Conforms to Regulation (EC) No.1907/2006 (REACH), Annex 11- United Kingdom (UK) SAFETY DATA SHEET HUNTSMAN HARDENER HW 2934 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Product name Product code Product description HARDENER HW 2934 00048074 Not available. 1.2 Relevant identified uses of the substance or mixture and uses advised against Product use : Hardener for adhesive systems 1.3 Details of the supplier of the safety data sheet Supplier Huntsman Advanced Materials (Europe)BVBA Everslaan 45 3078 Everberg I Belgium Tel. : +41 61 299 20 41 Fax: +41 61 299 20 40 e-mail address of person responsible for this SDS [email protected] 1.4 Emergency telephone number Supplier Telephone number EUROPE: +32 35 75 1234 France ORFILA: +33(0)145425959 ASIA: +65 6336-6011 China: +86 20 39377888 Australia: 1800 786 152 New Zealand: 0800 767 437 USA: +1/800/424.9300 ISECTION 2: Hazards identification 2.1 Classification of the substance or mixture Product definition : Mixture Classification according to Directive 1999/45/EC [DPDJ The product is classified as dangerous according to Directive 1999/45/EC and its amendments. R43 Classification R52/53 Human health hazards May cause sensitisation by skin contact. Environmental hazards Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. See Section 16 for the full text of the R phrases or H statements declared above. See Section 11 for more detailed information on health effects and symptoms. 2.2 Label elements Hazard symbol or symbols Indication of danger Date of issue I Date of revision Irritant : 8 September 2011 1113 H226 STOT SE 3. R20/22 N. 4. are classified as hazardous to health or the environment and hence require reporting in this section.Keep out of the reach of children . H315 Eye lrrit. There are no additional ingredients present which. H314 Eye Dam.Wear suitable gloves. Safety phrases S2. Annex II • United Kingdom (UK) HARDENER HW 2934 Date of printing : 8 September 2011 MSDS no. H314 Eye Dam. 1. H336 Type [1] [1] [1) [1] (1] (2] See Section 11 for the full text of the H statements declared above. R22 C.3-propylenediamine CAS: 10563-29-8 1. R34 R43 2.Avoid contact with skin .3 Xn. ~ I Date of Issue I Date of revision 8 September 20 11 2113] .R22 Xi. R51/53 N(3dimethylaminopropyl)1. R52/53. may cause long-term adverse effects in the aquatic environment. H318 Skin Sens. 2. R21 /22 C. R36/38 4-dimethylaminoethyl1-methyl-4-piperazine CAS: 104-19-8 1• 3 T. 16. 1. Special packaging reguirements Containers to be fitted with child-resistant fastenings Tactile warning of danger : Not applicable. 3. 3. 1.3 Xn. H31 7 Acute Tox.May cause sensitisation by skin contact. H302 Skin lrrit. ISECTION 3: Composition/informatio n on ingredients : Mixture Substance/mixture Classification Identifiers % CAS: 14970-87-7 triethylene glycol dimercaptan N. 1272/2008 [CLP] Acute Tox.If swallowed. 4. Liq . 4. H302 Acute Tox.Harmful to aquatic organisms.6- CAS: 90-72-2 1. H332 Aquatic Chronic 2. Not applicabte. Hazardous ingredients N(3-dimethylaminopropyl)-1. 4. 00048074 Date of issue : 8 September 2011 Version 1. 4. H302 Acute Tox. H302 Acute Tox. H319 Acute Tox. H3 11 Skin Corr.Conforms to Regu lation (EC) No. S46. 1907/2006 (REACH). within the current knowledge of the supplier and in the concentrations applicable.R67 Product/ingredient name tris(dimethy1aminomethy1)phenol 67/548/EEC See section 16 for the full text of the Rphrases declared above Regulation (EC) No. H312 Skin Corr.3-propylenediamine Supplemental label elements Not applicable. R51/53 1-3 Xn. R24 Xn .4. R34 n-butyl acetate CAS: 123-86-4 Index: 607-025-00-1 1-3 R10 R66. H411 Acute Tox. S37. seek medical advice immediately and show this container or label. 2. 4. H318 Flam. 2.3 Other hazards Other hazards which do not result in classification : Not available. 18.02 SECTION 2: Hazards ident ification Risk phrases R43. S24. Skin contact May cause sensitisation by skin contact. Annex II. Continue to rinse for at least 10 minutes. if breathing is irregular or if respiratory arrest occurs. belt or waistband. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. or wear gloves. If material has been swallowed and the exposed person is conscious. or wear gloves. ISECTION 4: First aid measures 4. 00048074 Version 1. Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. provide artificial respiration or oxygen by trained personnel. Over-exposure signs/symptoms Eye contact No specific data.2 Most important symptoms and effects. Maintain an open airway. Remove dentures if any. Ingestion No known significant effects or critical hazards. Annex XIII Substance meets the criteria for vPvB according to Regulation (EC) No. Inhalation No specific data. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. tie. Wash contaminated clothing thoroughly with water before removing it. Annex X III Occupational exposure limits. Get medical attention if irritation occurs .IJ. Get medical attention.RDENER HW 2934 ] Date of printing Date of issue 3/13 8 September 2011 8 September 2011 MSDS no. occasionally lifting the upper and lower eyelids. Skin contact Adverse symptoms may include the following: irritation redness Ingestion No specific data. give small quantities of water to drink. Date of issue I Date of revision : 8 September 2011 3113 . avoid further exposure. are listed in Section 8. 1907/2006 (REACH). Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if adverse health effects persist or are severe. place in recovery position and get medical attention immediately. 4. In the event of any complaints or symptoms. Clean shoes thoroughly before reuse. Maintain an open airway.1 Description of first aid measures Eye contact Immediately flush eyes with plenty of water. W ash clothing before reuse. Never give anything by mouth to an unconscious person.Conforms to Regulation (EC) No. place in recovery position and get medical attention immediately. Continue to rinse for at least 10 minutes. symptoms may be delayed. Skin contact Flush contaminated skin with plenty of water.United Kingdom (UK) H. if available. Stop if the exposed person feels sick as vomiting may be dangerous. Wash contaminated clothing thoroughly with water before removing it. Remove victim to fresh air and keep at rest in a position comfortable for breathing . In case of inhalation of decomposition products in a fire. Remove contaminated clothing and shoes. the head should be kept low so that vomit does not enter the lungs. Serious effects may be delayed following exposure. Loosen tight clothing such as a collar. Ingestion Wash out mouth with water. Inhalation Exposure to decomposition products may cause a health hazard.02 SECTION 3: Composition/information on ingredients [1] [2] [3] [4] Substance classified with a health or environmental hazard Substance with a workplace exposure limit Substance meets the criteria for PBT according to Regulation (EC) No. If not breathing. If unconscious. Check for and remove any contact lenses. 1907/2006. Get medical attention if adverse health effects persist or are severe. The exposed person may need to be kept under medical surveillance for 48 hours. 1907/2006. If unconscious. If vomiting occurs. Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Loosen tight clothing such as a collar. belt or waistband. both acute and delayed Potential acute health effects Eye contact No known significant effects or critical hazards. tie .