1.(a) What is a covalent bond? (1) (b) Draw diagrams to show the shapes of the following molecules and in each case show the value of the bond angle on the diagram. BeCl2 BF3 CCl4 SF6 (8) (c) Explain why the shape of NF3 is not the same as the shape of BF3. (3) (Total 12 marks) 2. Describe, with the aid of diagrams, the structure of, and bonding in, sodium chloride, iodine, diamond and graphite. How do the properties of these different types of crystal enable you to distinguish between them? (Total 20 marks) 3. (a) (i) Showing the outer electrons only, draw a dot-and-cross diagram to indicate the bonding in calcium oxide. (2) (ii) Describe the nature and strength of the bonding in solid calcium oxide. (3) (iii) Use the kinetic theory to describe the changes that take place as calcium oxide is heated from 25°C to a temperature above its melting point. (3) (iv) State two properties of calcium oxide that depend on its bonding. (2) (b) (i) Define lattice enthalpy. (2) (ii) State and explain the influence of both ionic charge and ionic radius on lattice enthalpy values. (4) (Total 16 marks) 4. (a) (i) Write an equation for the reaction of calcium with water. Identify the oxidation numbers of all the atoms involved by writing the numbers underneath each symbol in the equation. (2) (ii) State which substance in (b)(i) has been oxidised, and write a half-equation to show the oxidation process. (2) (iii) What is the common name of the solution formed by the reaction of calcium with water? Suggest the likely pH of the solution. (2) cranford community college 1 (b) What would be observed if aqueous sodium hydroxide were added dropwise, until in excess, to aqueous solutions of (2) (c) Account for the observations in (c), giving any relevant ionic equations. (3) (Total 11 marks) 5. (a) Figure 1 shows some data concerned with halogens. Element Electronegativity Boiling point of hydride / K fluorine 4.0 293 chlorine 3.0 188 bromine 2.8 206 iodine 2.5 238 Figure 1 (i) Define the term electronegativity. (2) (ii) Explain the trend in boiling points from hydrogen chloride to hydrogen iodide. (2) (iii) Explain why hydrogen fluoride does not fit this trend. (2) (b) The oxygen atoms in the sulphate ion surround the sulphur in a regular tetrahedral shape. (i) Write the formula of the ion. (1) (ii) State the O–S–O. bond angle. (1) (iii) Figure 2 shows two bond lengths for sulphur - oxygen bonds. Bond Length / nm S-O single 0.154 S=O double 0.143 Figure 2 Suggest what value(s) of bond length would be found in the sulphate ion and state your reasoning. (5) (Total 13 marks) 6. The boiling temperatures, Tb, of some Group IV and Group V hydrides are given below cranford community college 2 (a) Compound CH4 SiH4 NH3 PH3 Tb/K 112 161 240 185 δ – — δ The polarity of a carbon-hydrogen bond can be shown as C H (i) What does the symbol +, above the hydrogen atom, signify? (ii) Explain briefly, in terms of its shape, why a CH4 molecule has no overall polarity. (3) (b) Name the type of intermolecular forces which exist between CH 4 molecules in liquid methane. (1) (c) Explain why the boiling temperature of PH3 is greater than that of CH4. (3) (d) Explain why the boiling temperature of NH3 is greater than that of PH3 (2) (e) Sketch a diagram to show the shape of a molecule of NH 3 and indicate on your diagram how this molecule is attracted to another NH 3 molecule in liquid ammonia. (3) (f) Suggest why the strength of the C–H bond in CH4 is greater than that of the Si–H bond in SiH4. State the relationship, if any, between the strength of the covalent bond in CH 4 and the boiling temperature of CH4 (2) (Total 14 marks) 7. (a) State the type of bonding in a crystal of potassium bromide. Write an equation to show what happens when potassium bromide is dissolved in water and predict the pH of the resulting solution. (3) (b) When iodine reacts directly with fluorine, a compound containing 57.2% by mass of iodine is formed. (i) Determine the empirical formula of this compound. (ii) The empirical formula of this compound is the same as the molecular formula. Write a balanced equation for the formation of this compound. (4) (c) (i) Sketch a diagram to show the shape of a BrF3 molecule. Show on your sketch any lone pairs of electrons in the outermost shell of bromine and name the shape. (ii) BrF3 reacts with an equimolar amount of potassium fluoride to form an ionic compound which contains potassium ions. Give the formula of the negative ion produced, sketch its shape, show any lone pair(s) and indicate the value of the bond angle. (6) cranford community college 3 (Total 13 marks) 8. The table below provides some information regarding the metals sodium, magnesium and iron. M e lt in g p o in t /K M e ta llic r a d iu s /n m C r y sta l str u c tu re (a) s o d iu m m a g n e s iu m ir o n 371 923 1808 0 .1 8 6 0 .1 6 0 0 .1 2 6 b o d y -c e n tre d c lo se -p a c k e d b o d y -c e n tre d Complete the electronic configurations for the metals sodium and iron. In each case state the block in the Periodic Table to which the element belongs. (4) (b) Describe the bonding found in metals. (3) (c) Use data from table above and your knowledge of the bonding in these metals to explain why the melting point of magnesium is higher than that of sodium. (3) (d) State and explain the similarities and differences in electrical conductivity of sodium, graphite and diamond. (4) (Total 14 marks) 9. (a) (i) State one feature which molecules must have in order for hydrogen bonding to occur between them. (1) (ii) Give the name of the type of intermolecular bonding present in hydrogen sulphide, H2S, and explain why hydrogen bonding does not occur. (2) (iii) Account for the much lower boiling point of hydrogen sulphide (–61 °C) compared with that of water(100 °C). (2) (b) Protein molecules are composed of sequences of amino acid molecules that have joined together, with the elimination of water, to form long chains. Part of a protein chain is represented by the graphical formula given below. R O C C H R O N C C H H R O N C C H H R N C H H Explain the formation of hydrogen bonding between protein molecules. (4) (Total 9 marks) cranford community college 4 10. (a) Co-ordinate bonding can be described as dative covalency. In this context, what is the meaning of each of the terms covalency and dative? (2) (b) Write an equation for a reaction in which a co-ordinate bond is formed. (2) (c) Why is sodium chloride ionic rather than covalent? (2) (d) Why is aluminium chloride covalent rather than ionic? (2) (e) Why is molten sodium chloride a good conductor of electricity? (1) (f) Explain, in terms of covalent bonding, why the element iodine exists as simple molecules whereas the element carbon does not. (3) (Total 12 marks) 11. (a) When considering electron pair repulsions in molecules, why does a lone pair of electrons repel more strongly than a bonding pair? (1) (b) The diagram below shows a hydrogen peroxide molecule. H O O H (i) On the diagram above, draw the lone pairs, in appropriate positions, on the oxygen atoms. (ii) Indicate, on the diagram, the magnitude of one of the bond angles. (iii) Name the strongest type of intermolecular force which exists between molecules of hydrogen peroxide in the pure liquid. (4) (c) Draw a diagram to illustrate the shape of a molecule of SF 4 and predict the bond angle(s). (4) (d) Name two types of intermolecular force which exist between molecules in liquid SF 4 (2) (Total 11 marks) 12. The diagram below shows how a water molecule interacts with a hydrogen fluoride molecule. cranford community college 5 H O + – H F H (a) What is the value of the bond angle in a single molecule of water? (1) (b) Explain your answer to part (a) by using the concept of electron pair repulsion. (4) (c) Name the type of interaction between a water molecule and a hydrogen fluoride molecule shown in the diagram above. (1) (d) Explain the origin of the + charge shown on the hydrogen atom in the diagram. (2) (e) When water interacts with hydrogen fluoride, the value of the bond angle in water changes slightly. Predict how the angle is different from that in a single molecule of water and explain your answer (2) (Total 10 marks) 13. The diagram below represents a section of a crystal of silicon dioxide. Si O O O Si Si Si O (a) O O Name an element which has a structure similar to this. (1) (b) Name the type of bonding between silicon and oxygen in this crystal. (1) (c) Name the type of structure illustrated by this diagram. (1) (d) Describe the motion of the atoms in this crystalline solid. (2) (e) In terms of structure and bonding, describe what happens to the atoms in this crystal when it melts. (2) (f) Explain why this crystal is a non-conductor of electricity in the solid state and why graphite is a good conductor. (2) (Total 9 marks) cranford community college 6 14. Read the passage carefully and then answer the question. TUNGSTEN-HALOGEN LAMPS Incandescent lamps (those that give off light when their filaments are at high temperatures) have been in use for more than a century, and their development still continues. In recent decades, tungsten-halogen lamps have been increasingly used because of their advantages over other types. In the early days, one problem was to find a suitable material for the filament, and some attempts involved the use of graphite. Graphite is suitable because of its high melting point (about 3730 °C) and good electrical conductivity. Unfortunately, at temperatures just below its melting point, it vaporises relatively quickly and this results in the thinning of the filament, followed by breakage and consequent lamp failure. Attempts to find a better material than graphite led to the choice of tungsten which, although having a lower melting point (3410 °C), has a lower rate of vaporisation. The conversion of electrical energy to light energy is greater at higher filament temperatures, so these lamps are designed to operate at temperatures not much below the melting point of tungsten. Although pure tungsten is brittle, the metal is used in the form of an alloy, which makes it possible for very thin filaments to be manufactured. Using tungsten rather than graphite for the filament means slower vaporisation, and this allows longer lamp life. However, there is another problem. The vaporised tungsten is deposited on the inside of the wall of the lamp and results in its progressive blackening, so reducing light output. One solution is to fill the lamp with an unreactive gas to reduce vaporisation, and the effectiveness of this is greater with noble gases of higher atomic mass and at higher pressures. The relatively small size of tungsten-halogen lamps makes it feasible to use more expensive quartz glass, which is much stronger than normal lamp glass and so able to withstand higher pressures. An additional method of reducing blackening involves the use of small amounts of a halogen or halogen compound inside the lamp. Atoms of tungsten vaporised from the filament react with halogen atoms to form a tungsten halide, which is gaseous at the operating temperature of the lamp. The tungsten halide molecules mix with the other gas particles until they come close to the hot filament. When this happens the tungsten halide molecules decompose, depositing tungsten atoms on the filament and releasing halogen atoms. The halogen atoms are then free to combine with other atoms of vaporised tungsten, and so the cycle continues. tu n g s te n a to m s e v a p o ra te fro m f ila m e n t tu n g s te n fila m e n t tu n g s te n a to m s re jo in fila m e n t tu n g ste n io d id e fo rm s tu n g ste n io d id e decom p oses 5 10 15 20 25 30 io d in e a to m s fro m g a s m ix tu re io d in e a to m s re jo in g a s m ix tu re Iodine was the first halogen to be used in lamps, although others have been tried. Bromine causes increased problems of chemical attack on the colder parts of the filament, although this attack is reduced if bromine compounds, such as bromoalkanes, are used. These can be manufactured using the free radical substitution reaction between methane and bromine. cranford community college 7 35 Explain, in terms of their bonding and structures, why both graphite and tungsten have good electrical conductivities and high melting points. (Total 6 marks) 15. (a) State what is meant by the term polar bond. (1) (b) Sulphuric acid is a liquid that can be represented by the formula drawn below. O O H O H S O Given that the electronegativity values for hydrogen, sulphur and oxygen are 2.1, 2.5 and 3.5 respectively, clearly indicate the polarity of each bond present in the formula given. (2) (c) Suggest the strongest type of intermolecular force present in pure sulphuric acid. Briefly explain how this type of intermolecular force arises. (2) (Total 5 marks) 16. (a) Complete the following to show the electronic configuration of silicon. 2 2 1s 2s ........................................................................................................................ (1) (b) Write chemical equations, including state symbols, for the following enthalpy changes: the first molar ionisation energy of silicon; the second molar ionisation energy of silicon. (3) (c) Silicon dioxide has a macromolecular structure. Draw a diagram to show the arrangement of atoms around a silicon atom in silicon dioxide. Give the name of the shape of this arrangement of atoms and state the bond angle. (3) (Total 7 marks) 17. (a) Sketch the shapes of each of the following molecules, showing any lone pairs of electrons. In each case, state the bond angle(s) present in the molecule and name the shape. Molecule Sketch of shape Bond angle(s) Name of shape BF3 cranford community college 8 NF3 ClF3 (9) (b) State the types of intermolecular force which exist, in the liquid state, between pairs of BF3 molecules and between pairs of NF3 molecules. (3) (c) Name the type of bond which you would expect to be formed between a molecule of BF 3 and a molecule of NF3. Explain how this bond is able to form. (3) (Total 15 marks) 18. The diagram below shows the trend in the first ionisation energies of the elements from neon to aluminium. F irs t io n is a tio n e n e rg y N e N a M g A l Si P S E le m e n t (a) Draw crosses on the graph to show the first ionisation energies of silicon, phosphorus and sulphur. (3) (b) Write an equation to illustrate the process which occurs during the first ionisation of neon. (1) cranford community college 9 (c) Explain why the first ionisation energy of neon and that of magnesium are both higher than that of sodium. (4) (d) Explain why the first ionisation energy of aluminium is lower than that of magnesium. (2) (e) State which one of the elements neon, sodium, magnesium, aluminium and silicon has the lowest melting point and explain your answer in terms of the structure and bonding present in that element. (3) (f) State which one of the elements neon, sodium, magnesium, aluminium and silicon has the highest melting point and explain your answer in terms of the structure and bonding present in that element. (3) (Total 16 marks) 19. (a) With the aid of diagrams, describe the structure of, and bonding in, crystals of sodium chloride, graphite and magnesium. In each case, explain how the melting point and the ability to conduct electricity of these substances can be understood by a consideration of the structure and bonding involved. (23) (b) Explain how the electron-pair repulsion theory can be used to predict the shapes of the molecules H2O and PF5. Illustrate your answer with diagrams of the molecules on which the bond angles are shown. (7) (Total 30 marks) 20. The table below gives the boiling points, Tb, of some hydrogen halides. Hydrogen halide HF HCl HBr HI Tb /K 293 188 206 238 (a) By referring to the types of intermolecular force involved, explain why energy must be supplied in order to boil liquid hydrogen chloride. (3) (b) Explain why the boiling point of hydrogen bromide lies between those of hydrogen chloride and hydrogen iodide. (2) (c) Explain why the boiling point of hydrogen fluoride is higher than that of hydrogen chloride. (2) (d) Draw a sketch to illustrate how two molecules of hydrogen fluoride interact in liquid hydrogen fluoride. (2) (e) Draw sketches to predict the shape of a CIF+2 ion and the shape of a ClF5 molecule. In each case indicate, on the sketch, the bond angle value(s). (5) (Total 14 marks) 21. (a) Name the type of force that holds the particles together in an ionic crystal. cranford community college 10 (1) (b) What is a covalent bond? (1) (c) State how a co-ordinate bond is formed. (2) (d) Describe the bonding in a metal. (2) (e) A molecule of hydrogen chloride has a dipole and molecules of hydrogen chloride attract each other by permanent dipole-dipole forces. Molecules ot chlorine are non-polar. (i) What is a permanent dipole? (ii) Explain why a molecule of hydrogen chloride is polar. (iii) Name the type of force which exists between molecules of chlorine. (5) (f) Show, by means of a diagram, how two molecules of hydrogen fluoride are attracted to each other by hydrogen bonding; include all lone-pair electrons and partial charges in your diagram. (3) (g) Why is there no hydrogen bonding between molecules of hydrogen bromide? (1) (Total 15 marks) 22. (a) Describe the motion of the particles in solid iodine and in iodine vapour. (3) (b) Explain why solid iodine vaporises when warmed gently. (2) (c) Silver and sodium chloride melt at similar temperatures. Give two physical properties of silver which are different from those of sodium chloride and, in each case, give one reason why the property of silver is different from that of sodium chloride. (4) (d) Draw the shapes of BeCl2, NCl3 and BeCl 2 –4 . In each case, show any lone-pair electrons on the central atom and state the value of the bond angle. (6) (Total 15 marks) 23. (a) Aluminium, magnesium and vanadium are metals. (i) Complete the electronic configurations for aluminium and vanadium. 2 Electronic configuration of aluminium 1s ................................................. Electronic configuration of vanadium 1s ................................................. 2 (2) (ii) State the block in the Periodic Table to which magnesium belongs. (1) (b) (i) Describe the bonding that is present in metals. cranford community college 11 (3) (ii) Explain how the bonding and structure lead to the typical metallic properties of electrical conductivity and malleability. (4) (iii) Suggest a reason why aluminium is a better conductor of electricity than magnesium. (2) (Total 12 marks) 24. (a) Define the term electronegativity. (2) (b) State and explain the trend in electronegativity of the elements across Period 3 from sodium to chlorine. (3) (c) State the bond type in sodium oxide and the bond type in sulphur dioxide. In each case, explain the link between the bond type and the electronegativity of the elements involved. (4) (d) Write an equation for the reaction of sulphur trioxide with water and predict an approximate value for the pH of the resulting solution. (2) (e) Give one reason why silicon dioxide is insoluble in water. (1) (Total 12 marks) 25. (a) Describe the structure of, and bonding in, three different types of crystal. Illustrate your answer with a specific example of each type of crystal and sketch labelled diagrams of the structures. In each case, explain how the ability to conduct electricity is influenced by the type of bonding. (18) (b) Explain how the concept of bonding and lone (non-bonding) pairs of electrons can be used to predict the shape of, and bond angles in, a molecule of sulphur tetrafluoride, SF 4. Illustrate your answer with a sketch of the structure. (8) (c) Explain the circumstances in which ions are polarised, give an example and state the effect of polarisation on the type of bonding between such ions. (4) (Total 30 marks) 26. (a) The diagram below represents a part of the structure of sodium chloride. The ionic charge is shown on the centre of only one of the ions. + cranford community college 12 (i) On the diagram, mark the charges on the four negative ions. (ii) What change occurs to the motion of the ions in sodium chloride when it is heated from room temperature to a temperature below its melting point? (2) (b) Sodium chloride can be formed by reacting sodium with chlorine. (i) Write an equation for this reaction. (ii) A chloride ion has one more electron than a chlorine atom. In the formation of sodium chloride, from where does this electron come? (2) (c) In some ionic compounds the chloride ions are polarised. (i) What is a polarised chloride ion? (ii) What feature of a cation causes a chloride ion to become polarised? (2) (d) (i) What is a covalent bond? (ii) What property of the atoms joined by a covalent bond causes the bond to be polar? (3) (Total 9 marks) 27. (a) The shape of the molecule BCl3 and that of the unstable molecule CCl2 are shown below. Cl B Cl C C l C l Cl (i) Why is each bond angle exactly 120° in BCl 3? (ii) Predict the bond angle in CCl2 and explain why this angle is different from that in BCl3 Predicted bond angle ................................................................................... Explanation .................................................................................................. ...................................................................................................................... (5) (b) Give the name which describes the shape of molecules having bond angles of 109° 28'. Give an example of one such molecule. Name of shape ........................................................................................................ Example................................................................................................................... (2) cranford community college 13 (c) The shape of the XeF4 molecule is shown below. F F X e F F (i) State the bond angle in XeF4 (ii) Suggest why the lone pairs of electrons are opposite each other in this molecule. (iii) Name the shape of this molecule, given that the shape describes the positions of the Xe and F atoms only. (4) (d) Draw a sketch of the NF3 molecule. Indicate in your sketch any lone pairs of electrons on nitrogen. (2) (Total 13 marks) 28. (a) (i) Describe the bonding in a metal. (ii) Explain why magnesium has a higher melting point than sodium. (4) (b) Why do diamond and graphite both have high melting points? (3) (c) Why is graphite a good conductor of electricity? (1) (d) Why is graphite soft? (2) (Total 10 marks) 29. (a) An ammonium ion, made by the reaction between an ammonia molecule and a hydrogen ion, can be represented as shown in the diagram below. + H H N H H (i) Name the type of bond represented in the diagram by N—H (ii) Name the type of bond represented in the diagram by NH (iii) In terms of electrons, explain why an arrow is used to represent this NH bond. + (iv) In terms of electron pairs, explain why the bond angles in the NH 4 ion are all 109° 28’ (7) (b) Define the term electronegativity. (2) cranford community college 14 (c) δ A bond between nitrogen and hydrogen can be represented as N δ H (i) In this representation, what is the meaning of the symbol + ? (ii) From this bond representation, what can be deduced about the electronegativity of hydrogen relative to that of nitrogen? (2) (Total 11 marks) 30. The table below shows some values of melting points and some heat energies needed for melting. Substance I2 NaCl HF HCl HI Melting point/K 387 1074 190 158 222 7.9 28.9 3.9 2.0 2.9 Heat energy for melting /kJ mol (a) –1 Name three types of intermolecular force. (3) (b) (i) Describe the bonding in a crystal of iodine. (ii) Name the crystal type which describes an iodine crystal. (iii) Explain why heat energy is required to melt an iodine crystal. (4) (c) In terms of the intermolecular forces involved, suggest why (i) hydrogen fluoride requires more heat energy for melting than does hydrogen chloride, (ii) hydrogen iodide requires more heat energy for melting than does hydrogen chloride. (5) (d) (i) Explain why the heat energy required to melt sodium chloride is large. (ii) The heat energy needed to vaporise one mole of sodium chloride (171 kJ mol ) is much greater than the heat energy required to melt one mole of sodium chloride. Explain why this is so. –1 (3) (e) In terms of its structure and bonding, suggest why graphite has a very high melting point. (2) (Total 17 marks) 31. (a) Predict the shapes of the SF6 molecule and the AlCl 4– ion. Draw diagrams of these species to show their three-dimensional shapes. Name the shapes and suggest values for the bond angles. Explain your reasoning. (8) (b) Perfume is a mixture of fragrant compounds dissolved in a volatile solvent. When applied to the skin the solvent evaporates, causing the skin to cool for a short time. After a while, the fragrance may be detected some distance away. Explain these cranford community college 15 observations. (4) (Total 12 marks) 32. (a) (i) Complete the electronic configuration of aluminium. 2 1s .................................................................................................................... (ii) State the block in the Periodic Table to which aluminium belongs. (2) (b) Describe the bonding in metals. (2) (c) Explain why the melting point of magnesium is higher than that of sodium. (3) (d) Explain how metals conduct electricity. (2) (Total 9 marks) 33. (a) Both HF and HCl are molecules having a polar covalent bond. Their boiling points are 293 K and 188 K respectively. (i) State which property of the atoms involved causes a bond to be polar. (ii) Explain, in terms of the intermolecular forces present in each compound, why HF has a higher boiling point than HCl. (4) (b) When aluminium chloride reacts with chloride ions, as shown by the equation below, a co-ordinate bond is formed. AlCl3 + Cl – AlCl4– Explain how this co-ordinate bond is formed. (2) (c) + Draw the shape of the PCl5 molecule and of the PCl4 ion. State the value(s) of the bond angles. (4) (Total 10 marks) 34. (a) Iodine and graphite crystals both contain covalent bonds and yet the physical properties of their crystals are very different. For iodine and graphite, state and explain the differences in their melting points and in their electrical conductivities. (9) (b) Draw the shape of the BeCl2 molecule and explain why it has this shape. 2+ – State and explain the effect that an isolated Be ion would have on an isolated Cl ion and explain how this effect would lead to the formation of a covalent bond. Give one chemical property of Be(OH)2 which is atypical of the chemistry of Group II hydroxides. (6) (Total 15 marks) 35. (a) Name the strongest type of intermolecular force between hydrogen fluoride molecules cranford community college 16 and draw a diagram to illustrate how two molecules of HF are attracted to each other. In your diagram show all lone pairs of electrons and any partial charges. Explain the origin of these charges. Suggest why this strong intermolecular force is not present between HI molecules. (7) (b) Crystals of sodium chloride and of diamond both have giant structures. Their melting points are 1074 K and 3827 K, respectively. State the type of structure present in each case and explain why the melting point of diamond is so high. (4) (Total 11 marks) 36. (a) Magnesium and chlorine react together to form the ionic compound magnesium chloride, MgCl2. (i) Explain how each of the ions in this compound is formed. (ii) Explain why compounds with ionic bonding tend to have high melting points. (4) (b) (i) Define the term electronegativity. (ii) Explain why electronegativity increases across a period in the Periodic Table. (4) (c) Chloride ions are polarised more by aluminium ions than they are by magnesium ions. (i) State what is meant by the term polarised. (ii) Why is a chloride ion polarised more by an aluminium ion than by a magnesium ion? (iii) Predict the type of bonding in aluminium chloride. (5) (Total 13 marks) 37. Iodine and diamond are both crystalline solids at room temperature. Identify one similarity in the bonding, and one difference in the structures, of these two solids. Explain why these two solids have very different melting points. (Total 6 marks) 38. Phosphorus and nitrogen are in Group V of the Periodic Table and both elements form hydrides. Phosphine, PH3, reacts to form phosphonium ions, PH 4 , in a similar way to that by which ammonia, NH3, forms ammonium ions, NH 4 (a) + Give the name of the type of bond formed when phosphine reacts with an H ion. Explain how this bond is formed. (3) (b) Draw the shapes, including any lone pairs of electrons, of a phosphine molecule and of a phosphonium ion. Give the name of the shape of the phosphine molecule and state the bond angle found in the phosphonium ion. (4) (Total 7 marks) 39. Diamond and graphite are both forms of carbon. Diamond is able to scratch almost all other substances, whereas graphite may be used as a cranford community college 17 lubricant. Diamond and graphite both have high melting points. Explain each of these properties of diamond and graphite in terms of structure and bonding. Give one other difference in the properties of diamond and graphite. (Total 9 marks) 40. The table below shows the electronegativity values of some elements. Electronegativity (a) Fluorine Chlorine Bromine Iodine Carbon Hydrogen 4.0 3.0 2.8 2.5 2.5 2.1 Define the term electronegativity. (2) (b) The table below shows the boiling points of fluorine, fluoromethane (CH 3F ) and hydrogen fluoride. F–F H–F F C H Boiling point/K (i) 85 H H 194 293 Name the strongest type of intermolecular force present in: Liquid F2 ......................................................................................................... Liquid CH3F ................................................................................................... Liquid HF ....................................................................................................... (ii) Explain how the strongest type of intermolecular force in liquid HF arises. (6) (c) The table below shows the boiling points of some other hydrogen halides. Boiling point / K HCl HBr HI 188 206 238 (i) Explain the trend in the boiling points of the hydrogen halides from HCl to HI. (ii) Give one reason why the boiling point of HF is higher than that of all the other hydrogen halides. (3) (Total 11 marks) 41. Phosphorus exists in several different forms, two of which are white phosphorus and red phosphorus. White phosphorus consists of P4 molecules, and melts at 44°C. Red phosphorus is macromolecular, and has a melting point above 550°C. Explain what is meant by the term macromolecular. By considering the structure and bonding present in these two forms of phosphorus, explain why their melting points are so different. (Total 5 marks) cranford community college 18 42. The equation below shows the reaction between boron trifluoride and a fluoride ion. – BF3 + F → BF 4– (i) Draw diagrams to show the shape of the BF3 molecule and the shape of the BF 4– ion. In each case, name the shape. Account for the shape of the BF 4– ion and state the bond angle present. (ii) In terms of the electrons involved, explain how the bond between the BF 3 molecule and – the F ion is formed. Name the type of bond formed in this reaction. (Total 9 marks) cranford community college 19