SAFETY DATA SHEETPRODUCT Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16, for Emergency Telephone Numbers. 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING PRODUCT NAME : Tri-ACT® 1800 APPLICATION : BOILER STEAM CONDENSATE TREATMENT COMPANY IDENTIFICATION : NALCO EUROPE B.V. Postbus 627 2300 AP Leiden, The Netherlands EMERGENCY TELEPHONE NUMBER(S) : See section 16, for Emergency Telephone Numbers. Date issued : Version Number : 06.10.2010 5.0 COMPANY CONTACT TELEPHONE NUMBERS. NALCO EUROPE B.V. NALCO AB (SE) +31 71 5241 100 +46 (0)31-707 22 70 NALCO NORGE AS (NO) Distributor Nalco Mobotec Polska Sp. z o.o. NALCO ANADOLU KIMYA (TR) NALCO APPLIED SERVICES OF EUROPE BV NALCO BELGIUM BVBA NALCO DANMARK ApS NALCO DEUTSCHLAND GmbH (D) NALCO ESPAÑOLA S.L. (E) +90 216 5743464 +31 (0)73 6456980 NALCO PORTUGUESA LDA. (P) NTD S.r.l (IT) +32 (0)3-450 69 10 +45-48195800 +49 (0)69-79340 Nalco Switzerland AG (CH) Nalco Company OOO NALCO ÖSTERREICH Ges.m.b.H. (A) First Distributor: Nalco Czechia s.r.o. (CZ) +34 93-4095555 NALCO FINLAND OY (FI) +358 (0)9 2519 5600 NALCO FRANCE SAS +33 (0)3 20 11 70 00 NALCO HELLAS S.A. (GR) +30 210 238 9620 NALCO ITALIANA S.R.L.(I) NALCO NETHERLANDS B.V. +39 06-54565000 +31 (0)13-5952200 Local Support: Nalco Hungary Kft. (HU) Local Support: Nalco Österreich Ges.m.b.H., Representation Office Predstavnistvo Zagreb (HR) Local Support: Nalco Österreich Ges.m.b.H. Representation Office ROMANIA (RO) NALCO LIMITED +47 51 96 36 00 PRZEMYS ŁOWA 55 PL-43-110 TYCHY TEL:+48 (0)32-3262750 FAX: +48(0)32 329 13 11 e-mail: [email protected] +351 214121852 +39 (0) 313351325 +41 (0)52 235 38 38 +7 (0)495 980 72 80 + 43(0)1 27026350 Hlavní 1222/60,141 00 Praha 4,Czech Republic,+420 267 912 350 & +420 272 913 512 +36 1 8805610 +385 (0)1 377 95 21 +40 (0) 21 224 17 93 +44 (0)1606 74488 For Product Safety information please contact Jacqueline Dudley, e-mail [email protected] 2. HAZARDS IDENTIFICATION HAZARD CLASSIFICATION : This product is classified as dangerous in accordance with the Preparations Directive 1999/45/EC. Causes burns. May cause sensitization by skin contact. Harmful in contact with skin and if swallowed. Possible risk of impaired fertility. HUMAN HEALTH HAZARDS - ACUTE : NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www.nalco.com and request access 1 / 15 R62 R20/21/22. SKIN CONTACT : May cause severe irritation or tissue damage depending on the length of exposure and the type of first aid administered. Exposure to low vapor concentrations can result in foggy or blurred vision. FIRST AID MEASURES INHALATION : Remove to fresh air. R43. COMPOSITION/INFORMATION ON INGREDIENTS This product is classified as dangerous in accordance with the Preparations Directive 1999/45/EC.com and request access 2 / 15 . in high concentrations. R22. R34. throat and lungs. INHALATION : Irritating. nausea and vomiting. to the eyes.< 20 Refer to Section 16 for descriptions of relevant risk phrases and Notas. INGESTION : DO NOT INDUCE VOMITING. Wash off affected area immediately with plenty of water. Remove contaminated clothing.< 20 10 .SAFETY DATA SHEET PRODUCT Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16. Hazardous Substance(s) CAS NO SYMBOL Cyclohexylamine EINECS / ELINCS NO 203-629-0 108-91-8 C Monoethanolamine Methoxypropylamine 205-483-3 226-241-3 141-43-5 5332-73-0 C C R-PHRASES / NOTAS R10. 3. R52 % (w/w) 5 . May cause sensitization by skin contact. nose. Will cause eye burns and permanent tissue damage. washout mouth and give water to drink. If conscious. shoes. Harmful if swallowed. R35. EYE CONTACT : PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Get immediate medical attention. 4. HUMAN HEALTH HAZARDS . Contaminated clothing. EYE CONTACT : Corrosive. Immediately flush eye with water for at least 15 minutes while holding eyelids open. R21/22. R34 R10. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www. flood body under a shower. Get immediate medical attention. Get medical attention. throat and stomach.CHRONIC : Possible risk of impaired fertility. and leather goods must be discarded or cleaned before re-use.nalco. INGESTION : Not a likely route of exposure. causes chemical burns to the mouth.< 10 10 . treat symptomatically. NOTE TO PHYSICIAN : NALCO EUROPE B. objects appearing bluish and appearance of a halo around lights. These symptoms are temporary. Vapors may have a strong offensive odor which may cause sensory response including headache. For a large splash.V. SKIN CONTACT : Immediately flush with plenty of water for at least 15 minutes. Harmful if absorbed through skin. Corrosive. Get immediate medical attention. for Emergency Telephone Numbers. Wash affected area. 6. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). may release vapors that form flammable mixtures at or above the flash point. weld.) readily available. HANDLING AND STORAGE HANDLING : Do not get in eyes. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations). ENVIRONMENTAL PRECAUTIONS : Do not contaminate surface water.nalco. spills. Store separately from acids. Do not take internally. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS : Restrict access to area as appropriate until clean-up operations are complete. LARGE SPILLS: Contain liquid using absorbent material.com and request access 3 / 15 . For large fires. Water mist may be used to cool closed containers. NALCO EUROPE B. May evolve oxides of carbon (COx) under fire conditions. Keep away from acids and oxidizing agents. Amine and sulphite products should not be stored within close proximity or resulting vapors may form visible airborne particles.SAFETY DATA SHEET PRODUCT Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16. STORAGE CONDITIONS : Store the containers tightly closed. or expose containers to flame or other sources of ignition. Do not breathe vapors/gases/dust. Dry powder. Stop or reduce any leaks if it is safe to do so. Other extinguishing agent suitable for Class B fires. spill or pour near heat. Have emergency equipment (for fires. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www. wear a full face positive-pressure self contained breathing apparatus and protective suit. thoroughly drenching the burning material. Use with adequate ventilation. Do not touch spilled material. Reclaim into recovery or salvage drums or tank truck for proper disposal. FIRE AND EXPLOSION HAZARD : Flammable Liquid. sparks or open flame. FIRE FIGHTING MEASURES FLASH POINT : 57 °C PMCC EXTINGUISHING MEDIA : Foam. METHODS FOR CLEANING UP : SMALL SPILLS: Soak up spill with absorbent material. on skin. by digging trenches or by diking. store. etc. Store away from heat and sources of ignition. Do not use. on clothing. Carbon dioxide. leaks. Empty product containers may contain product residue. Use proper grounding procedures. Based on the individual reactions of the patient. occupational health and safety and environmental authorities. Have emergency equipment (for fires. cut. Ventilate spill area if possible. 5. covered. properly labeled container. Store separately from oxidizers. leaks.V. Avoid generating aerosols and mists. Remove sources of ignition.) readily available. Keep the containers closed when not in use. the physician's judgement should be used to control symptoms and clinical condition. Clean contaminated surfaces with water or aqueous cleaning agents. Contact an approved waste hauler for disposal of contaminated recovered material. May evolve oxides of nitrogen (NOx) under fire conditions. Ensure clean-up is conducted by trained personnel only. Notify appropriate government. use water spray or fog. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING : In case of fire. Do not pressurize. Probable mucosal damage may contraindicate the use of gastric lavage. for Emergency Telephone Numbers. spills. 7. heat. etc. Place residues in a suitable. SAFETY DATA SHEET PRODUCT Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16. Natural rubber.nalco. Epoxyresin coating SPECIFIC USE(S) : BOILER STEAM CONDENSATE TREATMENT For specific dosages and customized applications please contact your representative. 8. Compatibility with Plastic Materials can vary. PTFE. Country/Source AUSTRIA BELGIUM BULGARIA DENMARK Substance(s) Cyclohexylamine Category: MAK MAK CEIL Skin* ppm 10 10 mg/m3 40 40 Monoethanolamine MAK MAK STEL Skin* 1 3 2.6 Cyclohexylamine TWA 20 Monoethanolamine TWA STEL 8 15 Cyclohexylamine GV Skin* GV Skin* Monoethanolamine FINLAND FRANCE 10 40 10 GV Skin* GV Skin* 1 2.5 Cyclohexylamine HTP 8H HTP 15MIN Skin* 1 10 4.6 Cyclohexylamine VME Skin* 10 40 1 NALCO EUROPE B.com and request access 4 / 15 . Polypropylene.1 41 Monoethanolamine HTP 8H HTP 15MIN Skin* 1 3 2. Perfluoroelastomer. Surface-modified HDPE (high density polyethylene). Fluoroelastomer. for Emergency Telephone Numbers. we therefore recommend that compatibility is tested prior to use. SUITABLE CONSTRUCTION MATERIAL : HDPE (high density polyethylene).5 7. Stainless Steel 316L.6 Cyclohexylamine TWA 10 42 Monoethanolamine TWA STEL Skin* 1 3 2. EXPOSURE CONTROLS/PERSONAL PROTECTION OCCUPATIONAL EXPOSURE LIMITS Exposure guidelines have not been established for this product. Stainless Steel 304.V.5 7. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www. Available exposure limits for the substance(s) are shown below.5 7. UNSUITABLE CONSTRUCTION MATERIAL : Carbon Steel C1018. for Emergency Telephone Numbers.5 7.2 Monoethanolamine AGW Skin* 2 5.6 NETHERLANDS Monoethanolamine TGG TGG 15 Skin* NORWAY Cyclohexylamine ADM.5 7.5 Cyclohexylamine NGV KTV 5 10 20 40 Monoethanolamine NGV KTV Skin* 3 6 8 15 Cyclohexylamine TWA STEL Skin* 2 4 8.nalco.6 NALCO EUROPE B. NORM Skin* 10 40 Monoethanolamine ADM.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www.5 Cyclohexylamine ÁK CK 40 40 GERMANY IRELAND SPAIN SWEDEN SWITZERLAND UNITED KINGDOM POLAND HUNGARY 2.5 7.2 16. Monoethanolamine VME VLE Skin* 1 3 2.1 Cyclohexylamine TWA Skin* 10 40 Monoethanolamine TWA STEL 3 6 8 15 ITALY Monoethanolamine TWA STEL Skin* 1 3 2.4 Monoethanolamine TWA STEL 2 4 5 10 Cyclohexylamine TWA 10 41 Monoethanolamine TWA STEL Skin* 1 3 2.6 Cyclohexylamine MAK 2 8.5 7.5 7. NORM Skin* 3 1 8 2. NORM ADM.6 Cyclohexylamine MAC-NDS MAC-NDSC h 40 80 Monoethanolamine MAC-NDS MAC-NDSC h 2.com and request access 5 / 15 .5 7.5 Cyclohexylamine VLA-ED 10 41 Monoethanolamine VLA-ED VLA-EC Skin* 1 3 2.SAFETY DATA SHEET PRODUCT Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16. 5 7.) CEIL 1 Monoethanolamine (Vapor and aerosol. including mucous membranes and the eyes.com and request access 6 / 15 .) CEIL 0.5 7. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www.5 Cyclohexylamine MAC Skin* 10 40 Monoethanolamine MAC Skin* 3 8 Cyclohexylamine TWA CEILING 2 8.5 Cyclohexylamine GVI 10 41 Monoethanolamine GVI KGVI Skin* 1 3 2.5 Cyclohexylamine PEL NPK-P Skin* 20 40 Monoethanolamine PEL NPK-P Skin* 2. MONITORING MEASURES : A small volume of air is drawn through an absorbant or barrier to trap the substance(s) which can then be desorbed or removed and analyzed as referenced below: Substance(s) Method Analysis Absorbant Cyclohexylamine US NIOSH: 2010 Gas chromatography Silica gel NALCO EUROPE B.5 7.5 * A skin notation refers to the potential significant contribution to overall exposure by the cutaneous route.6 Cyclohexylamine TWA 1 Monoethanolamine TWA 0.5 7.6 Cyclohexylamine TWA STEL MULT Skin* 10 41 Monoethanolamine STEL MULT Skin* TWA 1 2.5 7. LATVIA CZECH REPUBLIC CROATIA ROMANIA RUSSIAN FEDERATION SERBIA SLOVAKIA SLOVENIA Monoethanolamine ÁK CK Skin* 2.4 Monoethanolamine TWA CEILING Skin* 1 2.2 16.nalco.6 Cyclohexylamine TWA STEL 5 10 20 40 Monoethanolamine TWA STEL Skin* 1 3 2.SAFETY DATA SHEET PRODUCT Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16. for Emergency Telephone Numbers.V.6 Cyclohexylamine (Vapour. training. Monoethanolamine US NIOSH: 2007 Methoxypropylamine No method identified Gas chromatography Silica gel ENGINEERING MEASURES : General ventilation is recommended. EYE PROTECTION : Wear a face shield with chemical splash goggles. EN 143 and EN 14387. Consider the use of filter type: AX-P In event of emergency or planned entry into unknown concentrations a positive pressure. SKIN PROTECTION : When handling this product. EN 137. maintenance and inspection. fit testing. remove clothing and thoroughly wash the affected area. The choice of work glove depends on work conditions and what chemicals are handled. The applicable European standard can be found in EN 166. RESPIRATORY PROTECTION : Where concentrations in air may exceed the limits given in this section. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www. the use of a half face filter mask or air supplied breathing apparatus is recommended. but we have positive experience under light handling conditions using gloves made from PVC Gloves should be replaced immediately if signs of degradation are observed. full-facepiece SCBA should be used.nalco. the use of a chemical resistant suit and rubber boots is recommended. The applicable European standard can be found in EN 140. Keep an eye wash fountain available. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE Liquid NALCO EUROPE B. HAND PROTECTION : When handling this product. legs and body be used.com and request access 7 / 15 .V. the use of chemical gauntlets is recommended. If clothing is contaminated. HYGIENE RECOMMENDATIONS : Use good work and personal hygiene practices to avoid exposure.SAFETY DATA SHEET PRODUCT Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16. When handling this product never eat. Keep a safety shower available. institute a complete respiratory protection program including selection. Always wash thoroughly after handling chemicals. The applicable European standard can be found in EN 14605 and EN ISO 20345. The applicable European standard can be found in EN 166. Launder contaminated clothing before reuse. The applicable European standard can be found in EN 374. we recommend as a minimum precaution that safety glasses with side-shields and workclothes protecting arms. 9. consult PPE manufacturers. In addition any person visiting an area where this product is handled should at least wear safety glasses with side-shields. In general. the workplace and the way the product is handled. PERSONAL PROTECTION GENERAL ADVICE : The use and choice of personal protection equipment is related to the hazard of the product. drink or smoke. A suitable filter material depends on the amount and type of chemicals being handled. for Emergency Telephone Numbers. Use local exhaust ventilation if necessary to control airborne mist and vapor. Breakthrough time not determined as preparation. If respiratory protection is required. MATERIALS TO AVOID : Contact with strong oxidizers (e. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www.8 5 cps (25 °C) ASTM D-2983 -13.33 °C ASTM D-1177 Note: These physical properties are typical values for this product and are subject to change.. TOXICOLOGICAL INFORMATION The following results are for the product.g. hydrochloric. chromic. explosions and/or toxic vapors.com and request access 8 / 15 . 10. ACUTE ORAL TOXICITY : Species: Rat LD50: 1. HAZARDOUS DECOMPOSITION PRODUCTS : Under fire conditions: Oxides of carbon. nitric. sulfonic) may generate heat. STABILITY AND REACTIVITY STABILITY : Stable under normal conditions. Avoid contact with SO2 or acidic bisulfite products. Contact with strong acids (e. which may react to form visible airborne amine salt particles. concentrated oxygen.000 mg/kg Test Descriptor: Hazardous component Monoethanolamine Species: LD50: Test Descriptor: Rabbit > 2.SAFETY DATA SHEET PRODUCT Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16. perchlorate. splattering or boiling and toxic vapors. fires.2. Strong acids. phosphoric.267 mg/kg Test Descriptor: Product ACUTE DERMAL TOXICITY : Species: Rabbit LD50: 400 . peroxides.99 (25 °C) ASTM D-1298 Complete 12. nitric acid. permanganate) may generate heat. HAZARDOUS POLYMERIZATION : Hazardous polymerization will not occur.g.. Oxides of nitrogen 11. sulfuric. chromates. CONDITIONS TO AVOID : Heat and sources of ignition including static discharges. APPEARANCE Light yellow ODOR Amine FLASH POINT : SPECIFIC GRAVITY SOLUBILITY IN WATER pH (100 %) VISCOSITY MELTING POINT 57 °C PMCC 0.V.nalco. chlorine. The following results are for the hazardous components.000 mg/kg Product NALCO EUROPE B. for Emergency Telephone Numbers. 0 mg/l NOEC 150 mg/l 150 mg/l Method Test Descriptor Product Product Product EC50 250 .464.400 mg/l Method Test Descriptor Product Product PERSISTENCY AND DEGRADATION : Chemical Oxygen Demand (COD) : 524. SENSITIZATION : Methoxypropylamine is reported to cause skin sensitization in guinea pigs.SAFETY DATA SHEET PRODUCT Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16. ACUTE FISH RESULTS : Species Exposure Rainbow Trout 96 hrs Fathead Minnow 96 hrs Inland Silverside 96 hrs LC50 200 mg/l 194 mg/l 1.3 mg/l ACUTE INVERTEBRATE RESULTS : Species Exposure LC50 Daphnia magna 48 hrs 326 mg/l Mysid Shrimp (Mysidopsis bahia) 96 hrs 614. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www. CARCINOGENICITY : Possible risk of impaired fertility.0 Test Descriptor: Similar Product Remarks: Causes burns.nalco. ECOLOGICAL INFORMATION ECOTOXICOLOGICAL EFFECTS : The following results are for the product.V. please consult section 2 and 12.com and request access 9 / 15 .000 mg/l NALCO EUROPE B. for Emergency Telephone Numbers. For additional information on the hazard of the preparation. ACUTE INHALATION TOXICITY : Species: Rat LC50: 8000 PPM (4 hrs) Test Descriptor: Hazardous component Cyclohexylamine PRIMARY SKIN IRRITATION : Species: Rabbit Draize Score: /8. 12. PRIMARY EYE IRRITATION : Remarks: Causes burns. in accordance with all applicable regulations. 13. of Laws No. recycling and disposal of packaging waste should comply with the existing regulations (Act of 11 May 2001 on Packaging and Packaging Waste. natural streams or rivers. 63. The waste product should be disposed of at an authorised incineration plant or a waste treatment/disposal plant in line with the existing regulations (Act of 27 April 2001 on Waste. or disposal through a suitably qualified or licensed contractor. This product is ashless and can be burned directly in appropriate equipment. Act of 22 January 2010 amending the Act on waste and certain other acts (J.04. sewers. Ensure compliance with EC. Do not dispose into municipal drains. The product incineration produces ash. 477/2001 Coll. natural streams or rivers. item 145.V. for Emergency Telephone Numbers. J.OFF SPECIFICATION BATCHES AND UNUSED PRODUCTS . This product is NOT suitable for disposal by either landfill or via municipal sewers. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www.com and request access 10 / 15 . 185/2001 Coll. If this product is used in any further processes. 381/2001 Coll.). Do not dispose of wastes in local sewer or with normal garbage. Decree about waste of 27. BIOACCUMULATION POTENTIAL This preparation or material is not expected to bioaccumulate. J.62 item 628 with later changes Dz U 2003. national and local regulations. soil. item 251 of 2007). item 638. consolidated text annexed to the J. Use the services of appropriately authorised businesses. of Laws No. 112. EUROPE WASTE CODE : 16 03 05*. Dispose of wastes in an approved incinerator or waste treatment/disposal site. NATIONAL REGULATIONS AUSTRIA : Waste Code :55352 NATIONAL REGULATIONS CZECH REPUBLIC Valid and applicable waste legislation in the Czech Republic: Waste Act (No. 94/62/EC Directive of the European Parliament and of the Council of 20 December 1994 on packaging and packaging waste. Biological Oxygen Demand (BOD) : Incubation Period Value 6. 91/689/EEC Council Directive of 12 December 1991 on hazardous waste. Reclamation. recovery. 39. drains.oL. the final user must redefine and assign the most appropriate European Waste Catalogue Code. no. of Laws No. Waste catalogue. 28.U nr.400 mg/g Method Test Descriptor Product The organic portion of this preparation is expected to be readily biodegradable. Empty drums should be taken for recycling. item 1206.nalco. Packaging Act (No.). Do not dispose into a local sewage system or with normal household waste. Use only authorized contractors.2001 (DZ.Organic wastes containing dangerous substances.) Directive 2006/12/EC of the European Parliament and of the Council of 5 April 2006 on waste. as amended NATIONAL REGULATIONS POLAND : Waste Code: Regulations of 27 September 2001.) and the Decree of the Ministry of the Environment on the Catalogue of Wastes (No. DISPOSAL CONSIDERATIONS If this preparation becomes a waste. as amended). The product may be incinerated directly using suitable equipment. nr 7 item 78 NALCO EUROPE B.SAFETY DATA SHEET PRODUCT Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16. the final user must define and assign the appropriate European Waste Catalogue code. Please note that the proper Shipping Name / Hazard Class may vary by packaging.S. Cyclohexylamine UN 2734 8 3 II 83 CF1 AIR TRANSPORT (ICAO/IATA) Proper Shipping Name : Technical Name(s) : UN/ID No : Hazard Class .n. LIQUID.I. CORROSIVE. Methoxypropylamine. N. LAND TRANSPORT Proper Shipping Name : Technical Name(s) : UN/ID No : Hazard Class .Secondary : Packing Group : IATA Cargo Packing Instructions : IATA Cargo Aircraft Limit : IATA Passenger Packing Instructions : IATA Passenger Aircraft Limit : AMINES. 14. FLAMMABLE.O. properties.Primary : Hazard Class . and mode of transportation.Primary : Hazard Class . N.com and request access 11 / 15 .S.V. HAZARD SYMBOLS NALCO EUROPE B.SAFETY DATA SHEET PRODUCT Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16.O.Secondary : Packing Group : AMINES. FLAMMABLE. for Emergency Telephone Numbers. Typical Proper Shipping Names for this product are as follows. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www.Primary : Hazard Class . TRANSPORT INFORMATION The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order.nalco. CORROSIVE.O. : CLASSIFICATION CODE : AMINES. LIQUID. Methoxypropylamine. REGULATORY INFORMATION CLASSIFICATION AND LABELLING : GOVERNING DIRECTIVE(S): Dangerous Substances Directive 67/548/EEC and Dangerous Preparations Directive 1999/45/EC.5 L / 1 L MARINE TRANSPORT (IMDG/IMO) Proper Shipping Name : Technical Name(s) : UN/ID No : Hazard Class . CORROSIVE. FLAMMABLE.Secondary : Packing Group : ADR/RID H. N.S. Methoxypropylamine. Cyclohexylamine UN 2734 8 3 II OTHER APPLICABLE INFORMATION CEFIC TREMCARD REFERENCE : EMERGENCY ACTION CODE : 80GCF1-II 2W 15. Cyclohexylamine UN 2734 8 3 II 812 30 L (Max net quantity per package) Y808 / 808 0. LIQUID. see table(s): 49. rinse immediately with plenty of water and seek medical advice.SAFETY DATA SHEET PRODUCT Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16. S26 .com and request access 12 / 15 . and per Act 371/2008 Coll. Classified Industrial Sites (ICPE): Relevant. Social Security Code. 178/2001 Coll. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www.Possible risk of impaired fertility.In case of accident or if you feel unwell. S36/37/39 . Article L461-4. R43 . CORROSIVE Contains:. R21/22 . gloves and eye/face protection. S45 . 356/2003 Coll. R62 . 49 bis Special medical supervision . SAFETY PHRASES S24/25 .V. seek medical advice immediately (show the label where possible). NATIONAL REGULATIONS CZECH REPUBLIC This preparation is classified as per Act on Chemical Substances and Chemical Preparations (No. Headings: 1432B NATIONAL REGULATIONS GERMANY WGK 1 (Annex 4) NATIONAL REGULATIONS HOLLAND ABM RESULT ABM RESULT Substance(s) 9B % (w/w) NATIONAL REGULATIONS HUNGARY Relevant and applicable Hungarian legislation on protection of human health and the environment: NALCO EUROPE B.Decree of 11 July 1977: Relevant. for Emergency Telephone Numbers.Avoid contact with skin and eyes.Wear suitable protective clothing. laying down conditions of health protection of employees at work NATIONAL REGULATIONS FRANCE Table of occupational diseases.In case of contact with eyes.) This Safety Data Sheet is drawn up as per Act No.Causes burns.Methoxypropylamine Cyclohexylamine Monoethanolamine RISK PHRASES R34 . 356/2003 Coll.Decree 11/2/2003: Relevant.May cause sensitization by skin contact.Harmful in contact with skin and if swallowed..nalco. Occupational exposure limits for the Czech Republic in section 8 are given as per Government's Regulation No. 27.V. Minister of Health Regulation of 5 March 2009 concerning labelling of dangerous substances and preparations (J. Authorization and Restriction of Chemicals (REACH).com and request access 13 / 15 . packaging and labelling of dangerous preparations. Regulation 1907/2006/EC concerning Registration. as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC. (VI. 93/67/EEC. 10 January 2002. The law of Russian Federation "About protection of the rights of the consumers". regulations and administrative provisions of the Member States relating to the classification. The law of Russian Federation "Basics of the legislation of The law of Russian Federation "About the industrial regulation". Joint Ministerial Decree: 25/2000. The law of Russian Federation "On Environmental Protection".oL. No. (XII. (IV. General requirements.oL. 27 December 2002 N 184-FZ. No 152. The law of Russian Federation "About the safety of the dangerous industrial objects". 30 March 1999 N 52-FZ. Evaluation.453/2010/ EC Commission regulation of 20 May 2010 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning Registration.oL. labelling and packaging of substances and mixtures. GOST 19433-88: Dangerous goods. item 2173 of 2005). No. No. Classification and marking. Classification and general safety requirements).) EüM (Minister of Health Affairs) and its amendments: Decree 33/2004. item 162). 73.nalco. 27 item 140). for the purposes of its adaptation to technical and scientific progress. item 84 as amended).oL. Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification. Minister of Health Regulation of 2 September 2003 concerning criteria and way of classification of chemical substances and preparations (J. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www.7. 21 July 1997 No. No 27. amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and No 1488/94. 217.1. Evaluation. N 7-FZ. NATIONAL REGULATIONS POLAND Act on chemical substances and preparations of 11 January 2001 (J. NATIONAL REGULATIONS RUSSIAN FEDERATION The law of Russian Federation "About the sanitary-epidemiological safety of the population". 116-FZ.oL. item 1666 as amended). No 171. Minister of Health Regulation of 8 February 2010 concerning a list of dangerous substances including classification and labelling (J. 07 February 1992 N 2300-1. 259.REACH) on detailed rules of certain procedures and activities related to dangerous substances and preparations.oL. No.Minister of Health Regulation of 20 April 2005 on tests and measurements of factors hazardous for health in the working environment (J. Minister of Economy Regulation of 21 December 2005 on essential requirements for Personal Protective Equipment (J.26.007-76 (Occupational safety standards system.SAFETY DATA SHEET PRODUCT Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16. no. establishing a European Chemicals Agency. 93/105/EC and 2000/21/EC Regulation 1272/2008/EC of the European Parliament and of the Council of 16 December 2008 on the classification. labelling and packaging of substances and mixtures.) EüM-ESzCsM on chemical safety at work.790/2009/EC Commission Regulation of 10 August 2009 amending.oL of 2009. Government Statement dated 16 January 2009 on introduction of changes in appendices A and B to European Agreement on road transport of hazardous goods (ADR) prepared in Geneva on 30 September 1957 (J. Decree 44/2000.30. Regulation of MPiPS [Minister of Labour and Social Policy] dated 29 November 2002 on maximum allowable concentrations and levels of harmful factors in the working environment (J. no.) EüM (1907/2006/EK . PRODUCT REGISTRATION NUMBER NALCO EUROPE B.1999/45/EC Directive of the European Parliament and of the Council of 31 May 1999 concerning the approximation of the laws. Social and Family Affairs) and Decree 26/2007. item 645 dated 2005 as amended). amending and repealing Directive 67/548/EEC and 1999/45/EC and amending Regulation (EC) No 1907/2006. Unified text (J. Authorization and Restriction of Chemicals (REACH). item 1833 as amended). (IX. for Emergency Telephone Numbers. Noxious substances. 11.oL. GOST 12.oL. item 1222).) ESzCsM (Minister of Health. 53 item 439). GOST 30333-2007: Chemical production safety passport. nalco.Flammable. R62 .Harmful to aquatic organisms. R43 . R35 . Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. Should you require any further information on Nalco's REACH programme please contact us at [email protected] cause sensitization by skin contact.REVISED INFORMATION: section(s): -2 -3 -8 . R52 . Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www. For any other uses.11 . R21/22 . NALCO EUROPE B. Authorization and restriction of CHemicals (REACH) regulation. OTHER INFORMATION LIST OF RELEVANT R-PHRASES AND NOTAS IN SECTION 3 R10 .Possible risk of impaired fertility. exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. R34 . Nalco is committed to and fully supports the Registration. Safety Data Sheet according to Regulation (EC) No 1907/2006. Please consult your local sales representative for any further information. Denmark 1784346 INTERNATIONAL CHEMICAL CONTROL LAWS EUROPE The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories.Causes severe burns.Harmful in contact with skin and if swallowed. R20 . R22 .Harmful if swallowed.com or visit our website. The product is to be used in applications consistent with our product literature.com and request access 14 / 15 . . 16. JAPAN All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Existing and New Chemical Substances list (ENCS).V.SAFETY DATA SHEET PRODUCT Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16.Causes burns. Evaluation. UNITED STATES : The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710) CANADA : The substance(s) in this preparation are included in or exempted from the Domestic Substance List (DSL). for Emergency Telephone Numbers. It is our intention to pre-register all chemical substances that we manufacture or import into European Union and to work with our suppliers to ensure a smooth transition to this new regulatory environment.Harmful by inhalation.15 This product material safety data sheet provides health and safety information. for Emergency Telephone Numbers. Nagyvárad tér 2) + 371 67042473 +421 (0)2 5477 4166 Prepared By : SHE Department Date issued : 06.V. EMERGENCY TELEPHONE NUMBER(S) Trans-European Belgium / Luxembourg Bulgaria Croatia Czech Republic Denmark Finland France / French Switzerland Germany / Austria / German Switzerland Hungary Italy / Italian Switzerland Latvia The Netherlands Norway Poland Portugal Romania Russia / Belarus Saudi Arabia Serbia Slovak Republic Slovenia Spain Sweden UAE UK and Republic of Ireland Nalfleet International +32-(0)3-575-5555 +32-(0)3-575-0330 +32-(0)3-575-5555 +385 (0)91-1-25-75-23 +420-602-669421 +47-22-33-69-99 +358-(0)9-471 977 +33-(0)6-11-07-32-81 +49-(0)6232-130128 +36-30-9-506-447 +39-333-210-7947 +32-(0)3-575-5555 & Local emergency telephone number 112 +32-(0)3-575-0330 +47-22-33-69-99 +48-(0)601-66-2626 (SGS) / +48(0)14 637 40 81 (SPOT) +351-91-911-1399 +40-744 -34-14-53 +7-812-449-0474 +966-(3)847-1515 +32-(0)3-575-5555 +421-(0)905-585-938 +386-41-634-916 +34-977-551577 +47-22-33-69-99 +44-(0)7071-223-738 +44-(0)7071-223-738 +32-(0)3-575-5555 POISON CONTROL CENTER TELEPHONE NUMBERS Belgium Czech Republic France Hungary Latvia Slovak Republic +32-70-245245 +420 224 91 92 93 +33-(0)145-42-59-59 ORFILA +36-80-201-199 (ETTSZ.0 Numbers quoted in the MSDS are given in the format: 1.SAFETY DATA SHEET PRODUCT Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16.com and request access 15 / 15 .1 = 1 tenth and 0.000 = 1 thousand.001 = 1 thousandth NALCO EUROPE B.000 = 1 million and 1.10.nalco. 0.2010 Version Number : 5. 1096 Budapest.000. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www.