degradation from common contaminants Model 3062 Software available containing template for heating value calculation and other sample specifications Plumbed in sulfur-resistant materials to enhance H2S detection This analyzer is for natural gas. DIN 51872-5 Types of sample analyzed: Gas. H2S.0. O2.Natural Gas Analyzer Model 2302 Analyzer Description Published methods met: ASTM D1945. Application note reference number with technical details: D-6622.2-dimethylbutane) is included in the backflush. liquid. LPG samples can not be analyzed on this analyzer without modification.01 to 4%.0. all other components . which meets ASTM D2163 methodology for LPG analysis. Rugged packed columns. H2. D-6651. D-6625. C6+ composite Guaranteed detection ranges/concentration levels: Ar – 0. GPA 2261. Natural Gas Analyzer Model 2303 Analyzer Description Published methods met: ASTM D1945, ASTM D1946, GPA 2261, DIN 51872-5 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: He; H2; O2; N2; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: O2 and C6+ composite - 0.01 to 10%; N2 – 0.01 to 20%; H2S - 0.1 to 5%; He, H2, CO2 and C1 through C5 - 0.01 to 100%, Application note reference number with technical details: D-6622, D-6626, D-6651, D-6652 Major Features and Benefits • • • • • • • • • • Full-range hydrogen detection using separate channel with nitrogen carrier gas Dual channel/dual thermal conductivity detector (TCD/TCD) Added liquid-sampling capability to Model 2103 Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid sample introduction, plus a vaporization zone for proper liquid sample injection Separation and measurement of O2 and N2 individually Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. Rugged packed columns, no degradation from common contaminants Model 3062 Software available containing template for heating value calculation and other sample specifications Plumbed in sulfur-resistant materials to enhance H2S detection This analyzer is for natural gas. Natural gas does not contain light hydrocarbon unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis. Typical Chromatogram H2 measured in one TCD utilizing a nitrogen carrier gas and the remaining compounds measured in a second TCD utilizing a helium carrier gas. 45 Natural Gas Analyzer Model 2306 Analyzer Description Published methods met: None Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: He; H2; O2, N2 composite; CO2; H2S; C1 through C10; C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2, N2 composite and CO2 – 0.01 to 20%; He, H2, C1 through C5 - 0.01 to 100%; H2S - 0.1 to 25%; C6+ composite 0.01 to 10%; Channel two (FID): C4 to C10 - 0.005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622, D-6627, D-6651, D-6652 Major Features and Benefits • • • • • • • • • • • Capillary channel added to Model 2301 Added liquid-sampling capability to Model 2106 Full-range hydrogen detection using separate channel with nitrogen carrier gas Three channel (TCD/TCD/FID) Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid sample introduction, plus a vaporization zone for proper liquid sample injection No separation and measurement of O2 and N2 individually Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush on TCD channel. Packed and capillary columns, extended hydrocarbon analysis to C10 Model 3062 Software available containing template for heating value calculation Plumbed in sulfur-resistant materials to enhance H2S detection This analyzer is for natural gas. Natural gas does not contain light hydrocarbon unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis. Typical Chromatograms Heptane Hexane Pentanes p-Xylene Octane n-Propylbenzene 10 Time (min) 20 Channel one and two – TCD/TCD 46 Channel three - FID Decane n-Butylbenzene Butanes Natural Gas Analyzer Model 2310 Analyzer Description Published methods met: ASTM D1945, GPA 2261, ISO 6974-5 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: He; H2; O2, N2 composite; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2, N2 composite and CO2 – 0.01 to 20%; He, H2, C1 through C5 - 0.01 to 100%; H2S - 0.1 to 25% Channel two (FID): C6+ composite - 0.001 to 100% Application note reference number with technical details: D-6622, D-6630, D-6651, D-6652 Major Features and Benefits • • • • • • • • • • • Model 2301 with C6+ backflush to FID channel (no water interference, better sensitivity) Added liquid-sampling capability to Model 2110 Full-range hydrogen detection using separate channel with nitrogen carrier gas Three channel (TCD/TCD/FID) Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid sample introduction, plus a vaporization zone for proper liquid sample injection No separation and measurement of O2 and N2 individually Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. Rugged packed columns, no degradation from common contaminants Model 3062 Software available containing template for heating value calculation and other sample specifications Plumbed in sulfur-resistant materials to enhance H2S detection This analyzer is for natural gas. Natural gas does not contain light hydrocarbon unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis. Typical Chromatogram He, H2 measured by TCD using Nitrogen carrier gas. C6+ backflushed to FID, all other compounds measured using TCD using Helium carrier gas. 47 Simulated Distillation Software Simulat and Software Enhancements Model 3012 Model 3013 Model 3062 Simulated Distillation Software . disk or screen Typical Chromatogram and Report 130 120 110 100 90 80 70 60 50 40 30 20 10 Chromatogram of Reference Gas Oil (RGO) standard for ASTM D2887 ASTM D2887 report for the RGO sample 49 . depending upon method Application note reference number with technical details: D-6631 Major Features and Benefits • • • • • • • • • Runs with PerkinElmer TotalChrom and Turbochrom Workstation or Client Server software Up to eight Sim Dis analyzers per each software license Step-by-step instruction manual Long and short reporting formats Cut point reports Setup templates for each Sim Dis Method Auto sequence multiple methods Batch reprocessing Reports to printer. ASTM D3710.Simulated Distillation Software Model 3012 Software Description Published methods met: ASTM D2887. ASTM D5307 Types of sample analyzed: Liquid Compounds analyzed: C4 through C110. if supplied Sample interpreted Sample run at on-site installation by PerkinElmer Typical Chromatogram and Report 130 120 110 100 90 80 70 60 50 40 30 20 10 Chromatogram of Reference Gas Oil (RGO) standard for ASTM D2887 ASTM D2887 report for the RGO sample 50 .Simulated Distillation Software Model 3013 Analyzer Description Published methods met: ASTM D2887. using Model 3012 Software Customer purchases total system specified for their desired methodology Sampling procedure and report format developed Chromatographic parameters established for the method Column identified Operating conditions identified Calibration material chosen Calibration and actual customer sample run. ASTM D3710. ASTM D5307 Types of sample analyzed: Liquid Compounds analyzed: C4 through C110. depending upon method Application note reference number with technical details: D-6631 Major Features and Benefits • • • • • • • • • • Model 3013 includes method development. rst Proc Method: C:\USERPROG\tc6DEMO\NGA\CAP.32 19.seq Inst Method: C:\TC4\1METHOD\2306F from c:\userprog\tc6demo\nga\pack.01228 0.491 324.01192 16.41 3 2.283 .0436 0.76 19.00275 0.45144 0.03848 0.rst Proc Method: C:\USERPROG\tc6DEMO\NGA\PACKED.99 81.03848 0.00493 0.00072 0.00185 0.1342 0.01984 0.03553 0.00407 0. Taylor Instrument: TABLE_2_________(2B) Compressibility: 0.00619 0.15 Specific Gravity (R 0.8 0 53.0276 0.178 0.05001 0.1 3269.00176 0.064 0.2376 0.9753 4758 0.52 0.2-dimethylButane 5 3.00994 0.03075 0.21 50.00027 0.85 0.9 0.mth Channel:A Raw Data File: c:\userprog\tc6demo\nga\cap.03002 0.96 32.0382 1.02021 0.1825 0.5 0.00493 0.25 0 0 824.96 32.00026 0.00078 0.01011 0.02029 0.0917 0.01 0.0202 0.9 2523 3260.0696 1 1.00117 0.0067 2.0202 0.00989 0.00478 0.00114 1012 1772.01011 0.mth Calib Method: C:\USERPROG\tc6DEMO\NGA\PACKED.49 0.00989 0.03849 0.2377 Time: 08/07/98 12:05:42 PM Study: Default Sequence Data Acquisition Time: 06/06/97 01:50:24 PM B B B B B B B B B B B A A A Hydrogen Air Argon Methane CO2 Ethane Propane i-Butane n-Butane i-Pentane n-Pentane i-Pentane n-Pentane 2.00256 1.26 0.48 0.rst Channel:B Raw Data File: c:\userprog\tc6demo\nga\pack.raw Result File: c:\userprog\tc6demo\nga\cap.64715 1061.3792 0.01372 0.00479 0.5224 2.00271 0.03001 0.00348 0.02 1.81524 0.5194 1.03116 0.6484 Sequence File: C:\Userprog\Tc6demo\Nga\Nga32.00028 0.49 0.00761 0.00995 0.99 0.Software Enhancements Model 3062 Software Description Published methods met: ASTM D3588 Types of sample analyzed: All Application note reference number with technical details: D-6632 Major Features and Benefits • Combine two Turbochrom or TotalChrom reports into a single report • Full computational power of Excel™ • Full reporting power of Excel • Translation of report into local language • Automatic output to paper and/or computer file path • Typical uses include Natural gas computations using the supplied template and multiple detector analyzers report merge • Changing the Turbochrom or TotalChrom report to match a company format • Special calculations based upon measured concentrations • Examples supplied include two detector-bridged Natural Gas Analyzer heat calculation and Refinery Gas Analyzer two-integrator channel merge Typical Heating Calculation Report Sample Name: 3062 Demo Operator: M.mth Calib Method: C:\USERPROG\tc6DEMO\NGA\CAP.04895 2.05 0.22 Compressibilty Rleative Density Calorific Value Compressibility Fraction Btu/ft3 sqr rt (b) 0.6 4009.48 0.63 Heat (Dry): 1064.65 51 12.16 0.00256 1 0.81502 0.mth A/B Component Name Mol % Mol Fraction Mol FractioSpecific GrCalorific Fraction Bridged Normalizedfraction 0.00408 0.5539 1.9977 Heat (Saturated): 1045.4 4018.491 2.0067 2.raw Result File: c:\userprog\tc6demo\nga\pack. Trace Sulfur Analyzers S Trace Model 4025 Model 4026 Model 4027 Model 4028 Model 4029 Model 4227 Model 4229 Model 4425 Model 4428 Model 4429 Model 4629 Trace Sulfur Analyzers . aromatic sulfur compounds. and Kraft gas Uses a Sievers Sulfur Chemiluminescence Detector (SCD) The SCD has an equimolar response to sulfur compounds. SO2. lack of carbon interference and requires simple calibration Capillary column solution Can be modified with a second or third channel to perform additional analyses Can be modified to analyze liquid and pressurized liquid samples (Model 4028) Can be designed to be on-line and/or a multistream system Typical Chromatogram COS H2 S SO2 Methylmercaptan 53 t-Butylmercaptan Ethylmercaptan Dimethylsulfide Propylmercaptan . ASTM D5623. COS. ASTM D6021 Types of sample analyzed: Gas Compounds separated: H2S. mercaptans. natural gas. process gas.Trace Sulfur Components Analyzer Model 4025 Analyzer Description Published methods met: ASTM D5504. sulfides Guaranteed detection levels: less than 10 ppb Application note reference number with technical details: D-6643 Major Features and Benefits • • • • • • • Analyzes samples such as refinery gas. Trace Sulfur Components Analyzer Model 4026 Analyzer Description Published methods met: ASTM D5504. sulfides Guaranteed detection levels: less than 10 ppb Application note reference number with technical details: D-6643 Major Features and Benefits • • • • • • • Analyzes samples such as LPG. ASTM D6021 Types of sample analyzed: Liquid. lack of carbon interference and requires simple calibration Capillary column solution Can be modified with a second or third channel to perform additional analyzes Can be modified to analyze gas samples (Model 4028) Can be designed to be on-line and/or a multistream system Typical Chromatogram COS H2 S SO2 Methylmercaptan 54 t-Butylmercaptan Ethylmercaptan Dimethylsulfide Propylmercaptan . SO2. COS. ASTM D5623. naphtha. mercaptans. aromatic sulfur compounds. pressurized liquid (valve injection) Compounds separated: H2S. gasoline and other liquid petroleum products Uses a Sievers Sulfur Chemiluminescence Detector (SCD) The SCD has an equimolar response to sulfur compounds. COS. aromatic sulfur compounds. ASTM D6021 Types of sample analyzed: Liquid (syringe injection) Compounds separated: H2S. gasoline and other liquid petroleum products that can be syringe injected Uses a Sievers Sulfur Chemiluminescence Detector (SCD) The SCD has an equimolar response to sulfur compounds. lack of carbon interference and requires simple calibration Capillary column solution Can be modified with a second or third channel to perform additional analyses Can be modified to analyze gas samples (Model 4029) Can be designed to be on-line and/or a multistream system Typical Chromatogram COS H2 S SO2 Methylmercaptan 55 t-Butylmercaptan Ethylmercaptan Dimethylsulfide Propylmercaptan . mercaptans. sulfides Guaranteed detection levels: less than 10 ppb Application note reference number with technical details: D-6643 Major Features and Benefits • • • • • • • Analyzes samples such as naphtha. SO2. ASTM D5623.Trace Sulfur Components Analyzer Model 4027 Analyzer Description Published methods met: ASTM D5504. Trace Sulfur Components Analyzer Model 4028 Analyzer Description Published methods met: ASTM D5504. ASTM D6021 Types of sample analyzed: Gas. COS. LPG. aromatic sulfur compounds. natural gas. SO2. naphtha. ASTM D5623. lack of carbon interference and requires simple calibration Dual-capillary column solution Can be modified with a second or third channel to perform additional analyzes Can be designed to be on-line and/or a multistream system Typical Chromatogram COS H2 S SO2 Methylmercaptan 56 t-Butylmercaptan Ethylmercaptan Dimethylsulfide Propylmercaptan . pressurized liquid Compounds separated: H2S. liquid. mercaptans. Kraft gas. sulfides Guaranteed detection levels: less than 10 ppb Application note reference number with technical details: D-6643 Major Features and Benefits • • • • • • Analyzes samples such as refinery gas. process gas. gasoline and other gaseous and liquid petroleum products Uses a Sievers Sulfur Chemiluminescence Detector (SCD) The SCD has an equimolar response to sulfur compounds. gasoline and other liquid petroleum products that can be syringe injected Uses a Sievers Sulfur Chemiluminescence Detector (SCD) The SCD has an equimolar response to sulfur compounds. liquid Compounds separated: H2S. ASTM D5623. sulfides Guaranteed detection levels: less than 10 ppb Application note reference number with technical details: D-6643 Major Features and Benefits • • • • • • • Analyzes samples such as refinery gas. mercaptans. COS. ASTM D6021 Types of sample analyzed: Gas. aromatic sulfur compounds. process gas. naphtha. Kraft gas. lack of carbon interference and requires simple calibration Dual-capillary column solution Can be modified with a second or third channel to perform additional analyses Can be modified to analyze pressurized liquid samples by adding a liquid sampling valve (Model 4229) Can be designed to be on-line and/or a multistream system Typical Chromatogram COS H 2S SO2 Methylmercaptan 57 t-Butylmercaptan Ethylmercaptan Dimethylsulfide Propylmercaptan . SO2. natural gas.Trace Sulfur Components Analyzer Model 4029 Analyzer Description Published methods met: ASTM D5504. ASTM D6021 Types of sample analyzed: Liquid (syringe injection). lack of carbon interference and requires simple calibration Includes a secondary filter and back-pressure regulation for proper liquid sample introduction Capillary column solution Can be modified to analyze gas samples (Model 4229) Can be designed to be on-line and/or a multistream system Typical Chromatogram COS H2S SO2 Methylmercaptan 58 t-Butylmercaptan Ethylmercaptan Dimethylsulfide Propylmercaptan . liquid and pressurized liquid (valve injection Compounds separated: H2S. aromatic sulfur compounds. COS. gasoline and other liquid petroleum products that can be syringe injected Uses a Sievers Sulfur Chemiluminescence Detector (SCD) The SCD has an equimolar response to sulfur compounds. mercaptans. SO2. sulfides Guaranteed detection levels: less than 10 ppb Application note reference number with technical details: D-6643 Major Features and Benefits • • • • • • • Analyzes samples like naphtha. ASTM D5623.Trace Sulfur Components Analyzer Model 4227 Analyzer Description Published methods met: ASTM D5504. lack of carbon interference and requires simple calibration Includes a secondary filter and back-pressure regulation for proper liquid sample introduction. SO2. sulfides Guaranteed detection levels: less than 10 ppb Application note reference number with technical details: D-6643. ASTM D6021 Types of sample analyzed: Gas. Kraft gas. mercaptans. pressurized liquid Compounds separated: H2S. COS. natural gas. gasoline and other liquid petroleum products Uses a Sievers Sulfur Chemiluminescence Detector (SCD). liquid. The SCD has an equimolar response to sulfur compounds. ASTM D5623. naphtha.Trace Sulfur Components Analyzer Model 4229 Analyzer Description Published methods met: ASTM D5504. aromatic sulfur compounds. D-6652 Major Features and Benefits • • Analyzes samples like refinery gas. process gas. LPG. plus a vaporization zone for proper liquid sample injection Dual-capillary column solution Can be modified with a second or third channel to perform additional analyses Can be designed to be on-line and/or a multistream system • • • • Typical Chromatogram COS H2S SO2 Methylmercaptan 59 t-Butylmercaptan Ethylmercaptan Dimethylsulfide Propylmercaptan . against an NBS traceable calibrator for accuracy Chamber Schematic 60 . SO2.Trace Sulfur Components Analyzer Models 4425. 4428. COS. 4429 and 4629 Analyzer Description Published methods met: ASTM D5504. 4028. sulfides Guaranteed detection levels: less than 10 ppb Application note reference number with technical details: D-6643 Major Features and Benefits • • • • • • • Adds an integrated permeation tube chamber for calibration option to Trace Sulfur Components Analyzer Models 4025. mercaptans. 4029 and 4229 Saves both space and cost Mounts on top of the analyzer for easy access Manual valve is used to select the calibration chamber or the sample input Permeation tube chamber can accommodate up to four permeation tubes or wafers for calibration of other non sulfur compounds Includes certified dimethyl-sulfide permeation tube Permeation tube shipped with the product is tested with the analyzer. ASTM D5623. ASTM D6021 Types of sample analyzed: Gas Compounds separated: H2S. aromatic sulfur compounds. Other Analyzers Analyzers for Light Gas. Chlorine. Transformer Oil Gas. LPG and Simulated Distillation through Detailed Hydrocarbon Analyses Model 4001 Model 4002 Model 4003 Model 4081 Model 4004 Model 4005 Model 4006 Model 4007 Model 4008 Model 4009 Model 4010 Model 4011 Model 4012 Model 4013 Model 4014 Model 4015 Model 4016 Model 4017 Model 4018 Model 4019 Model 4020 Model 4021 Model 4022 Model 4023 Model 4024 Model 4032 Model 4033 Model 4034 Model 4035 Model 4036 Model 4037 Model 4080 Model 4082 Model 4083 Model 4086 Other Analyzers . 4008). refer to Model 4013 (ASTM D3606) or Model 4006 (ASTM D4420). isopropanol. n-butanol. tert-butanol.1 to 12% Application note reference number with technical details: D-6633 Major Features and Benefits • • • • • Guaranteed to meet the scope of ASTM D4815-99 methodology Fully automated Low cost of operation Available with thermal conductivity detector (Model 4001) or flame ionization detector (Model 4002) The determination of benzene. ETBE. TAME. heavy hydrocarbons Guaranteed detection ranges/concentration levels: MTBE.1 to 20%. ETBE. To analyze benzene. ethanol. secbutanol. DIPE. separated by this valve/column system. DIPE. is not qualified by this method. isobutanol. all other components – 0.Standard Method (ASTM D4815) Analyzers Model 4001/4002 Analyzer Description Published methods met: ASTM D4815-99 Types of sample analyzed: liquid Compounds separated: Methanol. TAME – 0. 4010 or 4007. benzene. tert-pentanol. MTBE. Model 4013 or Model 4006 can be incorporated as a second channel in the Model 4001/4002 (see Models 4009. n-propanol. Typical Chromatogram 62 . CO. C2H4. CO2. O2. CH4. Method C Purged sampling valve housing on Model 4003 Analyzer Passivated tubing for optimum CO response Injection port and gas sampling valve for various sample introductions High capacity methanizer Typical Chromatogram Carbon Dioxide Ethylene Ethane Nitrogen Methane Hydrogen 63 Carbon Monoxide Acetylene Oxygen . C2H2 2. N2 – 500 ppm Application note reference number with technical details: D-6634 Major Features and Benefits • • • • • • • Model 4081 Transformer Oil Gas Extraction Apparatus and Model 4003 Analyzer meets the scope of ASTM D3612-01. Method A Dual detector (TCD/FID) Model 4003 can be connected to a Headspace Sampler to meet ASTM D3612-01.0 ppm. C2H6.Transformer Oil Gas Analyzer Model 4003/4081 Analyzer Description Published methods met: ASTM D3612-01 Types of sample analyzed: Gas Compounds separated: H2. O2. C4s – 3.0 ppm. C2H6. CO. C3s. C2H2. H2 – 50 ppm. N2. C3 and C4 hydrocarbons Guaranteed detection ranges/concentration levels: CO2. CH4.0 ppm. C2H4 – 1. toluene. as required. n-butanol. isopropanol. total C9 and heavier aromatics – 5 to 30%. only the FID performing ASTM D4815 is appropriate for this analyzer See Models 4002 and 4005 for more details • • • Typical Chromatograms ASTM D4815 analysis ASTM D5580 analysis 1 ASTM D5580 analysis 2 64 . npropanol. isobutanol. DIPE. individual C8 aromatics – 0. For this reason and since the same column system is utilized for both methods. TAME. all other components – 0. p/m-xylene.1 to 5%. as well as the benzene. ethylbenzene and other aromatics. ETBE. tert-butanol.1 to 20%. DIPE. ethanol. D-6635 Major Features and Benefits • Analyzer has the capability to determine the ether and alcohol additives (see Model 4001/4002). MTBE. tert-pentanol. o-xylene. TAME – 0.1 to 12%. sec-butanol. C9 and heavier aromatics. total aromatics – 10 to 80% Application note reference number with technical details: D-6633. (ASTM D5580): Benzene. ASTM D5580 Types of sample analyzed: Finished gasoline Compounds separated: (ASTM D4815): Methanol. heavy hydrocarbons. toluene. ethylbenzene. (ASTM D5580): (all v%) Benzene – 0.Standard Method (ASTM D4815/D5580) Analyzer Model 4004 Analyzer Description Published methods met: ASTM D4815. toluene – 1 to 15%.5 to 10%. benzene. ETBE. total aromatics Guaranteed detection ranges/concentration levels: (ASTM D4815): MTBE. (see Model 4005) in gasoline The same column system is utilized for both methods ASTM D5580 requires a flame ionization detector (FID). o-xylene. p/m-xylene. ethylbenzene and o-xylene separate The C9 and heavier aromatics are measured as a single group Two separate analyses are performed. total aromatics Guaranteed detection ranges/concentration levels: (all v%) Benzene – 0. total aromatics – 10 to 80% Application note reference number with technical details: D-6635 Major Features and Benefits • • • • • Aromatic hydrocarbons are separated without interferences from other hydrocarbons in the sample Nonaromatic hydrocarbons having a boiling point greater than n-dodecane may cause interferences with the C9 and heavier aromatics For the C8 aromatics. Alcohols and ethers added to gasoline do not interfere with the analysis • Typical Chromatogram Analysis 1 Analysis 2 65 . total C9 and heavier aromatics – 5 to 30%.5 to 10%. the quantitation of ethylbenzene.Standard Method (ASTM D5580) Analyzer Model 4005 Analyzer Description Published methods met: ASTM D5580 Types of sample analyzed: Finished Gasoline Compounds separated: Benzene.1 to 5%. toluene – 1 to 15%. o-xylene. and the C9 and heavier aromatics. The results are summed to determine total aromatic content. toluene. p/m-xylene. C9 and heavier aromatics. The second. ethylbenzene. The first. p-xylene and m-xylene coelute. the quantitation of benzene and toluene. individual C8 aromatics – 0. After C8 aromatics have eluted. the aromatics are backflushed from column one to column two. Before benzene elutes. • • Typical Chromatogram 66 . toluene.Standard Method (ASTM D4420) Analyzer Model 4006 Analyzer Description Published methods met: ASTM D4420 Types of sample analyzed: Finished Gasoline Compounds separated: Benzene. performing another method or application. total aromatics Guaranteed detection ranges/concentration levels: Benzene . C8. C9 and heavier aromatics – 5 to 30V%.1 to 5V%. The column oven temperature requirement of the second channel cannot operate above the maximum temperature allowed by Model 4006 (200 oC). C8 aromatics – 3 to 25V%. Sample results are compared to the analysis of a blend of known aromatic content. total aromatics – 10 to 80V% Application note reference number with technical details: D-6636 Major Features and Benefits • A sample is injected by syringe into a two column/valve system. C9 and heavier aromatics.0. Nonaromatics are vented as they elute column one. A knowledge of aromatics in gasolines is needed to access sample results This single channel analyzer can have a second channel added. toluene – 1 to 20V%. column two is backflushed to the TCD to obtain the C9 and heavier aromatics. Aromatics elute from column two to the thermal conductivity detector (TCD) in boiling point order. D-6636 Major Features and Benefits • Analyzer has the capability to determine the ether and alcohol additives (see Model 4001/4002).1 to 20%. toluene. npropanol. ethanol. (see Model 4006) in gasoline Two separate column systems are utilized for these methods See Models 4001/4002 and 4006 for more details • • Typical Chromatograms ASTM D4815 analysis ASTM D4420 analysis 67 . total aromatics – 10 to 80V% Application note reference number with technical details: D-6633. isopropanol. as well as the benzene. ASTM D4420 Types of sample analyzed: Finished gasoline Compounds separated: (ASTM D4815): Methanol. tert-butanol. DIPE.1 to 5V%. as required. ETBE.Standard Method (ASTM D4815/D4420) Analyzer Model 4007/4008 Analyzer Description Published methods met: ASTM D4815. MTBE. sec-butanol. benzene. toluene. isobutanol. heavy hydrocarbons. C8 and other heavier aromatics. total aromatics Guaranteed detection ranges/concentration levels: (ASTM D4815): MTBE. tert-pentanol. C8. ethylbenzene. TAME – 0. C8 aromatics – 3 to 25V%. n-butanol. (ASTM D4420): Benzene.0. C9 and heavier aromatics – 5 to 30V%. all other components – 0. ETBE. C9 and heavier aromatics. toluene – 1 to 20V%. TAME. (ASTM D4420): Benzene .1 to 12%. DIPE. tert-butanol. (ASTM D3606): Benzene. ethanol. TAME – 0. as required. sec-butanol. (ASTM D3606): Benzene . npropanol. ASTM D3606 Types of sample analyzed: Finished gasoline Compounds separated: (ASTM D4815): Methanol. heavy hydrocarbons. toluene – 2 to 20V% Application note reference number with technical details: D-6633.1 to 12%. as well as the benzene and toluene. (see Model 4013) in gasoline Two separate column systems are utilized for these methods See Models 4001/4002 and 4013 for more details • • Typical Chromatograms ASTM D4815 analysis ASTM D3606 analysis 68 . D-6637 Major Features and Benefits • Analyzer has the capability to determine the ether and alcohol additives (see Model 4001/4002). tert-pentanol.Standard Method (ASTM D4815/D3606) Analyzer Model 4009/4010 Analyzer Description Published methods met: ASTM D4815. n-butanol. all other components – 0. isobutanol. DIPE. isopropanol.1 to 20%. DIPE.0. ETBE. ETBE. MTBE. TAME. benzene.1 to 5V%. toluene Guaranteed detection ranges/concentration levels: (ASTM D4815): MTBE. (ASTM D3606-EPA modified): Benzene. sec-butanol. all other components – 0. heavy hydrocarbons. MTBE. DIPE. (see Model 4014) in gasoline EPA modification of ASTM D3606 adds additional column for enhanced benzene – ethanol (if present) separation.0. D-6637 Major Features and Benefits • Analyzer has the capability to determine the ether and alcohol additives (see Model 4001/4002). n-butanol. as required.1 to 5V%. isobutanol.Standard Method (ASTM D4815/D3606EPA modified) Analyzer Model 4011/4012 Analyzer Description Published methods met: ASTM D4815. as well as the benzene and toluene. ETBE. DIPE. ETBE. tert-butanol. Two separate column systems are utilized for these methods See Models 4001/4002 and 4014 for more details • • • Typical Chromatograms ASTM D4815 analysis ASTM D3606 (EPA modified) analysis 69 . ethanol. toluene – 2 to 20V% Application note reference number with technical details: D-6633. toluene Guaranteed detection ranges/concentration levels: (ASTM D4815): MTBE. benzene. TAME – 0.1 to 20%. ASTM D3606 (EPA modification) Types of sample analyzed: Finished gasoline Compounds separated: (ASTM D4815): Methanol. isopropanol. TAME. npropanol. All other specifications and method intent remain unchanged.1 to 12%. (ASTM D3606-EPA modified): Benzene . tert-pentanol. Standard Method (ASTM D3606) Analyzer Model 4013 Analyzer Description Published methods met: ASTM D3606 Types of sample analyzed: Finished Motor and Aviation Gasoline Compounds separated: Benzene, toluene Guaranteed detection ranges/concentration levels: Benzene – 0.1 to 5V%, toluene – 2 to 20V% Application note reference number with technical details: D-6637 Major Features and Benefits • A sample, containing methyl ethyl ketone (MEK) as an internal standard, is injected by syringe into two columns in series. The first column separates components by boiling point. After octane elutes from column one into column two, carrier flow is reversed in column one. Hydrocarbons heavier than octane are vented. Column two then separates the octane and lighter components. Aromatic and nonaromatic compounds are measured with reference to the MEK by thermal conductivity detector (TCD). Knowledge of benzene concentration may be an aid in evaluating the toxicity of the gasoline being analyzed. This method is not intended to evaluate that toxicity, however. This single-channel analyzer can have a second channel added, performing another method or application. The column oven temperature requirement of the second channel cannot operate above the maximum temperature allowed by Model 4013 (120 oC). • • Typical Chromatogram 70 Standard Method (ASTM D3606-EPA modified) Analyzer Model 4014 Analyzer Description Published methods met: ASTM D3606 (EPA modification) Types of sample analyzed: Finished Motor and Aviation Gasoline Compounds separated: Benzene, toluene Guaranteed detection ranges/concentration levels: Benzene – 0.1 to 5V%, toluene – 2 to 20V% Application note reference number with technical details: D-6637 Major Features and Benefits • • • EPA modification of ASTM D3606 adds additional column for enhanced benzene – ethanol (if present) separation All other specifications and method intent remain unchanged. See Model 4013 for details This single channel analyzer can have a second channel added, performing another method or application. The column oven temperature requirement of the second channel cannot operate above the maximum temperature allowed by Model 4014 (120 oC). Typical Chromatogram 71 Detailed Hydrocarbon Analyzer Model 4015 Analyzer Description Published methods met: ASTM D5443, ASTM D6623, ASTM D6730, ASTM D6733 Types of sample analyzed: liquid Compounds separated: Paraffins, Isoparaffins, Naphthenes, Olefins, Aromatics and Oxygenates (reported by carbon number) through C13 Guaranteed detection ranges/concentration levels: All components – 10 ppm Application note reference number with technical details: D-6638 Major Features and Benefits • • • • • Detailed analysis of gasolines, naphthas and similar samples that boil below 250 oC Software is mated to capillary-column output to obtain detailed hydrocarbon characteristics Reports include individual components, key boiling point data, oxygenates and oxygen content and multisubstituted aromatics Calculated values include percent carbon and hydrogen, vapor pressure, average molecular weight and density by carbon number, octane rating and bromine number Key separated compounds include methylcyclopentene-1/benzene; 2,3,3trimethylpentane/toluene and 1,4-dimethylbenzene (p-xylene)/2,3-dimethylheptane Page One of Typical Report Detailed Hydrocarbon Analysis (DHAX) Neil G. Johansen, Inc. Raw File: 0928001002.raw Sample: Method: DHA Initial Gasoline.mth Processed 445 peaks Analyzed: 28 Sep 1999 01:33PM Reported: 01 Oct 1999 02:32PM DHA DBase File: 5987A.csv Normalized to 100.00% Summary Report Group Type: Paraffins: I-paraffins: Olefins: Naphthenes: Aromatics: Total C14+: Total Unknowns: Grand Total Oxygenates: Total: Total Oxygen Content: Multisubstituted Aromatics: Average Molecular Weight: Relative Density: Total (mass%) 9.471 30.320 8.131 9.807 24.981 0.436 1.384 100.000 15.471 (mass%) 2.808 (mass%) 18.161 (mass%) 80.291 0.609 3.42 (psi @ 100°F) Total (vol%) 10.564 33.370 8.733 9.439 20.917 0.421 1.171 100.000 15.385 (vol%) 15.313 (vol%) Vapor Pressure calc RVP (EPA method): Calculated Octane Number: 87.08 72 N2. mine gases Packed columns/single thermal conductivity detector (TCD) Often used as one channel of an analyzer – very versatile Some common added channels are: .Light Gas Analyzer Model 4016 Analyzer Description Published methods met: ASTM D1946 Types of sample analyzed: Gas Compounds separated: Ar . CO.Flame ionization detector (FID) for better hydrocarbon detection .01 to 100% Major Features and Benefits • • • • Typical analyses are light gases. CO2. CH4. H2S Guaranteed detection ranges/concentration levels: H2S – 0.02 to 100%. combustion gases. Ethylene. furnace gases. Acetylene. decoking gases. all other components – 0.O2 composite. Ethane. stack gases.Flame photometric detector (FPD) or a Sievers Sulfur Chemiluminescence Detector (SCD) for trace levels of the light sulfur gases Typical Chromatogram 73 .Methanizer/FID and purged-valve housings for trace CO and CO2 analysis . all other components – 0. CH4. Acetylene. mine gases Full-range hydrogen detection using separate channel with nitrogen carrier gas added to Model 4016 Packed columns/dual Arnel thermal conductivity detector (TCD/TCD) Arnel dual TCD allows analyzer to have an added third channel Some common added channels are: .Light Gas Analyzer Model 4017 Analyzer Description Published methods met: ASTM D1946 Types of sample analyzed: Gas Compounds separated: He.01 to 100% Major Features and Benefits • • • • • Typical analyses are light gases. Ar . CO2. stack gases. Ethylene. N2. Ethane. CO. H2.Flame ionization detector (FID) for better hydrocarbon detection .02 to 100%. combustion gases. H2S Guaranteed detection ranges/concentration levels: H2S – 0.O2 composite. decoking gases.Methanizer/FID and purged valve housings for trace CO and CO2 analysis . furnace gases.Flame photometric detector (FPD) or a Sievers Sulfur Chemiluminescence Detector (SCD) for trace levels of the light sulfur gases Typical Chromatogram Nitrogen Hydrogen Ethylene Acetylene CO2 Ethane H2S Oxygen Methane 74 CO . 02 to 100%.01 to 100% Application note reference number with technical details: D-6639 Major Features and Benefits • Typical analyses are light gases. all other components – 0. CH4. CO. Ethylene. Ethane. mine gases Packed columns/dual thermal conductivity detector (TCD/TCD) Third channel added to Model 4016 for Ar – O2 separation and measurement • • Typical Chromatograms Nitrogen Channel one – TCD Channel two .Light Gas Analyzer Model 4018 Analyzer Description Published methods met: ASTM D1946 Types of sample analyzed: Gas Compounds separated: Ar. O2.TCD 75 Oxygen Argon 13 Minutes . N2. stack gases. H2S Guaranteed detection ranges/concentration levels: H2S – 0. decoking gases. furnace gases. CO2. combustion gases. Acetylene. CO2. mine gases Packed columns/dual Arnel thermal conductivity detector and PerkinElmer thermal conductivity detector (TCD/TCD/TCD) Third channel added to Model 4017 for Ar – O2 separation and measurement Arnel dual TCD allows analyzer to have added third channel Typical Chromatograms Nitrogen Hydrogen Oxygen Nitrogen Oxygen Methane CO Channel one and two – TCD/TCD Acetylene Channel three . H2.TCD 76 Argon 13 Minutes Ethylene CO2 Ethane H2S .Light Gas Analyzer Model 4019 Analyzer Description Published methods met: ASTM D1946 Types of sample analyzed: Gas Compounds separated: He.01 to 100% Application note reference number with technical details: D-6639 Major Features and Benefits • • • • Typical analyses are light gases. Ethane. CO. Acetylene. Ethylene. H2S Guaranteed detection ranges/concentration levels: H2S – 0. O2. decoking gases. CH4. combustion gases. stack gases. all other components – 0. Ar. furnace gases. N2.02 to 100%. H2.Light Gases in Chlorine Model 4020 Analyzer Description Published methods met: ASTM E1746 Types of sample analyzed: Gas Compounds separated: He.001 to 100%.0. H2 . O2. N2. CH4. CO2.01 to 100% Application note reference number with technical details: D-6640 Major Features and Benefits • • • • • All tubing and valves in contact with the samples are constructed of chlorine-resistant material Dual packed column channels/dual thermal conductivity detector (TCD/TCD) An important feature is the use of proprietary packing materials as the first column in both channels Samples containing water do not interfere with the analysis or create hardware problems Chlorine is backflushed to vent and does not enter the detector Typical Chromatogram 77 . CO Guaranteed detection ranges/concentration levels: He. all other components .. CH4.Trace CO. CH4 and CO2 Analyzer Model 4021 Analyzer Description Published methods met: ASTM D3416. ethylene – ethane composite. ISO 6381 Types of sample analyzed: Gas Compounds separated: CO.1 ppm Application note reference number with technical details: D-6641 Major Features and Benefits • • • • • • Single channel/methanizer/flame ionization detector (FID) One valve and one column Can handle large methane concentrations Acetylene elutes after ethylene – trace acetylene can not be analyzed in large quantities of ethylene Purged valve housings and passivated tubing are used to enhance sensitivity In practical use. CO2. the sample must be free of oxygen Typical Chromatogram Carbon Monoxide Methane Carbon Dioxide 78 8 Minutes . acetylene Guaranteed detection ranges/concentration levels: All components – 0. CH4 and CO2 Analyzer Model 4022 Analyzer Description Published methods met: ASTM D3416.Trace CO. ISO 6381 Types of sample analyzed: Gas Compounds separated: CO. CO2. CO2. acetylene Guaranteed detection ranges/concentration levels: All components – 0. ethane. ethylene. CH4. CO. CH4 can be analyzed in large quantities of ethylene Purged valve housings and passivated tubing are used to enhance sensitivity In practical use. the sample must be free of oxygen Typical Chromatogram Carbon Dioxide Methane Carbon Monoxide Ethylene 4 Minutes Acetylene 79 Ethane .1 ppm Application note reference number with technical details: D-6641 Major Features and Benefits • • • • • • Single channel/methanizer/flame ionization detector (FID) One valve and one column Can not handle large methane concentrations Acetylene elutes before ethylene – trace acetylene. as well as trace CO and CO2 analysis in liquefied light hydrocarbon gases The output of the Apparatus is connected directly to the analyzer to insure no air will be added to the expanded sample The Apparatus includes a metering valve for the sample flow.Liquid Sample Expansion Apparatus Model 4023 Analyzer Description Published methods met: ASTM D2712 Types of sample analyzed: Pressurized liquid Compounds separated: N/A Guaranteed detection ranges/concentration levels: N/A Application note reference number with technical details: D-6642 Major Features and Benefits • • • • • • Compliments analyzers for a fully tested complete system or sold as a stand-alone product If purchased with an analyzer. a metering valve for calibration gases. it will be additionally tested using an actual sample supplied by the customer or supplied by Arnel Designed to vaporize liquefied light hydrocarbons such as propylene Incorporates design improvements to meet the requirements for trace hydrocarbons. if introduced into the product Product Schematic 80 . which relieves a high-pressure (above 500 psi) sample to vent. a clear plastic graduated cylinder for use as a manometer and a burst disk located in the “liquid sample in” system. 5 ppm Application note reference number with technical details: D-6641 Major Features and Benefits • • • • • • Single channel/methanizer/flame ionization detector (FID) Valving and columns meet UOP 603 methodology Can handle large methane concentrations Does not include any C2 analysis (Acetylene and ethylene coelute off of the primary column) Purged valve housings and passivated tubing are used to enhance sensitivity In practical use. CO2. CH4 and CO2 Analyzer Model 4024 Analyzer Description Published methods met: UOP 603 Types of sample analyzed: Gas Compounds separated: CO. CH4 Guaranteed detection ranges/concentration levels: All components – 0.Trace CO. the sample must be free of oxygen Typical Chromatogram Carbon Monoxide Carbon Dinoxide 81 Methane . O2. O2. N2. He.Full Range H2. however. Information on the complete sample matrix is required to determine true detection and measurement ranges. in some cases. Model 4033. ASTM D1946 Types of sample analyzed: Gas Compounds separated: Model 4032. Better detection and measurement than 10 ppm can be achieved. Model 4034 is a dual-channel. thermal conductivity detector analyzers. dual-thermal conductivity detector analyzer. Some limitations are present. H2.He. with certain combinations of compound levels present.He. with modification. Model 4034. Model 4032 and 4033 have the ability to be combined with other application channels for cost savings • Typical Chromatogram Model 4032 and Model 4034 analysis one Model 4033 and Model 4034 analysis two 82 . O2 and N2 Analysis Model 4032/4033/4034 Analyzer Description Published methods met: ASTM D1945. N2 Guaranteed detection ranges/concentration levels: All components – 10 ppm to 100% Application note reference number with technical details: D-6645 Major Features and Benefits • • • Rugged and simple packed-column technology Models 4032 and 4033 are single channel. H2. Two very good applications are for propylene/butylenes manufacturing and analysis of butane streams.1 ppm Application note reference number with technical details: D-6663 Major Features and Benefits • • • • • • • Used to analyze a wide range of gaseous light hydrocarbon samples such as LPG Fully automatic operation All hydrocarbons from methane to hexane are analyzed. H2S). ASTM D4424. which are free of compounds that irreversibly poison the Alumina PLOT column (NH3. ISO 7941 Types of sample analyzed: Gas Compounds separated: All hydrocarbons from methane through hexane Guaranteed detection ranges/concentration levels: All components . ASTM D2712. This analyzer cannot be used for all samples. ASTM D2820. External valve oven design allows for full range temperature programming for column reconditioning (removing CO2 and H2O) The valve oven assures that no sample condensation occurs in the sample loop Possible to add second channel for another application Typical Chromatogram 83 . Complete separations of all possible compounds are obtained in approximately 20 minutes.Light Hydrocarbon Analyzer Model 4035 Analyzer Description Published methods met: ASTM D2163. The analysis usually includes a column temperature program. ASTM D2593.0. Light Hydrocarbon Analyzer Model 4036 Analyzer Description Published methods met: ASTM D2163. ASTM D2820. Complete separations of all possible compounds are obtained in approximately 20 minutes. which are free of compounds that irreversibly poison the Alumina PLOT column (NH3. The analysis usually includes a column temperature program. ASTM D2712. H2S). pressurized liquid Compounds separated: All hydrocarbons from methane through hexane Guaranteed detection ranges/concentration levels: All components .1 ppm Application note reference number with technical details: D-6663 Major Features and Benefits • • • • • • • Used to analyze a wide range of liquid light hydrocarbon samples such as LPG Fully automatic operation All hydrocarbons from methane to hexane are analyzed. Liquid sampling valve mounted at ambient temperature allows for full range temperature programming for column reconditioning (removing CO2 and H2O) Includes a secondary filter and back pressure regulation for proper liquid sample introduction. ISO 7941 Types of sample analyzed: Liquid. ASTM D2593. plus a vaporization zone for proper liquid sample injection Possible to add second channel for another application Typical Chromatogram 84 . This analyzer cannot be used for all samples. Two very good applications are for propylene/butylenes manufacturing and analysis of butane streams. ASTM D4424.0. H2S). Liquid sampling valve mounted at ambient temperature and external valve oven design for the gas sampling valve allows for full range temperature programming for column reconditioning (removing CO2 and H2O) Includes a secondary filter and back-pressure regulation for proper liquid sample introduction. pressurized liquid Compounds separated: All hydrocarbons from methane through hexane Guaranteed detection ranges/concentration levels: All components . plus a vaporization zone for proper liquid sample injection Typical Chromatogram 85 . This analyzer cannot be used for all samples.1 ppm Application note reference number with technical details: D-6663 Major Features and Benefits • • • • • • Analyzes a wide range of gaseous and liquid light hydrocarbon samples such as LPG Fully automatic operation All hydrocarbons from methane to hexane are analyzed. liquid. ASTM D2593.0. ASTM D4424. Complete separations of all possible compounds are obtained in approximately 20 minutes. Two very good applications are for propylene/butylenes manufacturing and analysis of butane streams. ASTM D2820.Light Hydrocarbon Analyzer Model 4037 Analyzer Description Published methods met: ASTM D2163. ISO 7941 Types of sample analyzed: Gas. which are free of compounds that irreversibly poison the Alumina PLOT column (NH3. The analysis usually includes a column temperature program. ASTM D2712. ethanol.17% to 15 % (m/m). it is possible to determine any oxygenate or aromatic found in petrol. individual organic oxygenate compounds .05 to 6 % (V/V). MTBE.7% (m/m) Application note reference number with technical details: D-6647 Major Features and Benefits • • • • Pressure switched (PreVent). Typical Chromatogram Petrol with heartcuts i-Butyl-methyl-ketone MTBE Toluene Benzene Measured MTBE. “heartcut” instrument configuration The analyzer features a capillary injection port. oxygenates Guaranteed detection ranges/concentration levels: Benzene . aromatics. benzene 86 .0. PreVent and three capillary columns (a liquid-sampling valve can also be used) Total flexibility .0.up to 3. total organically bound oxygen . The same sample can be run twice with different “heartcut” times. EN 13132. IP 425/96 Types of sample analyzed: Unleaded petrol (gasoline) with a boiling point not to exceed 220 oC Compounds separated: Benzene.Choosing the correct internal standard and varying the “heartcut” times. By spreading the components into two analyses.Benzene and Oxygenates Analyzer Model 4080 Analyzer Description Published methods met: EN 12177. the interferences found with a large number of components are eliminated. Upon minimizing the vaporization (bubbles) of the sample and obtaining a desired liquid flow rate. Gently close the valve at the top of the sight glass until the bubbles stop. open the toggle valve and the backpressure valve to vent the remaining liquid. This will provide a slight backpressure in order to prevent the vaporizing of the liquid sample. Once the run has commenced. Schematic of Mounted Model 4082 87 . close the toggle valve to stop the flow and make your injection. without sample vaporization before sample injection This product is normally sold as an “add on” to liquid sampling valved analyzers OPERATION OF THE MODEL 4082: Connect the filtered sample to the sample inlet and start the liquid flow.Liquid Sampling Apparatus Model 4082 Analyzer Description Published methods met: UOP 911 Types of sample analyzed: Pressurized liquid Compounds separated: N/A Guaranteed detection ranges/concentration levels: N/A Application note reference number with technical details: None Major Features and Benefits • • • Apparatus is designed to introduce pressurized liquid samples precisely. There may be bubbles passing through the sight glass. fittings. Ar. O2. this analyzer may not be appropriate for your samples Extreme care must be taken in providing sample to the analyzer. nitrogen. CH4 and CO in Light Hydrocarbons Analyzer Model 4083 Analyzer Description Published methods met: ASTM D2504 Types of sample analyzed: Gas Compounds separated: Hydrogen. N2. carbon monoxide Guaranteed detection ranges/concentration levels: CO – 100 ppb. The analyzer includes a carrier gas purifier to ensure carrier gas quality Can be combined with other applications or a second channel of trace level analysis Typical Chromatogram 88 . all other components – 50 ppb Application note reference number with technical details: D-6648 Major Features and Benefits • • • • • • Trace level detection and measurement of components by Discharge Ionization Detector (DID) To maximize performance. Sample connections and carrier gas connections to the analyzer must be leak free. If any of the target compounds are in % level concentrations in your sample. Key components are located in a carrier gas purged enclosure. tubing and columns are designed to be inert and leak tight. methane.Trace H2. oxygen /argon coelution. all features of the system’s valving. 5 V ppm to 1V%. all other components – 1 V ppm to 1V% Application note reference number with technical details: None Major Features and Benefits • • • • Split/splitless injector. Capillary PLOT silica main column for separation of oxygenated compounds • Typical Chromatogram 89 . others Guaranteed detection ranges/concentration levels: Acetaldehyde. methanol – 0. MTBE. dual capillary column. MTBE. 2-propanol. The use of a precolumn and backflushing keeps high boiling material from contaminating the main column. PreVent and flame ionization detector (FID) An autosampler should be included for precision Optional gas-sampling or liquid-sampling valves can be added Capillary non-polar precolumn for separation of light non-polar compounds and backflushing heavies. Backflushing of the precolumn is provided by PreVent hardware and a mid-point pressure switch time programmed from the Clarus Interface or TotalChrom. acetone. methanol.Trace Methanol and MTBE in Liquid Hydrocarbons Analyzer Model 4086 Analyzer Description Published methods met: None Types of sample analyzed: Liquid Compounds separated: Acetaldehyde. general testing and environmental . Systems and Accessories are available for other industries such as pharmaceutical.arnelinc.com) and the Arnel Inc. Many other standard and custom Analyzers.com) for other products. 90 . Examples of other guaranteed products are: • • • Model 4438 and 4046 Trace Impurities in Beverage CO2 Analyzers Series 5100 Acetaldehyde in PET Bottles Analyzer Series 5200 Workspace Air Quality Monitor Explore both the PerkinElmer web site (www. food & beverage.com for more details. plus contact your local PerkinElmer sales engineer or email Arnel at info@arnelinc. web site (www. and specialty gases for QC. literature and a quotation.perkinelmer.occupational safety monitoring applications.Related Industries Also Benefit The dedicated and guaranteed PerkinElmer Arnel Analyzers and Systems in this booklet specifically address the petrochemical laboratory and process industry. 006808_02 KG060303 Printed in USA . PerkinElmer is a registered trademark of PerkinElmer. CT 06484-4794 USA Phone: 800-762-4000 or (+1) 203-925-4602 www. All rights reserved. pictorial or typographical errors.PerkinElmer Life and Analytical Sciences 710 Bridgeport Avenue Shelton. Arnel is a trademark of Arnel Inc. PerkinElmer reserves the right to change this document at any time and disclaims liability for editorial.com © 2003 PerkinElmer. Inc.perkinelmer. Inc.