APG®„The Allrounder“ for Industrial & Institutional Applications April 2009 1 APG® for I & I Applications – April 2009 APG® for I&I Applications Content • APG® Product Overview • Applications • Performance Benefits • Emulsifier and Hydrotrope Potential • Cleaning Performance • Foaming Properties • Anti-streaking Properties • Gloss Retention • Wetting Behavior • Surface and Skin Compatibility 2 APG® for I & I Applications – April 2009 APG® for I&I Applications Content • APG® Product Overview • Applications • Performance Benefits • Emulsifier and Hydrotrope Potential • Cleaning Performance • Foaming Properties • Anti-streaking Properties • Gloss Retention • Wetting Behavior • Surface and Skin Compatibility 3 APG® for I & I Applications – April 2009 wheat coconut / palmkernel oil starch fatty alcohol glucose Alkyl Polyglucoside 4 APG® for I & I Applications – April 2009 .APG® for I&I Applications Chemical Structure coconut / palmkern corn. potato. renewable feedstocks synthetic feedstocks only physical purification by water/alcohol or energy chemically processed. catalyst or reaction aids used renewable & synthetic building blocks combined in a chemical process chemically processed ≥70% naturalCbased C <70% natural based C >70% natural <70% natural C Cognis Natural modified Cognis Naturals Cognis Ecohybrids Cognis Hybrids Cognis Synthetics 5 APG® for I & I Applications – April 2009 .TM Cognis Product Portfolio Easy Guide Systematic Approach 100 % natural. TM Portfolio Easy Guide Home Care / I&I Cognis Natural modified Cognis Ecohybrids Cognis Hybrids Cognis Synthetics Cognis Naturals ……… Eumulgin® VL 75 Gluadin® WLM Gluadin® W 40 Gluadin® WK Glucopon® 215 UP Glucopon® 225 DK Glucopon® 425 N Glucopon® 600 CSUP Glucopon® 650 EC Glucopon® 50 G Plantatex® LLE ……… Comperlan® 100 Comperlan® COD Comperlan® KD Comperlan® WB Dehypon® G 162 Dehydol® LS 2 N Dehyquart® AU 46 Dehyquart® AU 56 Dehyton® AB 30 Euperlan® PK 1200 Plantapon® 611 L Plantatex® HCC Sulfopon® 1218 G Texapon® LS 35 Texapon® N 70 ……… Aminogen® CT 2 APG® 325 N Araphen® K 100 Dehydol® LT 7 Dehydol® O 4 Dehydol® O 10 Dehydol® 980 Dehydol® HD-FC2 Dehypon® LT 104 Dehypon® LS 54 Dehypon® LS 531 Dehyton® PK 45 Deriphat® 160 C Eumulgin® HRE 40 Eumulgin® L Eumulgin® O5 Euperlan® HCO ……… Cosmedia® HC 40 Dehydran® 770 Dehydran® 780 Polyquart® Ampho 149 Polyquart® FDI Polyquart® Pro Polyquart® CCE ……… 6 APG® for I & I Applications – April 2009 . 12.000 (20° C) 11. manual dishwashing 50 G C12-14 1.0 (10%) < 40° C readily 425 N/HH C8-14 1.65 35 .000 – 4.5 yellowish liquid 48 .53 47 .000 – 4.53 47 .4 beige granules 45-55 ------< 40° C readily 215 UP C8-10 1.5 (20%) < 40° C readily 600 CS UP C12-14 1.52 300 .600 (20° C) 7.000 (40° C) 11.5 .72 28 .5 . manual dishwashing Laundry detergents. hard surface cleaners Laundry detergents.) Appearance Active substance [%] Water content [%] Viscosity [mPas] pH value Storage Temperature [° C] Biodegradation (OECD 301 A-F) Compliant with EU. slightly cloudy paste 50 .32 3.7 brownish liquid 68 .Line for Home Care / I&I (EU Production) Glucopon® Line Product Properties C-Chain DP (approx.0 .000 (20° C) 6.5 yellowish.12. slightly cloudy liquid 50 .50 1.Alkyl Polyglucosides Cognis Glucopon®.000 (20° C) 11.Detergent Regulation Laundry detergents.52 48 .38 3.5 .12.5 yellowish. automatic dish detergents Automatic dish detergents.5 (10%) < 40° C readily 225 DK C8-10 1. slightly cloudy liquid 62 .5 (20%) < 40° C readily Main Application I&I cleaners 7 APG® for I & I Applications – April 2009 .9.50 2.9.5 (20%) < 50° C readily 650 EC C8-14 1.500 – 5.0 .4 yellowish.500 – 3. hard surface cleaners Manual dishwashing. hard surface cleaners Manual dishwashing.5 600 UP C12-14 1.0 <40° C readily readily readily 325 N C9-11 1.0 .5 yellowish. hazy paste 48 . slightly cloudy liquid 62 – 65 35 – 38 3.0 .000 11.000 11. manual dishwashing readily readily readily Glucopon® Line 215 UP C8-10 1.25° C] pH value [10%] Storage Temperature [° C] Biodegradation (OECD 301 A-F) Compliant with EU.52 42 .48 21. hard surface cleaners Laundry detergents.12.000 7. clear liquid 48 .5 .5 .52 42 .48 4.500 11.7 brown liquid 68 .32 4.5 225 DK C8-10 1.5 Main Application I&I cleaners 8 APG® for I & I Applications – April 2009 .6 light yellow.9.Detergent Regulation Qualified for Bio-based and DFE ”Cleangredients“ Hard surface cleaners Automatic dish detergents.0 .4 light yellow.48 550 7.5 light yellow.5 425 N C8-14 1.48 18.800 6.Alkyl Polyglucosides Cognis Glucopon®.8.) Appearance Active substance [%] Water content [%] Viscosity [cps.52 42 .72 28 . manual dishwashing Laundry detergents.9.12.Line for Home Care / I&I (US Production) APG® Product Properties C-Chain DP (approx.52 42 .12.5 clear liquid 48 .5 625 UP C12-14 1.5 . hazy paste 48 . APG® for I&I Applications Content • APG® Product Overview • Applications • Performance Benefits • Emulsifier and Hydrotrope Potential • Cleaning Performance • Foaming Properties • Anti-streaking Properties • Gloss Retention • Wetting Behavior • Surface and Skin Compatibility 9 APG® for I & I Applications – April 2009 . APG® for I&I Applications Application Areas Personal Care Industrial Cleaning in Place CIP Food & Beverage Bottle Cleaning Car Wash Institutional Hard Surface Cleaning Ware Washing Laundry Floor Cleaning Home Care Hair / Body / Oral Care Skin Care Hard Surface Cleaning Dishwashing Laundry 10 APG® for I & I Applications – April 2009 . APG® for I&I Applications Application Areas Wetting Glucopon® 225 DK Hard Surface Cleaning / I&I Glucopon® 215 UP Hard Surface Cleaning / Household Glucopon® 425 N Glucopon® 650 EC Dishwash / Laundry Glucopon® 600 UP Emulsifying 11 APG® for I & I Applications – April 2009 . APG® for I&I Applications Content • APG® Product Overview • Applications • Performance Benefits • Emulsifier and Hydrotrope Potential • Cleaning Performance • Foaming Properties • Anti-streaking Properties • Gloss Retention • Wetting Behavior • Surface and Skin Compatibility 12 APG® for I & I Applications – April 2009 . APG® for I&I Applications Emulsifying Capacity • Detergent & Cleaner formulations should: Remove and emulsify soil from surfaces Maintain the soil in solution Carry the soil away in the washing and rinsing step “A perfect ingredient with high emulsifying capacity” Avoid soil re-deposition 13 APG® for I & I Applications – April 2009 . Tested Soils 1) 2) 3) 4) Myritol® 318 (Caprylic / Capric Trygliceride) Soybean Oil Olive Oil Tesco Lard* Tested Surfactants 1) 2) 3) 4) 5) 6) 7) Glucopon® 215 UP Glucopon® 600 CS UP Glucopon® 650 EC Texapon® N 70 Maranil® A 55 Dehydol® LT 7 Dehyton® K (Alkyl polyglucoside C8-C10) (Alkyl polyglucoside C10-C16) (Alkyl polyglucoside C8-C14) (Sodium Laureth Sulfate) (Sodium dodecylbenzenesulfonate) (Fatty alcohol C12-C18 + 7 EO) (Cocoamidopropyl Betaine) *Test Temperature 45° C 14 APG® for I & I Applications – April 2009 .APG® for I&I Applications Emulsifying Capacity Testing of emulsification properties by observation of the behaviour of different types of oil/grease and a surfactant solution. the better the emulsification properties of the test solution. Test Method 50 ml of oil/grease and 50 ml of surfactant solution (2% AM in water) is mixed 1200 +/-3 rpm for 2 minutes. 15 APG® for I & I Applications – April 2009 . Principle The lower the remaining level.APG® for I&I Applications Emulsifying Capacity Testing of emulsification properties by observation of the behaviour of different types of oil/grease and a surfactant solution. After 1 and 4 hours observation of the level of remaining test solution. APG® for I&I Applications Emulsifying Capacity 50 45 40 Aqueous Phase [ml] 35 30 25 20 15 10 5 0 Myritol® Soybean Oil Olive Oil Tesco Lard* 318 Glucopon® 215 UP Dehyton® K Glucopon® 650 EC Dehydol® LT 7 Myritol® Soybean Oil Olive Oil Tesco Lard* 318 Glucopon® 600 CS UP Texapon® N 70 Maranil® A 55 1h 4h *Test Temperature 45° C 16 APG® for I & I Applications – April 2009 . C18´.APG® for I&I Applications Emulsifying Capacity Hydrophilicity Glucopon® 215 UP C8 / C10 Glucopon® 650 EC C8 / C14 Glucopon® 600 UP C12 / C14 Myritol® 318 C8. C10 Soybean Oil C18´´. C18 Olive Oil Tesco Lard C18´ C18 Hydrophobicity "Equal solves equal" 17 APG® for I & I Applications – April 2009 . APG® for I&I Applications Hydrotrope Potential Test Conditions: Example for an alkaline cleaner containing Dehypon® LS 54 Evaluation of amount of hydrotrope needed to obtain a clear solution Data for various Dehypon® types available Without Hydrotrope 5% Dehypon® LS 54 10% KOH (50%) With Hydrotrope 5% Dehypon® LS 54 10% KOH (50%) 2% Glucopon® 225 DK Phase Separation 18 APG® for I & I Applications – April 2009 Clear Solution . APG® for I&I Applications Primary Cleaning Performance Automatic Test Equipment for Primary Cleaning Test equipment for: • All Purpose Cleaner • Bathroom Cleaner • Glass Cleaner • Kitchen Cleaner • Degreaser Soil Composition (83/21) 36% Benzine 80/110 17% Myritol® 318 40% Mineral Oil (Telura 310. Esso) 7% Carbon Black (Special black 4. Degussa) 19 APG® for I & I Applications – April 2009 . APG® for I&I Applications Primary Cleaning Performance Automatic Test Equipment for Primary Cleaning (1) Soiling by brush (2) Analysis of soiled surface (3) Applying test solution (4) Wiping with sponge 20 (5) Rinsing with water (6) Analysis of cleaned surface APG® for I & I Applications – April 2009 . 20° Dosage: 20 ml) C.APG® for I&I Applications Primary Cleaning Performance Soil removal of single surfactants (IPP 83/21. 100 90 80 70 Soil Removal [%] 60 50 40 30 20 10 0 Glucopon® Glucopon® Glucopon® Dehydol® 215 UP 650 EC 600 UP LT 7 Texapon® Texapon® N 70 LS 35 21 APG® for I & I Applications – April 2009 . APG® for I&I Applications Foaming Properties Test Conditions Trigger spray application Formulations (2% AM) were tested on ceramic tiles Evaluation of foaming behavior without rinsing and wiping the test solution. Comparative Foaming Test Glucopon® 215 UP 22 Texapon® N 70 Dehydol® LT 7 APG® for I & I Applications – April 2009 . Comparative Foaming Test Glucopon® 215 UP Glucopon® 650 EC Glucopon® 600 UP 23 APG® for I & I Applications – April 2009 .APG® for I&I Applications Foaming Properties Test Conditions Trigger spray application Formulations (2% AM) were tested on ceramic tiles Evaluation of foaming behavior without rinsing and wiping the test solution. APG® for I&I Applications Foaming Properties Self Foaming Performance of APG® derivatives (Dynamic Foam Cell: 400ppm AM in distilled water at 20 .55° ) C 2100 2000 1900 1800 1700 1600 total volume (min ≥ 400mL) [mL] 1500 1400 1300 1200 1100 1000 900 800 700 600 500 400 300 200 15 20 25 30 35 40 45 50 55 60 Temperature [° C] starting phase/fo am build-up Glucopon® 215 UP Glucopon® 225 DK Glucopon® 425 N/HH Glucopon® 600 CS UP Glucopon® 625 UP Glucopon® 650 EC 24 APG® for I & I Applications – April 2009 . without Dehypon® Base Liquor 400 200 0 -50 50 150 250 350 450 550 650 750 850 950 1050 1150 1250 1350 1450 1550 1650 1750 1850 1950 Dosage of Glucopon® 650 EC [ppm] 25 APG® for I & I Applications – April 2009 . 250 ppm AM in 1% NaOHaq at 65° C 2200 2000 1800 total volume (300mL ≤ V [mL] ≤ 2000mL) 1600 1400 1200 1000 800 600 Dehypon® Wet Blank Value .APG® for I&I Applications Foaming Properties Foam Suppressing on APG® of Dehypon® Wet Dynamic Foam Cell. 500ml. 20° C 2000 1800 Foam Volume + Liquor [ml] 1600 1400 100:0 1200 1000 800 600 400 200 0 0 5 10 Time [min] 15 20 25 75:25 50:50 25:75 0:100 26 APG® for I & I Applications – April 2009 .1% AM Solution. 0.APG® for I&I Applications Foaming Properties Self Foaming of Glucopon® 225 DK : Dehypon® Wet Dynamic Foam Cell. 0.5 1 2 5 Time [min] 10 15 20 75:25 50:50 25:75 0:100 27 APG® for I & I Applications – April 2009 . 20° C 2000 1800 Foam Volume + Liquor [ml] 1600 1400 100:0 1200 1000 800 600 400 200 0 0. 500ml.APG® for I&I Applications Foaming Properties Self Foaming of Glucopon® 600 CS UP : Dehypon® Wet Dynamic Foam Cell.1% AM Solution. Formulations were tested on ceramic tiles. Evaluation of streaking behavior by wiping the surface after application of test solution.APG® for I&I Applications Anti-streaking Properties Test Conditions: Trigger spray application. Comparative Anti-Streaking Test: Fatty Alcohol Ethoxylate 28 Glucopon® 215 UP APG® for I & I Applications – April 2009 . APG® for I&I Applications Gloss Retention Test Conditions: Trigger spray application. Evaluation of gloss retention visually and by reflectometer (BYK Gardner) Comparative Gloss Retention Test: Fatty Alcohol Ethoxylate (80% Gloss Retention) 29 Glucopon® 215 UP (98% Gloss retention) APG® for I & I Applications – April 2009 . Formulations were tested on ceramic tiles. APG® for I&I Applications Filming Behavior / Wetting Behavior Test Conditions Formulations are applied by film applicator (30µm thickness) Formulations were tested on ceramic tiles Evaluation of wetting behavior Comparative Filming Test Glucopon® 215 UP FAES SAS FAEO 30 APG® for I & I Applications – April 2009 . Assessment Range unchanged 31 fissures through-cracks fraction APG® for I & I Applications – April 2009 . The test strip is checked visually after • 4 hours • 3 days • 7 days and • 14 days test period. is dipped five days in a row shortly into the test solution. containing a stainless steal pin in a hole (tension).APG® for I&I Applications Plastic Compatibility Testing of Plastic Compatibility Spline / Corrosion Test According to the Hansgrohe Method Methodology The plastic test stripe. PC Makrolon. PP Novolen) Concentration: 5% AM Plastic: Plexiglas (PMMA) unchanged 14d 7d 3d fissures through-cracks fraction 4h d En 12 C 12 C 12 C G 13 C W o Is ca de no l8 EO G G c lu c lu c lu e at 4 /1 FA O 4E 4 /1 8 /1 5 /1 FA O 7E pp ca op op op r on FA FA O 7E on on ® ed ® ® 32 APG® for I & I Applications – April 2009 EO O /P 0 60 5 21 5 42 FA EO S C P U H /H N U P . ABS Terez. Nonionic surfactants POM Hostaform.APG® for I&I Applications Plastic Compatibility Test Conditions: Example Plexiglas (PMMA) Other plastic materials proved (e.g. APG® for I&I Applications Skin Compatibility (Modified Duhring-Chamber Test) APG® C12/14 LAS FAES SAS FAS C12/14 LAS / APG® (1:1) FAES / APG® (1:1) SAS / APG® (1:1) FAS / APG® (1:1) 0 100 200 300 400 Relative irritation score [%] 33 APG® for I & I Applications – April 2009 . APG® for I&I Applications Summary • Very good emulsifier potential • Excellent cleaning performance • Foaming properties of Glucopon® are significantly better than FAEO • Significant anti-streaking properties of Glucopon® in leave-on applications • High gloss retention on treated surface • Excellent wetting/filming behavior of Glucopon® in contrast to other surfactants • Perfect plastic compatibility by showing no stress-cracking behavior • Glucopon® surfactants are significantly less skin irritating than comparable nonionic surfactants and when used in combination with other surfactants. they can reduce the irritation potential of the surfactant system 34 APG® for I & I Applications – April 2009 . 35 APG® for I & I Applications – April 2009 .
Report "Glucopon for II Applications Final ICS_April 2009"