Safety Data SheetMaterial Name: FLEETGUARD DCA-4 LIQUID SDS ID: DCA-4_AUSTRALIA ____________________________________________________________ Page 1 of 7 Issue Date 01/10/12 Revision 1.0000 Print Date: 01/10/2012 * * * Section 1 - IDENTIFICATION OF THE MATERIAL AND SUPPLIER * * * Manufacturer Information Cummins Filtration Phone: (931) 526-9551 1200 Fleetguard Road Emergency # Chemtrec 703-527-3887 (Outside US) Cookeville, TN 38506 Material Name: FLEETGUARD DCA-4 LIQUID Product Code(s) DCA 60L (1 Pint / 473 mL); DCA 65L (64 ounce / 1.89L); DCA 75L (5 Gallon / 208 L Pail); DCA 80L (55 Gallon / 208 L Drum); DCA 70L (1 gallon/3.785 L); 391412663 (bulk) Product Use cooling system additive Usage Restrictions None known. * * * Section 2 - HAZARDS IDENTIFICATION * * * Hazard Classification Classified according to the criteria of NOHSC and the ADG Code. HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS Preparation Classification Xn Harmful Xi Irritant Risk Phrase(s) R22 Harmful if swallowed. R36/38 Irritating to eyes and skin. Safety Phrase(s) S23 Do not breathe gas, fumes, vapor, or spray. S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S46 If swallowed, seek medical advice immediately and show this container or label. * * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS * * * CAS Component Percent 7758-11-4 Dipotassium phosphate 5-10 7757-79-1 Potassium nitrate 1-5 19147-16-1 Dipotassium adipate 1-5 7632-00-0 Sodium nitrite 1-5 7631-95-0 Sodium molybdate 1-5 64665-57-2 Sodium tolyltriazole 1-3 Safety Data Sheet Material Name: FLEETGUARD DCA-4 LIQUID SDS ID: DCA-4_AUSTRALIA ____________________________________________________________ Page 2 of 7 Issue Date 01/10/12 Revision 1.0000 Print Date: 01/10/2012 * * * Section 4 - FIRST AID MEASURES * * * Inhalation If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. Skin Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Discard contaminated clothing and footwear. Eyes Flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Then get immediate medical attention. Ingestion If swallowed, get medical attention. DO NOT induce vomiting. Never give anything by mouth to an unconscious or convulsive person. Symptoms Immediate skin irritation, eye irritation (possibly severe), blood damage, cardiovascular system damage Symptoms Delayed blood damage, reproductive effects Medical Conditions Aggravated by Exposure skin disorders, eye disorders, blood system disorders, respiratory disorders * * * Section 5 - FIRE FIGHTING MEASURES * * * See Section 9 for Flammability Properties Fire and Explosion Hazards Negligible fire hazard during intended use. Extinguishing Media water spray Large fires: water spray Unsuitable Extinguishing Media extinguishing agent Protective Equipment and Precautions for Firefighters Wear full protective fire fighting gear including self contained breathing apparatus (SCBA) for protection against possible exposure. Fire Fighting Measures Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Thermal Decomposition Products Combustion: oxides of carbon, oxides of nitrogen, oxides of sodium, oxides of sulfur, phosphorus compounds Hazchem Code No data available * * * Section 6 - ACCIDENTAL RELEASE MEASURES * * * See Section 8 for personal protection information. Emergency Procedures Remove sources of ignition. Ventilate the area. Stop leak if possible without personal risk. Keep unnecessary people away, isolate hazard area and deny entry. Only personnel trained for the hazards of this material should perform clean up and disposal. Wear personal protective clothing and equipment, see Section 8. Safety Data Sheet Material Name: FLEETGUARD DCA-4 LIQUID SDS ID: DCA-4_AUSTRALIA ____________________________________________________________ Page 3 of 7 Issue Date 01/10/12 Revision 1.0000 Print Date: 01/10/2012 Methods and Materials for Containment and Cleanup Remove sources of ignition. Ventilate the area. Stop leak if possible without personal risk. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Large spills: Dike for later disposal. Keep unnecessary people away, isolate hazard area and deny entry. Stay upwind and keep out of low areas. * * * Section 7 - HANDLING AND STORAGE * * * Precautions for Safe Handling Do not breathe vapor or mist. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Wear protective gloves/clothing and eye/face protection. Do not eat, drink, or smoke when using this product. Use only outdoors or in a well-ventilated area. Avoid heat, flames, sparks and other sources of ignition. Conditions for Safe Storage Store and handle in accordance with all current regulations and standards. Store in a well-ventilated place. Store in a cool, dry place. Store in a tightly closed container. Protect from freezing. Keep separated from incompatible substances. Store locked up. Authorized persons only. Keep unauthorized personnel away. * * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION * * * Exposure Guidelines No exposure limits established. Biological Limit Values No biological limits allocated. Engineering Controls Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits. PERSONAL PROTECTIVE EQUIPMENT Eyes / Face Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Body Protection Wear appropriate chemical resistant clothing. Hands protection Wear appropriate chemical resistant gloves. Respiratory Protection If engineering controls do not maintain exposure to an acceptable level, respiratory protection may be needed. * * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES * * * Physical State: Liquid Appearance: blue liquid Color: blue Physical Form: liquid Odor: slight or none. Odor Threshold: Not available pH: 10-11 Melting Point: Not available Boiling Point: 100 °C Decomposition: Not available Flash Point: Not available Evaporation Rate: Not available LEL: Not available UEL: Not available Vapor Pressure: 760 mmHg @ 100°C Vapor Density (air = 1): Not available Density: Not available Specific Gravity (water = 1): 1.13-1.15 Water Solubility: Soluble Log KOW: Not available Safety Data Sheet Material Name: FLEETGUARD DCA-4 LIQUID SDS ID: DCA-4_AUSTRALIA ____________________________________________________________ Page 4 of 7 Issue Date 01/10/12 Revision 1.0000 Print Date: 01/10/2012 Coeff. Water/Oil Dist: Not available Auto Ignition: Not available Viscosity: Not available Volatility: Not available * * * Section 10 - STABILITY AND REACTIVITY * * * Chemical Stability Stable at normal temperatures and pressure. Conditions to Avoid Avoid heat, flames, sparks and other sources of ignition. Containers may rupture or explode if exposed to heat. Take precautionary measures against static discharge. Incompatibilities acids, combustible materials, oxidizing materials, reducing agents, organic materials, (e.g. petrochemicals, oils, greases), halogenated compounds, alcohols, aldehydes Decomposition Products Thermal Decomposition Products Combustion: oxides of carbon, oxides of nitrogen, oxides of sodium, oxides of sulfur, phosphorus compounds Possibility of Hazardous Reactions Will not polymerize. Hazardous Reactions No hazard expected. * * * Section 11 - TOXICOLOGICAL INFORMATION * * * Toxicity Data Likely Routes of Exposure Acute and Chronic Toxicity This material contains a constituent which has been reported to induce methemoglobinemia in humans. Symptoms/effects may include cyanosis, nausea, dizziness, irregular heartbeat, or difficulty breathing. Component Analysis - LD50/LC50 The components of this material have been reviewed in various sources and the following selected endpoints are published: Potassium nitrate (7757-79-1) Oral LD50 Rat 3015 mg/kg Sodium molybdate (7631-95-0) Inhalation LC50 Rat >2080 mg/m3 4 h; Oral LD50 Rat 4 g/kg Sodium nitrite (7632-00-0) Inhalation LC50 Rat 5.5 mg/L 4 h; Oral LD50 Rat 85 mg/kg Immediate Effects May cause skin irritation, eye irritation (possibly severe), or blood damage. Delayed Effects May cause blood damage or reproductive effects. Irritation/Corrosivity Data skin irritation, eye irritation (possibly severe) Serious Eye Damage/Eye Irritation Respiratory Sensitizer No data available. Dermal Sensitizer No data available. Safety Data Sheet Material Name: FLEETGUARD DCA-4 LIQUID SDS ID: DCA-4_AUSTRALIA ____________________________________________________________ Page 5 of 7 Issue Date 01/10/12 Revision 1.0000 Print Date: 01/10/2012 Carcinogenicity Component Carcinogenicity None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA. Mutagenic Data No data available. Reproductive Effects Data May cause reproductive effects. Tumorigenic Data No data available. Specific Target Organ Toxicity - Single Exposure cardiovascular system, blood Specific Target Organ Toxicity - Repeated Exposure blood Aspiration Hazard No data available. Medical Conditions Aggravated by Exposure skin disorders, eye disorders, blood system disorders, respiratory disorders * * * Section 12 - ECOLOGICAL INFORMATION * * * Ecotoxicity No information available for the product. Component Analysis - Aquatic Toxicity Sodium nitrite (7632-00-0) Fish: 96 Hr LC50 Oncorhynchus mykiss: 0.19 mg/L [flow-through] (juvenile); 96 Hr LC50 Oncorhynchus mykiss: 0.092-0.13 mg/L [flow-through]; 96 Hr LC50 Oncorhynchus mykiss: 0.4- 0.6 mg/L [semi-static]; 96 Hr LC50 Oncorhynchus mykiss: 0.65-1 mg/L [static]; 96 Hr LC50 Pimephales promelas: 2.3 mg/L [flow-through]; 96 Hr LC50 Pimephales promelas: 20 mg/L [static] Other Toxicity No information available for the product. Bioaccumulation No information available for the product. Bioconcentration No information available for the product. Biodegradation No information available for the product. Persistence / Degradability No information available for the product. Mobility No information available for the product. * * * Section 13 - DISPOSAL CONSIDERATIONS * * * Disposal Methods and Containers Dispose in accordance with all applicable regulations. Reprocess whenever possible. Co-process or incinerate in authorized facilities. Incineration should be done in accordance with prevailing municipal, state, and federal laws and standards from local environmental agencies. Safety Data Sheet Material Name: FLEETGUARD DCA-4 LIQUID SDS ID: DCA-4_AUSTRALIA ____________________________________________________________ Page 6 of 7 Issue Date 01/10/12 Revision 1.0000 Print Date: 01/10/2012 Component Waste Numbers None of the components of this material are found on any Hazardous Waste Act list. * * * Section 14 - TRANSPORT INFORMATION * * * IATA Information Not regulated as dangerous goods ICAO Information Not regulated as dangerous goods IMDG Information Not regulated as dangerous goods Marine Pollutant Information Sodium nitrite (7632-00-0) IBC Code: Category Y (solution) * * * Section 15 - REGULATORY INFORMATION * * * Australia - Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) The following component(s) are specifically listed. Sodium nitrite (7632-00-0) Sched. 2: for therapeutic use except when present as an excipient Sched. 5: <=1 % (in preparations except in preparations containing <=0.5% of Sodium nitrite, when present as an excipient in preparations for therapeutic use, or in aerosols) Sched. 6: <=40 % (in preparations except when included in Schedule 2 or 5, in preparations containing <=0.5% of Sodium nitrite, when present as an excipient in preparations for therapeutic use, or in aerosols containing <=2% of Sodium nitrite) Sched. 7: except when included in Schedule 2, 5 or 6, in preparations containing <=0.5% of Sodium nitrite, when present as an excipient in preparations for therapeutic use, or in aerosols containing <=2% of Sodium nitrite Australia - Substances Requiring Health Surveillance None of the components of this material are specified by NOHSC (or Australian Territories). Australia - Capital Territory - Environment Protection Regulation None of the components of this material are listed by the Australian Capital Territory Environment Protection Regulation. Australia - National Pollutant Inventory None of the components of this material are specified on the National Pollutant Inventory substance list as published by Environment Australia. Australia - High Volume Industrial Chemical List This material contains a component(s) listed on the High Volume Industrial Chemical List as published by the National Industrial Chemicals Notification and Assessment Scheme (NICNAS). Sodium nitrite (7632-00-0) Present OECD - List of High Production Volume Chemicals This material contains a component(s) on the List of High Production Volume Chemicals as published by the Organization for Economic Co-operation and Development (OECD). Dipotassium phosphate (7758-11-4) SIDS Chemical Potassium nitrate (7757-79-1) SIDS Chemical Safety Data Sheet Material Name: FLEETGUARD DCA-4 LIQUID SDS ID: DCA-4_AUSTRALIA ____________________________________________________________ Page 7 of 7 Issue Date 01/10/12 Revision 1.0000 Print Date: 01/10/2012 Sodium molybdate (7631-95-0) Present Sodium nitrite (7632-00-0) SIDS Chemical Sodium tolyltriazole (64665-57-2) Present WHO - Drinking Water Quality Guideline Values None of the components of this material are listed on the Drinking Water Quality Guideline Values as published by the World Health Organization (WHO). Inventory Component CAS AU Dipotassium phosphate 7758-11-4 Yes Potassium nitrate 7757-79-1 Yes Dipotassium adipate 19147-16-1 No Sodium molybdate 7631-95-0 Yes Sodium nitrite 7632-00-0 Yes Sodium tolyltriazole 64665-57-2 Yes * * * Section 16 - OTHER INFORMATION * * * Revision Date Revision 1.0000, 10 January 2012: New SDS. Key / Legend ACGIH - American Conference of Governmental Industrial Hygienists; CAS - Chemical Abstracts Service; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IMDG - International Maritime Dangerous Goods; Kow - Octanol/water partition coefficient; LEL - Lower Explosive Limit; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NTP = National Toxicology Program; STEL - Short-term Exposure Limit; TWA - Time Weighted Average; UEL - Upper Explosive Limit; UEL - Upper Explosive Limit Other Information The information set forth in this Safety Data Sheet does not purport to be all-inclusive and should be used only as a guide. While the information and recommendations set forth herein are believed to be accurate, the company makes no warranty regarding such information and recommendations and disclaims all liability from reliance thereon. End of Sheet DCA-4_AUSTRALIA