FAQ What is Temper Embrittlement, And How Can It Be Controlled

FAQ: What is temper embrittlement, and how can it be controlled?Technical Capabilities Membership Accessibility TWI Global TWI Global Training and Examinations Text Only Site Map Register  |  Member Login Search Advanced search Home Capabilities Industries Membership Technical Knowledge News and Events About Us > Technical Knowledge > FAQs > Material FAQs > FAQ: What is temper embrittlement, and how can it be controlled? Technical Knowledge FAQs Material FAQs FAQ: What are SiAlONs? FAQ: What is 'galling' FAQ: Can I bond Teflon? FAQ: What is Barrikade? FAQ: What is weld metal? Contact Us Share:   What is temper embrittlement, and how can it be controlled? Frequently Asked Questions Temper embrittlement refers to the decrease in notch toughness of alloy steels when heated in, or cooled slowly through, a temperature range of 400°C to 600°C. Temper embrittlement can also occur as a result of isothermal exposure to this temperature range. The occurrence of temper embrittlement can be determined by measurement of the change in the ductile to brittle transition temperature with a notched bar impact test, before and after heat treatment. In most cases, the hardness and tensile properties of the material will not show any change as a result of embrittlement, but the transition temperature can be raised by as much as 100°C for embrittling heat treatments. Temper embrittlement is caused by the presence of specific impurities in the steel, which segregate to prior austenite grain boundaries during heat treatment. The main embrittling elements (in order of importance) are antimony, phosphorous, tin and arsenic. The fracture surface of a material embrittled by these elements has an intergranular appearance. FAQ: How is Barrikade made? Plain carbon steels with less than 0.5% Mn are not susceptible to temper embrittlement. However, additions of Ni, Cr and Mn will cause greater susceptibility to temper embrittlement. Small additions of W and Mo can inhibit temper embrittlement, but this inhibition is reduced with greater additions. FAQ: What is Charpy Testing? The original toughness of a steel which has suffered temper embrittlement can be restored by heating to above 600°C, and then cooling rapidly to below 300°C. However, the best method of avoidance is to reduce the embrittling impurities through control of raw materials and steel production. FAQ: What is graphitisation? In order to assess susceptibility to temper embrittlement in Cr-Mo steels, two compositional parameters are commonly employed, the Watanabe J factor (1) and the Bruscato X factor (2). FAQ: What are electroceramics? J=(Mn + Si)(P + Sn) x104 (in wt %), has been applied to parent steels and weld metals. FAQ: Why use ceramic coatings? If J is less than or equal to 180, or if X is less than 20, the risk of temper embrittlement is considered to be low. A limit in this form can be specified for procurement, where concerns over temper embrittlement exist. A more general expression for embrittlement in weld metals was given by Sugiyama et al(3): FAQ: How do you weld cast iron? FAQ: What is an MCrAlY coating? FAQ: What is the contact angle? FAQ: How can I weld naval brass? X=(10P + 5Sb + 4Sn + As)/100 (in ppm), is applied to weld metals. P E = C + Mn + Mo + Cr/3 + Si/4 + 3.5 (10P + 5Sb + 4Sn + As) The maximum value for this expression to avoid serious embrittlement depends on the welding process, but is given as 2.8-3.0 where coarse grained weld metal exists. Step cooling can reveal the susceptibility of a steel to temper embrittlement. The Charpy impact energy and transition temperature for steel after an embrittling heat treatment involving step cooling have been related to give a mathematical expression that when fulfilled ensures that the material will not suffer an unacceptable degree of temper embrittlement in service (4). FAQ: What are ceramic adhesives? AF + 2.5(SC - AF) < 38°C where AF=As formed Charpy 54J temperature SC=Step cooled Charpy 54J temperature FAQ: What is 'chevron' cracking? This expression is used in the construction of pressure vessels that may operate in the embrittling temperature range, or that may pass slowly through that temperature range upon startup or shutdown. FAQ: Where can Barrikade be used? One step cooling method with hold times and temperatures is given in ASTM A387, supplementary requirements[5] although this gives a more stringent requirement for the acceptable degree of temper embrittlement. FAQ: What is a sandwich structure? Temper embrittlement has been also related to reheat cracking and low-ductility creep fractures, and a number of types and mechanisms have been proposed, considering carbide precipitation as well as grain boundary embrittling elements. FAQ: What are engineering ceramics? References http://www.twi-global.com/technical-knowledge/faqs/material-faqs/faq-what-is-temper-embrittlement-and-how-can-it-be-controlled/[3/1/2016 10:53:14 AM] Proceedings of the symposium on Applications of 2. R.1V and 3. FAQ: Where do I obtain ATIG Fluxes? FAQ: Is it possible to braze diamonds? FAQ: What are biocompatible adhesives? 5.75Cr0. Erwin. ASTM conference. Yoshino. Alloy steel. or please contact us. 1987.25%Cr-1%Mo pressure vessel steels with improved creep rupture strength".E. ASTM A387:"Standard specification for pressure vessel plates. S. J: "2. 1981. http://www. and Kerr. FAQ: What is a structural adhesive? 2. ASTM STP 755. Florida. Ohnishi. pp. Bruscato.5Ni steels". T.twi-global. M: "Embrittlement factors for estimating temper embrittlement in 2.FAQ: What is temper embrittlement. T. K and Watanabe. FAQ: How does a gel form from a sol? 4. WRC Bulletin 275.5Mo-0. N. Y.25%Cr-1%Mo steel for thickwall pressure vessels. F and Kiuchi. XII-E-6-81. Hatori. 1980. February 1982.25Cr:1Mo. 3. Ishiguo. IIW Doc.5Ni-1. W. Miami. A: "Temper embrittlement of Cr-Mo weld metals". 3. J. Sugiyama.G: "The use of Quenched and Tempered 2¼Cr-1Mo Steel for Thick Wall Reactor Vessels in Petroleum Refinery Processes: An Interpretive review of 25 Years of Research and Application". Murakami. Yamamoto. and how can it be controlled? FAQ: What is "matching" weld metal? 1.com/technical-knowledge/faqs/material-faqs/faq-what-is-temper-embrittlement-and-how-can-it-be-controlled/[3/1/2016 10:53:14 AM] . Chromium-molybdenum"   See further information about Materials and Corrosion Management. 129-147. IIW. and how is it detected? FAQ: What is porosity and how can it be prevented? FAQ: What types of engineering ceramics are there? http://www. and how can it be controlled? FAQ: What are biodegradable adhesives? FAQ: What are piezoelectric materials? FAQ: What are carboncarbon composites? FAQ: What are superconducting ceramics? FAQ: Why are some ceramics machineable? FAQ: How can I easily identify a plastic? FAQ: What is the LarsonMiller parameter? FAQ: Can I arc weld freemachining steels? FAQ: Use of ceramics as bearing materials.twi-global.com/technical-knowledge/faqs/material-faqs/faq-what-is-temper-embrittlement-and-how-can-it-be-controlled/[3/1/2016 10:53:14 AM] .FAQ: What is temper embrittlement. FAQ: What are inorganic ceramic adhesives? FAQ: Which materials can be laser drilled? FAQ: What are pressuresensitive adhesives? FAQ: What is the HollomanJaffe parameter? FAQ: Do polymers undergo changes in service? FAQ: How many times can a weld be re-welded? FAQ: How can I weld aluminium-nickel bronzes? FAQ: What are liquid crystal polymers (LCPs)? FAQ: What is a thermal barrier coating (TBC)? FAQ: What materials can you make with sol-gel? FAQ: Can I weld mild steel to high yield steel? FAQ: How can I convert between hardness scales? FAQ: What is a 'fish-eye' and how does it develop? FAQ: What is creep damage. FAQ: What is temper embrittlement. ceramics and glassceramics defined? FAQ: How do I select a consumable for welding cast iron? FAQ: What is meant by post-heating and how is it applied? FAQ: Can I normalise a welded C-Mn component or structure? FAQ: What is a sol (in the context of sol-gel technology)? FAQ: What is an oxide dispersion strengthened (ODS) alloy? FAQ: What is galvanic corrosion and how can it be avoided? FAQ: What is meant by the http://www.com/technical-knowledge/faqs/material-faqs/faq-what-is-temper-embrittlement-and-how-can-it-be-controlled/[3/1/2016 10:53:14 AM] .twi-global. and how can it be controlled? FAQ: Are polymeric adhesives microwave transparent? FAQ: Can you use organic adhesives to bond ceramics? FAQ: How can I assess the weldability of a material? FAQ: What determines the creep strength of an alloy? FAQ: What is hot cracking (solidification cracking)? FAQ: Is it easy to weld titanium and titanium alloys? FAQ: What is meant by wetting and how can it be used? FAQ: What is the best approach for cleaning ceramics? FAQ: What P Number is steel to BS (or EN or DIN) xxx? FAQ: What are wormholes and how can they be prevented? FAQ: What is type IV cracking. and how is it detected? FAQ: How is microwave energy absorbed into an adhesive? FAQ: Why are microwavetransparent adhesives important? FAQ: How are glass. FAQ: What is temper embrittlement. and how can it be controlled? FAQ: Does titanium need gas shielding when it is friction welded? FAQ: How are oxide dispersion strengthened (ODS) alloys produced? http://www.com/technical-knowledge/faqs/material-faqs/faq-what-is-temper-embrittlement-and-how-can-it-be-controlled/[3/1/2016 10:53:14 AM] .twi-global. and how can it be controlled? water permeability of a polymer? FAQ: What is the permissible limit of Cu in Pb-Sn solders? FAQ: What types of metal powder are used with HVOF spraying? FAQ: Are HVOF coatings an alternative to hard chrome plating? FAQ: Are quenched and tempered (Q&T) steels readily weldable? FAQ: Can ASME IX 'P' Numbers be applied to non-ASME material? FAQ: Why is the Ca:S ratio specified in steel specifications? FAQ: Why is the Ti:N ratio specified in steel specifications? FAQ: What are the implications of welding over existing welds? FAQ: What is the difference between heat input and arc energy? FAQ: What types of carbide powder are used with HVOF spraying? FAQ: Are ferritic stainless steels susceptible to hot cracking? FAQ: How do you weld grey cast iron using a MMA (SMAW) process? FAQ: How do you weld malleable cast iron by MMA (SMAW) welding? FAQ: How reliable are Electrically Conductive Adhesives (ECAs)? FAQ: What are the residual stresses in a dissimilar metal weld? FAQ: How do you weld austenitic cast iron by MMA (SMAW) welding? FAQ: What is temper embrittlement. and how can it be controlled? FAQ: What stress-strain behaviour can I expect adhesives to have? FAQ: How can weld porosity be detected and how can it be remedied? FAQ: How do impurities in an adhesive affect microwave attenuation? FAQ: What are the different types of cast iron which can be welded? What is high temperature hydrogen attack (HTHA)/hot hydrogen attack? FAQ: How do you determine the type of cast iron you are dealing with? FAQ: what are TMCP (Thermo-mechanically Controlled Processed) steels? FAQ: Why are my 300 series austenitic stainless steel welds magnetic? FAQ: What causes porosity in titanium welds and how can it be avoided? FAQ: Which thermoplastic materials can be RF (Radio Frequency) welded? FAQ: Which thermoplastics can be joined by hot bar or impulse welding? FAQ: Is it possible to predict the service life of a plastic component? FAQ: What sort of adhesives are used for medical/surgical applications? FAQ: Can friction welding be used to join nickel and cobalt superalloys? FAQ: What do the markings mean which are stamped on thermoplastic pipes? FAQ: What solders can be used to overcome gold scavenging on a substrate? FAQ: What treatments exist for altering the surface energy of a material? FAQ: Where can I find information regarding porosity in aluminium welds? FAQ: Do degradable plastics have a place in the medical/healthcare sector? http://www.twi-global.FAQ: What is temper embrittlement.com/technical-knowledge/faqs/material-faqs/faq-what-is-temper-embrittlement-and-how-can-it-be-controlled/[3/1/2016 10:53:14 AM] . can I identify an unknown plastic material? FAQ: What is heat-tint and how do I avoid it during welding of stainless steels? FAQ: Are TMCP (ThermoMechanically Contolled Processing) steels readily weldable? http://www.twi-global. brittle and insulating? FAQ: What precautions should I take when welding aluminium and its alloys? FAQ: How do you weld spheroidal or nodular cast iron by MMA (SMAW) welding? FAQ: Should steel plate be cold straightened if it is accidentally damaged? FAQ: What factors affect the choice of adhesive for a specific application? FAQ: What is meant by postweld heat treatment / stress relief heat treatment? FAQ: When do I need to use metal coatings as opposed to polymers and paints? FAQ: How do I measure the diffusible hydrogen level in my ferritic steel weld? FAQ: What is the relationship between flux moisture content and weld hydrogen? FAQ: What is the 'surface energy' of a material. using simple manual tests. and how can it be controlled? FAQ: How can I characterise the wear resistance of thermal spray coatings? FAQ: Is it true that ceramics are not always hard.FAQ: What is temper embrittlement. and how can it be determined? FAQ: Is it true that adhesives have more than one function in microelectronics? FAQ: What are the typical values of surface energy for materials and adhesives? FAQ: How can cracking be avoided when welding is used to restore tools and dies? FAQ: How.com/technical-knowledge/faqs/material-faqs/faq-what-is-temper-embrittlement-and-how-can-it-be-controlled/[3/1/2016 10:53:14 AM] . com/technical-knowledge/faqs/material-faqs/faq-what-is-temper-embrittlement-and-how-can-it-be-controlled/[3/1/2016 10:53:14 AM] .twi-global.FAQ: What is temper embrittlement. which factors affect the weldability of thermoplastics? FAQ: What causes crater pipes and what will prevent their formation during welding? FAQ: Can a welded repair to a pressure vessel be carried out without subsequent PWHT? FAQ: Do increased preheat and heat input always reduce the risk of hydrogen cracking? FAQ: What are low alloy steels. and how can it be controlled? FAQ: Can pickling of stainless steel welds be replaced by other cleaning methods? FAQ: What are the common properties of oxide dispersion strengthened (ODS) alloys? FAQ: What are the main industrial application areas for sol-gel derived materials? FAQ: How can I characterise the density and porosity of the thermal spray coatings? FAQ: In ultrasonic welding. and what precautions should I take when welding them? FAQ: What are the problems with laser cutting of aluminium and how do I overcome them? FAQ: What is liquid metal embrittlement and what are common embrittling metal couples? FAQ: What are the functions of the fibres and matrix in glass reinforced plastics (GRP)? FAQ: What can be done to help achieve a good colour match when welding aluminium alloys? FAQ: How can I determine the atmospheric corrosion performance of thermal spray coatings? FAQ: How can I minimise the risk of solidification cracking in Submerged Arc (SAW) welds? FAQ: What are the equivalent European and American Standards for common stainless steels? http://www. twi-global. Pearlite and Ferrite? FAQ: What are the distinguishing characteristics of steels made using different deoxidation practices? FAQ: Are duplex and superduplex stainless steels fit-for-purpose under conditions of cathodic protection? FAQ: Are there any particular points to http://www. Martensite. and how can it be controlled? FAQ: What methods of portable hardness testing are available and which is most reliable? FAQ: What are Electrically Conductive Adhesives.FAQ: What is temper embrittlement.com/technical-knowledge/faqs/material-faqs/faq-what-is-temper-embrittlement-and-how-can-it-be-controlled/[3/1/2016 10:53:14 AM] . Bainite. how do they work and where are they used? FAQ: What checks should be carried out to assess fire damage in a post-fire investigation? FAQ: What are the causes of and solutions to the preferential weld corrosion in C-Mn steels? FAQ: What materials issues must be considered when repairing hot section gas turbine blades? FAQ: What precautions do I need to take to avoid hydrogen cracking when welding C-Mn steels? FAQ: What is current industry standard practice for welding supermartensitic stainless steels? FAQ: What is the significance of nickel on sulphide stress cracking in duplex stainless steels? FAQ: What precautions should I take to avoid cracking when welding creep (heat)-resistant steels? FAQ: How do I remove heat-tint formed during welding or improper heat treatment of stainless steels? FAQ: What are the factors involved in the choice of consumables for MMA (SMAW) welding of cast iron? FAQ: What are the microstructural constituents Austenite. com/technical-knowledge/faqs/material-faqs/faq-what-is-temper-embrittlement-and-how-can-it-be-controlled/[3/1/2016 10:53:14 AM] .FAQ: What is temper embrittlement.twi-global. and how can I http://www. does this make it more difficult to friction weld? FAQ: Is post weld heat treatment normally required when welding chromium-nickel austenitic stainless steels? FAQ: Why does my steel specification say that the aluminium content must exceed twice the nitrogen content? FAQ: Can I weld duplex or superduplex stainless steel to carbon steel and. microstructure and toughness in steel heat affected zones? FAQ: How might the operating temperature limits of austenite-ferrite grades of stainless steel be increased? FAQ: If a metal or alloy has a high thermal conductivity. if so. what consumable should I use? FAQ: What is the difference between the various carbon equivalent formulae used in relation to hydrogen cracking? FAQ: What is the effect of moisture or hydrogen in shielding gas on hydrogen content of gas metal arc weld metal? FAQ: What are the causes of and solutions to preferential weld corrosion in electric resistance welded steel pipe? FAQ: What is a supermartensitic stainless steel and why is it an attractive alternative to duplex stainless steel? FAQ: Why are there different types of manganese sulphide (MnS) inclusions. and how can it be controlled? observe when clinching materials of dissimilar type or thickness? FAQ: What are the equivalent European and American Standards for common stainless steel filler materials? FAQ: What is the origin of embrittlement in austenitic stainless steel welds exposed to high temperatures? FAQ: What is the relationship between hardness. 0. how do I compare the results with the specification? FAQ: What is controlled deposition repair ('cold' repair.3% carbon steel. but my certificate shows J/cm?.25% Mo low alloy steel. a 0. a 0. under high restra FAQ: What is the procedure for welding En17 (subsequently known as 608M38).1186 C40E). under high restr FAQ: What is the procedure for welding En8 (subsequently known as 080M40 and 1. under high restr FAQ: My duplex or superduplex stainless steel WPQ has failed ASTM G48 testing FAQ: What is the procedure for welding En9 FAQ: For duplex stainless steel piping used in sour service environments.1178 C30E). a 0. and how is it carried FAQ: What is the procedure for welding En16 (subsequently known as 605M36). 0.5% Mo low alloy steel. What does non-ferrous mean. and how can it be controlled? distinguish between them? FAQ: I have to weld a nonferrous metal.twi-global. under high restraint? FAQ: For how long and at what temperature should I heat low hydrogen manual metal arc electrodes when baking is required? FAQ: My Charpy specification is in J. without a subsequent post-weld heat treatment).com/technical-knowledge/faqs/material-faqs/faq-what-is-temper-embrittlement-and-how-can-it-be-controlled/[3/1/2016 10:53:14 AM] .38% C. and what things do I need to be careful about? FAQ: How do you weld En 5 (subsequently known as 080M30 and 1.FAQ: What is temper embrittlement.4% carbon steel.4%C. a 0. are there Standards which provide hardness limits dire FAQ: What are the requirements of ASME Section IX for retestingand/or retraining of welders (and welding operators) who fail a FAQ: Why do the proof and tensile strength of Nibased weld metal (used for http://www. FAQ: What is temper embrittlement. a 0. and how can it be controlled? welding 9% Ni steels) differ in welds deposited in d FAQ: Is there a restriction on the heat input that can be used for the welding of TMCP (Thermomechanically Controlled Processed FAQ: What is the procedure for welding En19? FAQ: What is the procedure for welding En24 (subsequently known as 817M40 and 1. 1.6582 34CrNiMo6).com/technical-knowledge/faqs/material-faqs/faq-what-is-temper-embrittlement-and-how-can-it-be-controlled/[3/1/2016 10:53:14 AM] .3% Mo low FAQ: What is the effect on C-Mn and low alloy steels of multiple tempering or stress-relieving heat treatment cycles carried out FAQ: How can I achieve the specified minimum strength and toughness requirements for thicker section sizes and higher strength g FAQ: I've got to meet NACE Rockwell C hardness limits for duplex stainless steel welds but hardness was measured using the Vicke TWI Group websites The Welding Institute Training and Examinations TWI Certification TWI Software Plant Integrity The Test House Structural Integrity Research Foundation (SIRF) National Structural Integrity Research Centre (NSIRC) TWI-MTL LLC TWI Canada TWI China TWI Japan TWI North America Careers at TWI Find Us Procurement Terms and Conditions Privacy and Cookies TWI Ltd. Do you have any comments or suggestions about our site? We would like to hear you! Please click here to fill our feedback form. United Kingdom Tel: +44 (0)1223 899000 Copyright © 2016 TWI Ltd. Granta Park. All rights reserved.4% C.twi-global.25% Cr. Great Abington. Cambridge CB21 6AL. http://www. 0.