Safety Data Sheet according to Regulation (EC) No 1907/2006Product INTERCEPT® EC1017A SECTION 1. 1.1 Product identifier: Type of substance IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING INTERCEPT® EC1017A CLP Mixture 1.2 Relevant identified uses of the substance or mixture and uses advised against: Use of the Substance/Mixture : CORROSION INHIBITOR 1.3 Details of the supplier of the safety data sheet: COMPANY IDENTIFICATION Nalco Ltd. P.O. BOX 11, WINNINGTON AVENUE NORTHWICH, CHESHIRE, U.K. CW8 4DX TEL: +44 (0)1606 74488 LOCAL COMPANY IDENTIFICATION NALCO AB (SE) Box 164 SE-125 24 ÄLVSJÖ, SWEDEN TEL: +46 (0) 8-603 22 00 For additional copies of an MSDS visit www.nalco.com and request access. For Product Safety information please contact: [email protected] 1.4 Emergency telephone number: +32-(0)3-575-5555 Trans-European Date of Compilation/Revision:: Version Number: 09.10.2012 1.0 SECTION 2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture: Classification according to Regulation (EC) No 1272/2008 Skin sensitization - Category 1 H317 Classification according to EU Directives 67/548/EEC or 1999/45/EC This product is classified as dangerous in accordance with the Preparations Directive 1999/45/EC. Xi, IRRITANT R43 Refer to Section 16 for full details of the risk phrases, hazard statements and Notas. 2.2 Label elements: Labelling according to Regulation (EC) No 1272/2008 Contains: Carbohydrazide Nalco Europe Sàrl • Richtistrasse 7 • 8304 Wallisellen, Switzerland For additional copies of an MSDS visit www.nalco.com and request access. 1 / 12 2 / 12 .0 . P363 Wash contaminated clothing before reuse. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention.nalco. R43 Carbohydrazide EC-No. FIRST AID MEASURES 4.0 Refer to Section 16 for full details of the risk phrases.2 Mixture: COMPOSITION/INFORMATION ON INGREDIENTS The details below include all impurities and by-products that contribute to the product classification or that have an occupational exposure limit. P272 Contaminated work clothing should not be allowed out of the workplace. Switzerland For additional copies of an MSDS visit www.1 Description of necessary first-aid measures: In event of emergency assess the danger before taking action. 2. If in doubt.: 207-837-2 CAS-No. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. Precautionary Statements P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. hazard statements and Notas.Safety Data Sheet according to Regulation (EC) No 1907/2006 Product INTERCEPT® EC1017A Hazard pictograms: Signal Word: Warning Hazard Statements: H317 May cause an allergic skin reaction.10.com and request access. Hazardous Substance(s) % (w/w) Classification according to Regulation (EC) No 1272/2008 Acute toxicity 4 : Skin sensitization 1 : Skin corrosion/irritation 2 : Serious eye damage/eye irritation : 2 H302 H317 H315 H319 Classification according to 67/548/EEC Xn R22.3 Other hazards: None known SECTION 3. SECTION 4. Do not put yourself at risk of injury.: 497-18-7 5. contact emergency Nalco Europe Sàrl • Richtistrasse 7 • 8304 Wallisellen. 3. R38. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. If necessary give artifical respiration.Safety Data Sheet according to Regulation (EC) No 1907/2006 Product INTERCEPT® EC1017A INHALATION Remove to fresh air. both acute and delayed: May cause an allergic skin reaction. wear a full face positive-pressure self contained breathing apparatus and protective suit. showing the label and/or SDS. Immediately flush with plenty of water for at least 15 minutes. EYE CONTACT Immediately flush with plenty of water for at least 15 minutes. prevent material and fire water from entering sewers or waterways. and leather goods must be discarded or cleaned before re-use. treat symptomatically. Contaminated clothing. the physician's judgement should be used to control symptoms and clinical condition. Nalco Europe Sàrl • Richtistrasse 7 • 8304 Wallisellen. INGESTION Seek medical advice immediately. 5. Switzerland For additional copies of an MSDS visit www. do not give anything by mouth.1 Extinguishing media: SUITABLE EXTINGUISHING MEDIA Not expected to burn. Remove contaminated clothing.nalco.2 Most important symptoms and effects. seek medical advice. SKIN CONTACT Get immediate medical attention. If conscious. If symptoms develop. place in the recovery position. 4. Use extinguishing media appropriate for surrounding fire. FIRE-FIGHTING MEASURES 5. SECTION 5. PROTECTION FOR FIRST AID PERSONNEL Wear adequate personal protective equipment.3 Advice for firefighters: In case of fire. May evolve oxides of nitrogen (NOx) under fire conditions. Wash clothing before reuse. flood body under a shower. Get immediate medical attention. check breathing and pulse.com and request access. If unconsious. For a large splash. 3 / 12 .3 Indication of immediate medical attention and special treatment needed: Based on the individual reactions of the patient. 4. 5. In the event of a spill. washout mouth and give water to drink.2 Special hazards arising from the substance or mixture: May evolve oxides of carbon (COx) under fire conditions. shoes. Place residues in a suitable. Switzerland For additional copies of an MSDS visit www. 6. ACCIDENTAL RELEASE MEASURES 6. Call trained emergency responders immediately.2 for Environmental Precautions HYGIENE RECOMMENDATIONS Use good work and personal hygiene practices to avoid exposure. Contact an approved waste hauler for disposal of contaminated recovered material. Do not allow material to contaminate ground water system. covered.3 Methods and materials for containment and cleaning up: SMALL SPILLS: Soak up spill with absorbent material. ADVICE FOR EMERGENCY RESPONDERS Restrict access to area as appropriate until clean-up operations are complete. Use only in a closed system. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations). When handling this product never Nalco Europe Sàrl • Richtistrasse 7 • 8304 Wallisellen.com and request access. SECTION 7.1 Personal precautions. Keep a safety shower available. 4 / 12 . occupational health and safety and environmental authorities. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). do not attempt to clean up the spill.nalco. Keep an eye wash fountain available. 6.4 Reference to other sections: Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). spills. soil or sewers become contaminated. Refer to section 6.) readily available. Wash affected area. Always wash thoroughly after handling chemicals. Reclaim into recovery or salvage drums or tank truck for proper disposal. Ensure all containers are labeled.) readily available. Ensure clean-up is conducted by trained personnel only. Ventilate spill area if possible. spills. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations). If drains. Clean up only to be done by Emergency responders/personnel. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection).2 Environmental precautions: In the event of a spill. Clean contaminated surfaces with water or aqueous cleaning agents. etc. etc. leaks. properly labeled container. 6. HANDLING AND STORAGE 7. Have emergency equipment (for fires. Restrict access to area as appropriate until clean-up operations are complete. Do not breathe vapors/gases/dust. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection).Safety Data Sheet according to Regulation (EC) No 1907/2006 Product INTERCEPT® EC1017A SECTION 6. notify local authority. Keep the containers closed when not in use. Notify appropriate government. Use with adequate ventilation. streams. leaks. Have emergency equipment (for fires. protective equipment and emergency procedures: ADVICE FOR NON-EMERGENCY PERSONNEL This material may be hazardous by contact. Prevent product from entering drains. LARGE SPILLS: Contain liquid using absorbent material. by digging trenches or by diking. eyes and clothing.1 Precautions for safe handling: HANDLING Prevent contact with skin. prevent material from entering sewers or waterways. including any incompatibilities: STORAGE CONDITIONS Store the containers tightly closed. PTFE. Polypropylene. Neoprene. Provide mechanical ventilation of confined spaces. legs and body be used. Always wash thoroughly after handling chemicals.com and request access. the use of chemical gauntlets is recommended. Store in suitable labeled containers. SKIN PROTECTION When handling this product. Switzerland For additional copies of an MSDS visit www.3 Specific end uses: Specific use(s) : CORROSION INHIBITOR SECTION 8.2 Exposure controls: ENGINEERING MEASURES: General ventilation is recommended. Nylon 7. HDPE (high density polyethylene).1 Control parameters: EXPOSURE CONTROLS/PERSONAL PROTECTION OCCUPATIONAL EXPOSURE LIMITS This product does not contain any substance that has an established exposure limit. but we have positive experience under light handling Nalco Europe Sàrl • Richtistrasse 7 • 8304 Wallisellen. 5 / 12 . Nitrile. 8. Stainless Steel 316L. Polyvinylidene difluoride.nalco. When handling this product never eat. In general. PVC. Eye wash station and safety shower are necessary. Plasite 7122. Perfluoroelastomer. Laboratory samples should be handled in a fumehood. PERSONAL PROTECTIVE EQUIPMENT GENERAL ADVICE The use and choice of personal protection equipment is related to the hazard of the product. 8. Keep at temperatures above 4 °C SUITABLE CONSTRUCTION MATERIAL Stainless Steel 304. the use of splash chemical goggles is recommended. The applicable European standard can be found in EN 166.Safety Data Sheet according to Regulation (EC) No 1907/2006 Product INTERCEPT® EC1017A eat. EPDM. 7. EYE/FACE PROTECTION When handling this product. CPVC (rigid). The choice of work glove depends on work conditions and what chemicals are handled. Buna-N UNSUITABLE CONSTRUCTION MATERIAL Brass. The use of local exhaust ventilation is recommended to control emissions near the source. Fluoroelastomer. the workplace and the way the product is handled. In addition any person visiting an area where this product is handled should at least wear safety glasses with side-shields. drink or smoke. we recommend as a minimum precaution that safety glasses with side-shields and workclothes protecting arms. Plexiglass. Mild steel.2 Conditions for safe storage. drink or smoke. Breakthrough time not determined as preparation. Not applicable No data available. The applicable European standard can be found in EN 374. No data available.1 Information on basic physical and chemical properties: PHYSICAL STATE APPEARANCE Odour Odour Threshold pH (1 %) FREEZING POINT INITIAL BOILING POINT / BOILING RANGE FLASH POINT EVAPORATION RATE FLAMMABILITY (solid. full-facepiece SCBA should be used. 1. gas) LOWER EXPLOSION LIMIT UPPER EXPLOSION LIMIT VAPOR PRESSURE VAPOR DENSITY Relative density DENSITY SOLUBILITY IN WATER OCTANOL/WATER COEFFICIENT (log Kow) AUTOIGNITION TEMPERATURE DECOMPOSITION TEMPERATURE VISCOSITY EXPLOSIVE PROPERTIES OXIDIZING PROPERTIES 9.9 cps (15. No data available.com and request access.6 °C) Not applicable Not applicable Nalco Europe Sàrl • Richtistrasse 7 • 8304 Wallisellen. the use of a chemical resistant suit and rubber boots is recommended. RESPIRATORY PROTECTION No exposure limits have been assigned to this product or its components. Consider the use of filter type: K-P The applicable European standard can be found in EN 140. No data available. SECTION 9.Safety Data Sheet according to Regulation (EC) No 1907/2006 Product INTERCEPT® EC1017A conditions using gloves made from PVC Gloves should be replaced immediately if signs of degradation are observed. PHYSICAL AND CHEMICAL PROPERTIES Note: These physical properties are typical values for this product and are subject to change.7 ASTM E-70 -2 °C No data available. training. When handling this product. 6. maintenance and inspection. EN 137. institute a complete respiratory protection program including selection. 2. No data available. No data available.1 Information on basic physical and chemical properties: 9.2 Other information: Not applicable Liquid Colorless None No data available. The applicable European standard can be found in EN ISO 20345. If respiratory protection is required. 9.02 (20 °C) No data available. Nalco recommend the use of a full face filter mask or air supplied breathing apparatus. A suitable filter material depends on the amount and type of chemicals being handled. No data available. 6 / 12 . Complete No data available. fit testing. EN 143 and EN 14387.nalco. consult PPE manufacturers. No data available. Switzerland For additional copies of an MSDS visit www. In event of emergency or planned entry into unknown concentrations a positive pressure. 5 Incompatible materials: Contact with strong oxidizers (e. splattering or boiling and toxic vapors. Rabbit. TOXICOLOGICAL INFORMATION 11. Draize Test. phosphoric. the precipitate cannot be resolubilized and loss of product activity will occur. peroxides.000 mg/kg. explosions and/or toxic vapors. chromic. sulfonic) may generate heat. Storage temperature must be above 58 °F (14 °C) and below 90 °F (32 °C) to prevent crystallization at low temperatures and instability at high temperatures. Rat. Contact with strong acids (e. 7 / 12 . sulfuric. permanganate) may generate heat.nalco.2 Chemical stability: Stable if kept under conditions specified in Section 7.000 mg/kg. fires. Test substance: Product : Rabbit. 10. Test substance: Product : Rabbit.com and request access. nitric.1 Information on toxicological effects: Product: Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Genotoxicity : LD50: > 5.3 Possibility of hazardous reactions: Hazardous polymerization will not occur. Nitrites 10. Oxides of nitrogen SECTION 11.3. Switzerland For additional copies of an MSDS visit www. Test substance: Product : May cause an allergic skin reaction.Safety Data Sheet according to Regulation (EC) No 1907/2006 Product INTERCEPT® EC1017A SECTION 10. Result: 0. 10. the classification criteria are not met.g. 10. chromates. chlorine. Draize Test.4 Conditions to avoid: At temperatures below 4 °C (40 °F). nitric acid. this product loses its stability and forms precipitates.g.2.6 Hazardous decomposition products: Under fire conditions: Oxides of carbon. Nalco Europe Sàrl • Richtistrasse 7 • 8304 Wallisellen. Test substance: Product : Based on available data. hydrochloric. Once formed. : LD50: > 2. perchlorate.1 Reactivity: STABILITY AND REACTIVITY Stable under normal conditions. concentrated oxygen. Result: 0. 10. 10. HANDLING AND STORAGE. Test substance: Product : EC50: 45 mg/l.000 mg/l. : No aspiration toxicity classification SECTION 12. Static. GLP: Yes.1 Toxicity: ECOLOGICAL INFORMATION The following results are for the product. Static. Test substance: Product : LC50: 400 mg/l. Marine Algae (Skeletonema costatum). the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH). Corophium volutator. 48 hrs.repeated exposure Aspiration toxicity : Remarks: Based on available data. Switzerland For additional copies of an MSDS visit www. GLP: Yes. Test substance: Product : LC50: 190 mg/l. Carcinogenicity : Based on available data. the classification criteria are not met. GLP: Yes. 96 hrs. Assessment: Assessment: No toxicity to reproduction STOT . Fathead Minnow. the classification criteria are not met. Test substance: Product : LC50: > 10. 72 hrs. Bluegill Sunfish. Static. 12.nalco. ISO TC147SC5WG2. 96 hrs. Product: Toxicity to fish : LC50: 360 mg/l. Reproductive toxicity : Based on available data. GLP: Yes. 96 hrs. Toxicity to algae Ecotoxicology Assessment Acute aquatic toxicity Chronic aquatic toxicity Nalco Europe Sàrl • Richtistrasse 7 • 8304 Wallisellen. 96 hrs. the classification criteria are not met. Fathead Minnow. : Based on available data. ISO 10253. Rainbow Trout. the classification criteria are not met.com and request access. Scophthalmus maximus. : Not expected to demonstrate chronic toxicity to aquatic organisms Toxicity to daphnia and other aquatic invertebrates. OSPAR 1995.single exposure STOT . Test substance: Product : NOEC: 100 mg/l. Test substance: Product : LC50: 70 mg/l.Safety Data Sheet according to Regulation (EC) No 1907/2006 Product INTERCEPT® EC1017A Assessment : : Negative in the Ames Test. None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC). 8 / 12 . 96 hrs. 240 hrs. Test substance: Product : LC50: 156 mg/l. 72 hrs. Test substance: Product : Not expected to be harmful to aquatic organisms. Acartia tonsa. 13.com and request access. If this product is used in any further processes. recovery. DISPOSAL CONSIDERATIONS If this preparation becomes a waste.2 Persistence and degradability: Product: Biodegradability : Greater than 95% of this product consists of inorganic substances for which a biodegradation value is not applicable.Inorganic wastes containing dangerous substances. the final user must define and assign the appropriate European Waste Catalogue code. Switzerland For additional copies of an MSDS visit www. Empty drums should be taken for recycling. This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).Safety Data Sheet according to Regulation (EC) No 1907/2006 Product INTERCEPT® EC1017A 12.OFF SPECIFICATION BATCHES AND UNUSED PRODUCTS . or disposal through a suitably qualified or licensed contractor. Any chemical waste is a potential environmental pollutant and is NOT suitable for disposal via ground. national and local regulations. 12. EUROPE WASTE CODE: 16 03 03* . SECTION 13. in accordance with all applicable regulations. the final user must redefine and assign the most appropriate European Waste Catalogue Code. Nalco Europe Sàrl • Richtistrasse 7 • 8304 Wallisellen.5 Results of PBT and vPvB assessment: Product: Assessment : This mixture contains no substance considered to be persistent. 9 / 12 . Dispose of wastes in an approved incinerator or waste treatment/disposal site..3 Bioaccumulative potential: 12. bioaccumulating nor toxic (PBT).nalco. municipal sewers. natural streams or rivers. 12. drains. Use only authorized contractors.4 Mobility in soil: Product: Environmental fate and pathways : This substance is water soluble and is expected to remain primarily in water. Ensure compliance with EC.1 Waste treatment methods: Contact an approved waste hauler for disposal of contaminated recovered material. 12.6 Other adverse effects: Product: Additional ecological information : No adverse effects expected. Do not dispose of wastes in local sewer or with normal garbage. 3 Transport hazard class(es): 14. Evaluation.4 Packing group: 14.4 Packing group: 14. TRANSPORT INFORMATION The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order.5 Environmental hazards: 14.2 UN proper shipping name: 14. 10 / 12 .1 UN number: 14. REGULATORY INFORMATION 15. Should you require any further information on Nalco's REACH programme please contact us at reach@nalco. It is our intention to pre-register all chemical substances that we manufacture or import into European Union and to work with our suppliers to ensure a smooth transition to this new regulatory environment. Authorization and restriction of CHemicals (REACH) regulation.2 UN proper shipping name: 14. Switzerland For additional copies of an MSDS visit www. health and environmental regulations/legislation specific for the substance or mixture: INTERNATIONAL CHEMICAL CONTROL LAWS EUROPE Safety Data Sheet according to Regulation (EC) No 1907/2006.6 Special precautions for user: 14.5 Environmental hazards: 14.3 Transport hazard class(es): 14. properties.nalco. and mode of transportation. Nalco Europe Sàrl • Richtistrasse 7 • 8304 Wallisellen.6 Special precautions for user: AIR TRANSPORT (ICAO/IATA) 14. LAND TRANSPORT 14.1 Safety. Nalco is committed to and fully supports the Registration.6 Special precautions for user: MARINE TRANSPORT (IMDG/IMO) 14.Safety Data Sheet according to Regulation (EC) No 1907/2006 Product INTERCEPT® EC1017A SECTION 14.com or visit our website. Please note that the proper Shipping Name / Hazard Class may vary by packaging. Typical Proper Shipping Names for this product are as follows.com and request access.1 UN number: 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: not applicable PRODUCT IS NOT REGULATED DURING TRANSPORTATION not applicable not applicable No not applicable not applicable PRODUCT IS NOT REGULATED DURING TRANSPORTATION not applicable not applicable No not applicable not applicable PRODUCT IS NOT REGULATED DURING TRANSPORTATION not applicable not applicable No not applicable not applicable SECTION 15.3 Transport hazard class(es): 14.4 Packing group: 14.5 Environmental hazards: 14.2 UN proper shipping name: 14.1 UN number: 14. no warranty.May cause an allergic skin reaction.May cause sensitization by skin contact. The possible key literature references and data sources which may have been used in conjunction with the consideration of expert judgment to compile this Safety Data Sheet: European regulations/directives (including (EC) No. Chemical Inventories Module and the Generics Module (Ariel Insight™ CD-ROM Version). state. and to ensure that its activities comply with all federal. and is provided in good faith. 1907/2006. 11 / 12 . REVISED INFORMATION: section(s): 14 This product Safety Data Sheet provides health. North American Module. supplier data.Safety Data Sheet according to Regulation (EC) No 1907/2006 Product INTERCEPT® EC1017A CANADA The substance(s) in this preparation are included in or exempted from the Domestic Substance List (DSL). Non European official regulatory data and other data sources. and Nalco disclaims all liability for reliance on such information. Regulatory requirements are subject to change and may differ between European Member States and Nations. H319 .2 Chemical Safety Assessment: No Chemical Safety Assessment has been carried out. 67/548/EEC. Ariel Research Corp. R22 . ERIcards. Nalco Europe Sàrl • Richtistrasse 7 • 8304 Wallisellen. H315 . REFERENCES IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man. UNITED STATES The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710) NATIONAL REGULATIONS GERMANY WGK: 1 (Annex 4) NATIONAL REGULATIONS HOLLAND 15.nalco. or local laws and regulations. 1272/2008. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. R38 .com and request access. The product is to be used in applications consistent with Nalco’s product literature. International Agency for Research on Cancer. NOTAS AND HAZARD STATEMENTS IN SECTION 2. Geneva: World Health Organization. 1999/45/EC). R43 .Irritating to skin. For any other uses.Harmful if swallowed.Causes skin irritation. safety. It is the buyer’s/user’s responsibility to satisfy itself that the product is suitable for the intended use.1 AND 3 H302 . Ariel Insight™ (An integrated guide to industrial chemicals covered under major regulatory and advisory programs). inter-net. ESIS.Causes serious eye irritation.Harmful if swallowed. and regulatory information. (EC) No. OTHER INFORMATION LIST OF RELEVANT R-PHRASES. and believed to be accurate and reliable at the date of issue. Please consult your local sales representative for any further information. The information contained in this Safety Data Sheet is based on data available to us at the date of issue . Bethesda. SECTION 16. Western European Module. MD. exposures should be evaluated so that the appropriate handling practices and training programs can be established to ensure safe working conditions and operations. however. Switzerland For additional copies of an MSDS visit www. express or implied is provided.. H317 . provincial. IUCLID. 12 / 12 .000 = 1 million and 1.001 = 1 thousandth Nalco Europe Sàrl • Richtistrasse 7 • 8304 Wallisellen.Safety Data Sheet according to Regulation (EC) No 1907/2006 Product INTERCEPT® EC1017A Date issued : Version Number : Prepared By: 09.10. Switzerland For additional copies of an MSDS visit www.nalco.000.1 = 1 tenth and 0.2012 1.000 = 1 thousand.0 SHE Department Numbers quoted in the MSDS are given in the format: 1.com and request access. 0.