SAFETY DATA SHEETaccording to Regulation (EU) No. 453/2010 __________________________________________________________________ ZEOCHEM Molecular sieve Z10-04 __________________________________________________________________ 1. Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier CAS-No. EC-No. REACH No. 1318-02-1 215-283-8 01-2119429034-49-0012 Product code None. Synonyms 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the Substance/Preparation Adsorbent Desiccant 1.3. Details of the supplier of the safety data sheet Company/Undertaking Identification Zeochem AG Seestrasse 108 CH-8707 Uetikon Schweiz Tel. +41 44 922 93 93 [email protected] 1.4. Emergency telephone number Tox-Zentrum Zürich : 145 / +41 44 251 51 51 [24h/7d] Issuing date 10.03.2014 Version GHS 3 ZEOCHEM Molecular sieve Z10-04 GHS 3 Print Date 10.03.2014 1/8 2. Hazardous component(s) which must be listed on the label None. 1272/2008. Print Date 10.2.: 215-283-8 REACH No. Hazards identification 2. S-phrase(s) None. crystalline. synthetic.03. Label elements Labelling according to Directives 67/548/EEC or 1999/45/EC R-phrase(s) None. 3.2.1% 1% CAS-No. Composition/information on ingredients Chemical characterization Components Zeolite Zeolite. see Section 16.: 238-878-4 Clay binder Quarz For the full text of the phrases mentioned in this Section. see Section 16.3.: 01-211942903449-0012 0.: 1318-02-1 EC-No. non fibrous CLP Classification DSD/DPD Classification Product identifier 75% 90% CAS-No. Other hazards No dangerous ingredients according to Regulation (EC) No. Classification of the substance or mixture Classification according to EU Directives 67/548/EEC or 1999/45/EC None.1. The activated product evolves much heat on contact with water. Hazardous impurities ZEOCHEM Molecular sieve Z10-04 GHS 3 None known. 2.2014 2/8 . Additional information For the full text of the phrases mentioned in this Section.: 14808-60-7 EC-No. 4. Extinguishing media Suitable extinguishing media No special measures required. 6. 5. Skin contact Wash with water and soap as a precaution. Ingestion Clean mouth with water and drink afterwards plenty of water. If eye irritation persists. Environmental precautions No special environmental precautions required.4. consult a specialist. Most important symptoms and effects. ZEOCHEM Molecular sieve Z10-04 GHS 3 Print Date 10. Extinguishing media which must not be used for safety reasons None. 5. Firefighting measures 5. Specific methods No special measures required. Eye contact Rinse thoroughly with plenty of water. Special hazards arising from the substance or mixture No data is available on the product itself.2.3. Personal precautions.1. both acute and delayed None known.2014 3/8 .2. 6.03. Accidental release measures 6. Indication of any immediate medical attention and special treatment needed None known. First aid measures 4. also under the eyelids.1. Advice for emergency responders Handle in accordance with good industrial hygiene and safety practice.2. Description of first aid measures Inhalation No special measures required. 4. protective equipment and emergency procedures Advice for non-emergency personnel No special measures required. 5.1.3. Advice for firefighters Special protective equipment for firefighters Standard procedure for chemical fires. Skin and body protection No special measures required.03. Thermal hazards No special measures required.1.3.1.2. Specific end use(s) No information available. Environmental exposure controls No special measures required. 7. Eye protection Avoid contact with eyes. Conditions for safe storage. After cleaning. 8. flush away traces with water. ZEOCHEM Molecular sieve Z10-04 GHS 3 Print Date 10. Exposure controls/personal protection 8.2014 4/8 . Handling and storage 7. Methods and material for containment and cleaning up Use mechanical handling equipment.6. Precautions for safe handling Take precautionary measures against electrostatic discharges. 7. Personal protection equipment Respiratory protection No special protective equipment required. Hand protection DRY moleskin gloves.2.3. including any incompatibilities Store at room temperature in the original container. Alveolar dust fraction Permissible exposure limit: 3 mg/m³. Exposure controls Occupational exposure controls General industrial hygiene practice. 8. 7. Control parameters Exposure limit(s) Total dust Permissible exposure limit: 10 mg/m³. ZEOCHEM Molecular sieve Z10-04 GHS 3 Print Date 10. 9-11 (5% in H2O) > 400°C No information available. No information available.a. 10. Conditions to avoid Not required. Stability and reactivity 10.1.6.5. No information available. Incompatible materials The activated product evolves much heat on contact with water. Beige. Odourless No information available. 10.2. 500-700 g/L practically insoluble n.1. 10.2014 5/8 .9. does not flash Evaporation Rate: Flammability: Explosion limits: Vapour pressure: Vapor density: Relative density: Water solubility: Partition coefficient (noctanol/water): Autoignition temperature: Decomposition temperature: Viscosity: Combustion/explosion hazards: Oxidizing properties: No information available. Hazardous decomposition products None under normal use. No information available. Chemical stability No decomposition if used as directed. not hazardous None 9. Information on basic physical and chemical properties Form Colour Odour Odour Threshold pH: Melting point/range: Boiling point/range: Flash point: Pellets. Reactivity No information available. 10. Other information General Product Characteristics No information available. 10. No information available. No information available.2.03. Possibility of hazardous reactions No information available. 10. No information available.3.4. No information available. Physical and chemical properties 9. No observed adverse effect level (NOAEL): 250 . Aspiration hazard No data available. Results of PBT and vPvB assessment No information available. 12. oral). 12.2014 6/8 . 12. Specific target organ toxicity (repeated exposure) No data available. Accumulation in terrestrial organisms is unlikely. LC50/96h/fish > 680 mg/l. Other adverse effects No information available. Reproductive toxicity Animal testing did not show any hazardous effects. Persistence and degradability No data available. 12.4.1. ZEOCHEM Molecular sieve Z10-04 GHS 3 Print Date 10. Information on toxicological effects Acute toxicity Zeolite (CAS 1318-02-1) LD50/oral/rat > 5000 mg/kg. Human experience This product has no known adverse effect on human health. Respiratory / Skin Sensitisation None. Bioaccumulative potential Does not bioaccumulate.6. Specific target organ toxicity (single exposure) No data available. Toxicological information 11. Toxicity Zeolite (CAS 1318-02-1) EC50/48h/daphnia > 100 mg/l . Accumulation in aquatic organisms is unlikely. EC50/96h/algae = 300 mg/l. Skin corrosion/irritation No skin irritation.5.300 mg/kg (rat.1. Germ cell mutagenicity Animal testing did not show any mutagenic effects. Serious eye damage/eye irritation Slight eye irritation. 12. LD50/dermal/rabbit > 2000 mg/kg. Ecological information 12.03. Mobility in soil No data available.11.2.3. Carcinogenicity Animal testing did not show any carcinogenic effects. 12. LC50/inhalation/rat > 15 mg/l. 03. Contaminated packaging Offer rinsed packaging material to local recycling facilities.1. health and environmental regulations/legislation specific for the substance or mixture Regulatory Information In accordance with Regulation (EC) No. IMO Not required. 15. In accordance with Directive 1999/45/EC. Chemical safety assessment Not required. 14.1. Regulatory information 15. 1272/2008 (GHS/CLP) DSD/DPD: Classification according to EU Directives 67/548/EEC or 1999/45/EC PEL: Permissible Exposure Limit Full text of phrases referred to under sections 2 and 3 None. 16. Waste treatment methods Waste from residues / unused products Dispose of in accordance with local regulations. Further information ZEOCHEM Molecular sieve Z10-04 GHS 3 Print Date 10. ICAO Not required. the product does not need to be classified nor labelled. Transport information ADR/RID Not required. the product does not need to be classified nor labelled. 1272/2008 (GHS/CLP).2. Safety. Disposal considerations 13. Other information Key or legend to abbreviations and acronyms CLP: Classification according to Regulation (EC) No. 15. Further Information Not classified as dangerous in the meaning of transport regulations.13.2014 7/8 . 03. transportation.2014 8/8 . The information given is designed only as a guidance for safe handling.Disclaimer ZEOCHEM Molecular sieve Z10-04 GHS 3 The information provided in this Safety Data Sheet is correct to the best of our knowledge. storage. processing. It is not to be considered a warranty or quality specification. Print Date 10. disposal and release. information and belief at the date of its publication. use.