MATERIAL SAFETY DATA SHEETPRODUCT EC9017A EMERGENCY TELEPHONE NUMBER(S) (800) 424-9300 (24 Hours) CHEMTREC 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME : EC9017A APPLICATION : ANTIFOAM COMPANY IDENTIFICATION : Nalco Energy Services, L.P. P.O. Box 87 Sugar Land, Texas 77487-0087 EMERGENCY TELEPHONE NUMBER(S) : (800) 424-9300 (24 Hours) NFPA 704M/HMIS RATING HEALTH : 2/2 FLAMMABILITY : 2/2 INSTABILITY : 0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme 2. CHEMTREC 0/0 OTHER : COMPOSITION/INFORMATION ON INGREDIENTS Our hazard evaluation has identified the following chemical substance(s) as hazardous. Consult Section 15 for the nature of the hazard(s). Hazardous Substance(s) Kerosene 3. CAS NO 8008-20-6 % (w/w) 60.0 - 100.0 HAZARDS IDENTIFICATION **EMERGENCY OVERVIEW** WARNING Combustible. Irritating to eyes and skin. Keep away from heat. Keep away from sources of ignition - No smoking. Keep container tightly closed. Do not get in eyes, on skin, on clothing. Avoid breathing vapor. Use with adequate ventilation. Do not take internally. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of soap and water. Wear suitable protective clothing, gloves and eye/face protection. Empty product containers may contain product residue. Do not pressurize, cut, heat, weld, or expose containers to flame or other sources of ignition. Flammable Liquid; may release vapors that form flammable mixtures at or above the flash point. May evolve oxides of carbon (COx) under fire conditions. PRIMARY ROUTES OF EXPOSURE : Eye, Skin, Inhalation HUMAN HEALTH HAZARDS - ACUTE : EYE CONTACT : Can cause moderate irritation. Nalco Energy Services, L.P. P.O. Box 87 • Sugar Land, Texas 77487-0087 • (281)263-7000 For additional copies of an MSDS visit www.nalco.com and request access 1 / 11 Chronic : Frequent or prolonged contact with product may defat and dry the skin. May cause nausea and vomiting.O. P. INGESTION : Not a likely route of exposure. L. Can cause central nervous system depression. Get medical attention. 5. HUMAN HEALTH HAZARDS . INHALATION : Remove to fresh air. Texas 77487-0087 • (281)263-7000 For additional copies of an MSDS visit www. the physician's judgement should be used to control symptoms and clinical condition. seek medical advice. The relationship of these results to humans has not been fully established.P. washout mouth and give water to drink.CHRONIC : Contains kerosene. Get medical attention. Lifetime skin painting tests with fuels and certain fuel fractions derived from crude oil and cracked stocks. stupor or unconsciousness. vomiting. FIRE FIGHTING MEASURES FLASH POINT : 110 °F / 43 °C ( TCC ) Nalco Energy Services.MATERIAL SAFETY DATA SHEET PRODUCT EC9017A EMERGENCY TELEPHONE NUMBER(S) (800) 424-9300 (24 Hours) CHEMTREC SKIN CONTACT : Can cause moderate irritation.com and request access 2 / 11 . treat symptomatically. If symptoms develop. Can cause chemical pneumonia if aspirated into lungs following ingestion. SYMPTOMS OF EXPOSURE : Acute : Inhalation of high concentrations of organic solvents can cause nausea. 4.nalco. SKIN CONTACT : Immediately wash with plenty of soap and water. If conscious. seek medical advice. AGGRAVATION OF EXISTING CONDITIONS : Skin contact may aggravate an existing dermatitis condition. leading to discomfort and dermatitis. FIRST AID MEASURES EYE CONTACT : Immediately flush eye with water for at least 15 minutes while holding eyelids open. boiling between 175-370 deg C have shown that these middle distillate materials can produce tumors and/or cancers in laboratory mice. If symptoms develop. INHALATION : Repeated or prolonged exposure may irritate the respiratory tract. NOTE TO PHYSICIAN : Based on the individual reactions of the patient. INGESTION : Do not induce vomiting: contains petroleum distillates and/or aromatic solvents. Box 87 • Sugar Land. dizziness. Other extinguishing agent suitable for Class B fires. occupational health and safety and environmental authorities. may release vapors that form flammable mixtures at or above the flash point. Wash affected area. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS : Restrict access to area as appropriate until clean-up operations are complete. Nalco Energy Services. or expose containers to flame or other sources of ignition. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING : In case of fire. METHODS FOR CLEANING UP : SMALL SPILLS: Soak up spill with absorbent material. Carbon dioxide. Ensure clean-up is conducted by trained personnel only. P. etc.P.com and request access 3 / 11 . Ventilate spill area if possible.) readily available. Stop or reduce any leaks if it is safe to do so. Do not pressurize. on skin.O. Water mist may be used to cool closed containers.MATERIAL SAFETY DATA SHEET PRODUCT EC9017A EMERGENCY TELEPHONE NUMBER(S) (800) 424-9300 (24 Hours) CHEMTREC LOWER EXPLOSION LIMIT : 1 V% UPPER EXPLOSION LIMIT : 6 V% EXTINGUISHING MEDIA : Alcohol foam. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). Dry powder. covered. Vapors are much heavier than air. FIRE AND EXPLOSION HAZARD : Empty product containers may contain product residue. Texas 77487-0087 • (281)263-7000 For additional copies of an MSDS visit www. Have emergency equipment (for fires. Reclaim into recovery or salvage drums or tank truck for proper disposal. Foam. by digging trenches or by diking. May evolve oxides of carbon (COx) under fire conditions. Flammable Liquid. properly labeled container. Contact an approved waste hauler for disposal of contaminated recovered material. Clean contaminated surfaces with water or aqueous cleaning agents. Remove sources of ignition. UNSUITABLE EXTINGUISHING MEDIA : Do not use water unless flooding amounts are available. this can result in uneven distribution. L. Box 87 • Sugar Land. leaks. Keep the containers closed when not in use. Place residues in a suitable. LARGE SPILLS: Contain liquid using absorbent material. For large fires. on clothing. heat. Do not touch spilled material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations). Notify appropriate government. thoroughly drenching the burning material. Do not get in eyes. HANDLING AND STORAGE HANDLING : Use with adequate ventilation. wear a full face positive-pressure self contained breathing apparatus and protective suit. weld. use water spray or fog. leaks. Do not use in locations where vapor is likely to travel to welding flames or arcs or to other hot surfaces. Have emergency equipment (for fires.nalco. Do not breathe vapors/gases/dust. spills. 6. spills. etc. 7. ENVIRONMENTAL PRECAUTIONS : Prevent material from entering sewers or waterways. cut.) readily available. Do not take internally. Nalco Energy Services. 1. HAND PROTECTION : Nitrile gloves.nalco.MATERIAL SAFETY DATA SHEET PRODUCT EC9017A EMERGENCY TELEPHONE NUMBER(S) (800) 424-9300 (24 Hours) CHEMTREC STORAGE CONDITIONS : Store away from heat and sources of ignition. training. maintenance and inspection.P. Available exposure limits for the substance(s) are shown below. EYE PROTECTION : Wear chemical splash goggles. SUITABLE CONSTRUCTION MATERIAL : Compatibility with Plastic Materials can vary. full-facepiece SCBA should be used. In event of emergency or planned entry into unknown concentrations a positive pressure. Store separately from oxidizers. vapors or aerosols are generated an approved respirator is recommended. Use proper grounding procedures. Texas 77487-0087 • (281)263-7000 For additional copies of an MSDS visit www. L. If respiratory protection is required. institute a complete respiratory protection program including selection. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION OCCUPATIONAL EXPOSURE LIMITS : Exposure guidelines have not been established for this product. Polyvinyl alcohol gloves SKIN PROTECTION : Wear impervious apron and boots. RESPIRATORY PROTECTION : If significant mists. we therefore recommend that compatibility is tested prior to use. fit testing.com and request access 4 / 11 .200 mg/m3 ENGINEERING MEASURES : Use general ventilation with local exhaust ventilation. Viton# gloves. Have appropriate fire extinguishers available in and near the storage area.O. Box 87 • Sugar Land. An organic vapor cartridge with dust/mist prefilter or supplied air may be used. P. ACGIH/TLV : Substance(s) Oil Mist OSHA/PEL : Substance(s) Oil Mist TWA: 5 mg/m3 STEL: 10 mg/m3 TWA: 5 mg/m3 STEL: 10 mg/m3 Manufacturer's Recommendation : Substance(s) Kerosene TWA: 165 ppm . Store the containers tightly closed. P.com and request access 5 / 11 .8691 @ 77 °F / 25 °C 6. STABILITY AND REACTIVITY STABILITY : Stable under normal conditions. perchlorate. If clothing is contaminated.g. Texas 77487-0087 • (281)263-7000 For additional copies of an MSDS visit www. MATERIALS TO AVOID : Contact with strong oxidizers (e. nitric acid.7.0. peroxides. HUMAN EXPOSURE CHARACTERIZATION : Based on our recommended product application and personal protective equipment. permanganate) may generate heat. the potential human exposure is: Low 9. chromates. CONDITIONS TO AVOID : Heat and sources of ignition including static discharges.1 % Calculated Note: These physical properties are typical values for this product and are subject to change. Keep a safety shower available. TOXICOLOGICAL INFORMATION No toxicity studies have been conducted on this product.O.22 lb/gal Insoluble 70 .MATERIAL SAFETY DATA SHEET PRODUCT EC9017A EMERGENCY TELEPHONE NUMBER(S) (800) 424-9300 (24 Hours) CHEMTREC HYGIENE RECOMMENDATIONS : Keep an eye wash fountain available. explosions and/or toxic vapors. Nalco Energy Services. Box 87 • Sugar Land.88 . concentrated oxygen. fires. remove clothing and thoroughly wash the affected area.nalco. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE Liquid APPEARANCE Milky Yellow ODOR Hydrocarbon SPECIFIC GRAVITY DENSITY SOLUBILITY IN WATER VISCOSITY POUR POINT VAPOR PRESSURE VOC CONTENT 0. chlorine.130 cst @ 77 °F / 25 °C -40 °F / -40 °C 1 . L. P. 10.10 mm Hg @ 100 °F / 38 °C 74.8291 . HAZARDOUS DECOMPOSITION PRODUCTS : Under fire conditions: Oxides of carbon 11. HAZARDOUS POLYMERIZATION : Hazardous polymerization will not occur. Launder contaminated clothing before reuse. The level III model does not require equilibrium between the defined media. ECOLOGICAL INFORMATION ECOTOXICOLOGICAL EFFECTS : The following results are for the product. L.90% The portion in water is expected to float on the surface. ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION Based on our hazard characterization. boiling between 175-370 deg C have shown that these middle distillate materials can produce tumors and/or cancers in laboratory mice. CARCINOGENICITY : Contains kerosene.30% Soil/Sediment 70 . The model assumes a steady state condition between the total input and output. The relationship of these results to humans has not been fully established. Box 87 • Sugar Land. see CERCLA/SUPERFUND in Section 15. Nalco Energy Services. Lifetime skin painting tests with fuels and certain fuel fractions derived from crude oil and cracked stocks. Texas 77487-0087 • (281)263-7000 For additional copies of an MSDS visit www. HUMAN HAZARD CHARACTERIZATION : Based on our hazard characterization. ACUTE FISH RESULTS : Species Fathead Minnow Exposure 96 hrs LC50 1. P.908 mg/l ACUTE INVERTEBRATE RESULTS : Species Exposure Ceriodaphnia dubia 48 hrs LC50 4.O. the potential environmental exposure is: Low If released into the environment.MATERIAL SAFETY DATA SHEET PRODUCT EC9017A EMERGENCY TELEPHONE NUMBER(S) (800) 424-9300 (24 Hours) CHEMTREC SENSITIZATION : This product is not expected to be a sensitizer.P.com and request access 6 / 11 .nalco.063 mg/l Test Descriptor Product EC50 Test Descriptor Product MOBILITY : The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program interface) Suite TM . water and soil/sediment in the approximate respective percentages. the potential environmental hazard is: Moderate Based on our recommended product application and the product's characteristics. the potential human hazard is: Moderate 12. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models. Air <5% Water 10 . If released into the environment this material is expected to distribute to the air. BIOACCUMULATION POTENTIAL Component substances have a potential to bioconcentrate. provided by the US EPA. TRANSPORT INFORMATION The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. it could meet the criteria of a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.MATERIAL SAFETY DATA SHEET PRODUCT EC9017A EMERGENCY TELEPHONE NUMBER(S) (800) 424-9300 (24 Hours) CHEMTREC 13. disposal or recycling facility.Primary : Packing Group : IATA Cargo Packing Instructions : IATA Cargo Aircraft Limit : PETROLEUM DISTILLATES.S. P.Primary : Packing Group : Flash Point : PRODUCT IS NOT REGULATED DURING TRANSPORTATION PETROLEUM DISTILLATES.S. Before disposal. N.S. L.P.O. UN 1268 3 III 310 220 L (Max net quantity per package) MARINE TRANSPORT (IMDG/IMO) : Proper Shipping Name : Technical Name(s) : UN/ID No : PETROLEUM DISTILLATES. and federal regulations for specific requirements. Consult local.com and request access 7 / 11 .O. Typical Proper Shipping Names for this product are as follows.nalco. Box 87 • Sugar Land. Hazardous Waste: D001 Hazardous wastes must be transported by a licensed hazardous waste transporter and disposed of or treated in a properly licensed hazardous waste treatment. Please note that the proper Shipping Name / Hazard Class may vary by packaging. storage.O. state. properties. N. DISPOSAL CONSIDERATIONS If this product becomes a waste.O. UN 1268 COMBUSTIBLE III 43 °C / 110 °F AIR TRANSPORT (ICAO/IATA) : Proper Shipping Name : Technical Name(s) : UN/ID No : Hazard Class . it should be determined if the waste meets the criteria of a hazardous waste. LAND TRANSPORT : For Packages Less Than Or Equal To 119 Gallons: Proper Shipping Name : For Packages Greater Than 119 Gallons: Proper Shipping Name : Technical Name(s) : UN/ID No : Hazard Class . UN 1268 Nalco Energy Services. Texas 77487-0087 • (281)263-7000 For additional copies of an MSDS visit www. and mode of transportation. 14. N. Texas 77487-0087 • (281)263-7000 For additional copies of an MSDS visit www. Sec. Box 87 • Sugar Land. 40 CFR 116.1200 : Based on our hazard evaluation.MATERIAL SAFETY DATA SHEET PRODUCT EC9017A EMERGENCY TELEPHONE NUMBER(S) (800) 424-9300 (24 Hours) CHEMTREC Hazard Class . The current thresholds are: 500 pounds or the threshold planning quantity (TPQ). USA : OSHA HAZARD COMMUNICATION RULE. CLEAN AIR ACT. 40 CFR 117. 111 (40 CFR 60. 307. P. 40 CFR 401. SECTIONS 311 AND 312 . 29 CFR 1910. whichever is lower.com and request access 8 / 11 . Sec. CERCLA/SUPERFUND. The product should be reported under the following indicated EPA hazard categories: X X - Immediate (Acute) Health Hazard Delayed (Chronic) Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Under SARA 311 and 312. AND 313 : SECTION 302 . Nalco Energy Services.O.SECTIONS 302. Kerosene : Skin irritant. SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) . 112 (40 CFR 61. 311. Hazardous Air Pollutants).15 / formerly Sec. Sec. the EPA has established threshold quantities for the reporting of hazardous chemicals. 602 (40 CFR 82.000 pounds for all other hazardous chemicals.4 / formerly Sec. Class I and II Ozone Depleting Substances) : None of the substances are specifically listed in the regulation.Primary : Packing Group : 15. L.MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370) : Our hazard evaluation has found this product to be hazardous. for extremely hazardous substances and 10. TOXIC SUBSTANCES CONTROL ACT (TSCA) : The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710) FEDERAL WATER POLLUTION CONTROL ACT. CLEAN WATER ACT. Combustible. SECTION 313 . the following substance(s) in this product is/are hazardous and the reason(s) is/are shown below. Volatile Organic Compounds).nalco. 3 III REGULATORY INFORMATION NATIONAL REGULATIONS. 311 : None of the substances are specifically listed in the regulation.LIST OF TOXIC CHEMICALS (40 CFR 372) : This product does not contain substances on the List of Toxic Chemicals. 312.EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355) : This product does not contain substances listed in Appendix A and B as an Extremely Hazardous Substance. 302 : Notification of spills of this product is not required.P. WHMIS CLASSIFICATION : B3 . L. EUROPE The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories. CANADA : WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS) : This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. or have been reported in accordance with the New Substances Notification Regulations.O. MICHIGAN CRITICAL MATERIALS : None of the substances are specifically listed in the regulation. P.com and request access 9 / 11 . D2B . STATE RIGHT TO KNOW LAWS : The following substances are disclosed for compliance with State Right to Know Laws: Kerosene 8008-20-6 NATIONAL REGULATIONS. Box 87 • Sugar Land.MATERIAL SAFETY DATA SHEET PRODUCT EC9017A EMERGENCY TELEPHONE NUMBER(S) (800) 424-9300 (24 Hours) CHEMTREC CALIFORNIA PROPOSITION 65 : This product does not contain substances which require warning under California Proposition 65.Materials Causing Other Toxic Effects . Texas 77487-0087 • (281)263-7000 For additional copies of an MSDS visit www.Combustible Liquids.P. JAPAN All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Ministry of International Trade & industry List (MITI).nalco. INTERNATIONAL CHEMICAL CONTROL LAWS AUSTRALIA All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme (NICNAS).Toxic Material CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) : The substances in this preparation are listed on the Domestic Substances List (DSL). KOREA All substances in this product comply with the Toxic Chemical Control Law (TCCL) and are listed on the Existing Chemicals List (ECL) Nalco Energy Services. are exempt. CHINA All substances in this product comply with the Chemical Control Law and are listed on the Inventory of Existing Chemical Substances China (IECSC). The product is to be used in applications consistent with our product literature. 16. Micromedex.P. Toxic and Hazardous Substances. Texas 77487-0087 • (281)263-7000 For additional copies of an MSDS visit www. Occupational Safety and Health Administration (OSHA). MD. Public Health Service. Annual Report on Carcinogens. IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man. International Agency for Research on Cancer..com and request access 10 / 11 . Englewood. exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. We have evaluated our product's risk as follows: * The human risk is: Low * The environmental risk is: Low Any use inconsistent with our recommendations may affect the risk characterization.. Inc. CO. Together we can implement an appropriate risk management process. (TOMES CPS# CDROM Version).MATERIAL SAFETY DATA SHEET PRODUCT EC9017A EMERGENCY TELEPHONE NUMBER(S) (800) 424-9300 (24 Hours) CHEMTREC THE PHILIPPINES All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippine Inventory of Chemicals & Chemical Substances (PICCS). (TOMES CPS# CD-ROM Version).C. U. Maryland (TOMES CPS# CD-ROM Version). Englewood. CO. Registry of Toxic Effects of Chemical Substances. Inc. MD. L. REFERENCES Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices. P.O. Bethesda. we have characterized the product's general risk. Integrated Risk Information System. (Ariel Insight# CD-ROM Version). Washington. Geneva: World Health Organization. For any other uses. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. Based on our recommended use of this product. OH. U. Subpart Z. Our sales representative will assist you to determine if your product application is consistent with our recommendations..nalco. Micromedex.. (Ariel Insight# CD-ROM Version).S. Englewood. Part 1910. Department of Health and Human Services. Bethesda. Title 29 Code of Federal Regulations. Micromedex. Ariel Research Corp. Hazardous Substances Data Bank. American Conference of Governmental Industrial Hygienists. CO. OTHER INFORMATION F102595 Due to our commitment to Product Stewardship. National Library of Medicine. Ariel Research Corp. Nalco Energy Services. Inc. This product material safety data sheet provides health and safety information. Cincinnati. Bethesda. Environmental Protection Agency. D. National Institute for Occupational Safety and Health. This information should provide assistance for your own risk management practices.S. Please consult your local sales representative for any further information... Box 87 • Sugar Land. we have evaluated the human and environmental hazards and exposures of this product. National Toxicology Program. OH. P. Englewood.P. Prepared By : Product Safety Department Date issued : 06/27/2005 Version Number : 1. CO.nalco.MATERIAL SAFETY DATA SHEET PRODUCT EC9017A EMERGENCY TELEPHONE NUMBER(S) (800) 424-9300 (24 Hours) CHEMTREC Ariel Insight# (An integrated guide to industrial chemicals covered under major regulatory and advisory programs).. Seattle. Chemical Inventories Module and the Generics Module (Ariel Insight# CD-ROM Version). Micromedex.O. The Teratogen Information System. Bethesda. WA (TOMES CPS# CD-ROM Version). Western European Module. L. University of Washington. Texas 77487-0087 • (281)263-7000 For additional copies of an MSDS visit www. Inc. Ariel Research Corp..com and request access 11 / 11 . MD. North American Module.11 Nalco Energy Services. Box 87 • Sugar Land.