Additive‘sever creative and innovative for the polymer industry Profile of • Foundation 1917 • Business – Chemicals & Foods • Paid-in capital – 206 Million US$ • Turnover 2005 – Consolidated: 1.1 Billion US$ • A member of Furukawa Group corporation .5 Billion US $ – Single: 1. ADEKA Worldwide Location . and Plants in Japan 3 R&D Lab. SOHMA KUKI OGU KASHIMA-NISHI URAWA KASHIMA CHIBA AKASHI MIE 6 Plants .R&D Lab. Qualitiy Assurance System • Quality Assurance very important » 1t Stabilizer hundreds tons of resin • ISO 14001 certified in 1996 – earliest of all Japanese manufacturers • ISO 9001 certified in 2002 • OHSAS certified in 2001 . Organisation in Europe . Sales Profile Net Sales: $ 1.5 billion (2005/04-2006/03) Polymer Additives Foods IT related Chemicals Other Chemicals Epoxy Resins Surfactants Lubricants Others . ADDITIVES PRODUCT LINE UP Antioxidants (AO Series) UV Absorber (LA Series) POLYOLEFINS & ENGINEERING PLASTICS Plastic Articles Plastic Articles Hindered Amine Light Stabilizers (LA Series) Automotive Applications Nucleators / Clarifiers Automotive Applications Food Packaging (NA Series) Flame Retardants (FP Series) Electronic Appliances Construction Applications Plasticizers General Purpose & High Performance Stabilizers General Purpose & High Performance PVC . 330 Antioxidant for elastomers and styrenics Antioxidant with low extractability ADK STAB AO-50F PALMAROLE AO.STDP General purpose antioxidant for styrenics Special antioxiant for polyamides General purpose thiosynergist ADK STAB AO-40 PALMAROLE AO. styrenics TNPP ADK STAB PEP-24G ADK STAB 2112 General purpose process stabiliser for polyolefins General purpose processing antioxidant Full range of liquid phosphites.ADK STAB A611: AO 60/2112 (1:1) . Costabilization of PVC and elastomers .ADK STAB A612: AO 60/2112 (1:2) .ADK STAB A514: AO 50/2112 (1:4) •Blends ADK STAB AO60/2112 with different ratios •Blends with phenolic phosphites .OH.570 General purpose antioxidant Specific antioxidant for POM and styrenics ADK STAB AO-60 General purpose antioxidant Phosphites AO Binary Blends ADK STAB HP-10 ADK STAB PEP-36 High performance phosphite for polyolefins such as LLDPE High performance phosphite with high hydrolysis resistance and thermal stability ADK STAB PEP-8HT ADK STAB 1178 General purpose phosphite for polymers such as polyolefins.S.OH.ANTIOXIDANTS Sulphor containing AO Phenolic AO ADK STAB AO-20 ADK STAB AO-80 ADK STAB AO-26 ADK STAB AO-412S Antioxidant with low extractability for PP fibres High performance antioxidant for PP fibres. engineering plastics Antioxidant for w&c (crosslinked PE) Thiosynergist for high temperature applications ADK STAB AO-30 PALMAROLE AO.98 PALMAROLE AO.OH. Excellent thermostability.10 PALMAROLE MDA. whilst maintaining impact properties and cycle time reduction ADK STAB NA-901 / NA-902 New generation designes for benzoates replacement PALMAROLE MI.11 Traditional copper deactivator Mainly used in polyolefin for wire and cable application .NA.P.P.20 General purpose nucleating agents (benzoates) CLARIFYING AGENTS ADK STAB NA-21 Metal salt of organic phosphate providing increased transparency of homo and random PP as well as enhancement of mechanical properties.NUCLEATING AGENTS ADK STAB NA-11UH Organic phosphate salt providing increased stiffness. no deposit ADK STAB NA-71 New clarifying agent particularly for blow moulding applications METAL DEACTIVATORS ANTISTATIC AGENTS ADK STAB CDA-1 ADK STAB ZS-90 ADK STAB AS-113 PALMAROLE STAT-09 ADK STAB CDA-6 For deactivation of iron and other metallic contaminants Specifically for PC/ABS alloys Distilled GMS for polyolefins High temperature copper deactivator PALMAROLE MDA.NA. no odour.08 / PALMAROLE MI. Acid neutraliser . at 1200 ppm. 20% loading in PP is sufficient to attain UL-94/V-0 rating (1.FLAME RETARDANTS Phosphate-based low volatility flame retardants ADK STAB FP-700 / FP-600 Intumescent system ADK STAB FP-2100J / FP-2200 New nitrogen-phoshorus based FR with high flame retardancy and good physical properties •Can be processed at high temperature •Excellent colour stability •High water resistance •Approx.Acid neutraliser Synthetic hydrotalcite. headache.6mm) *Physiological effects of CO. Death within 1 hour CO-STABILIZERS ADK CIZER EP-17 PALMAROLE HT Epoxy. dizziness and nausea within 20 minutes. E / BA.C5.S / BA.S / BA.K4.M4.F3.K2.S1 / BA.S / BA.BLOWING AGENTS Extrusion process Injection moulding process PE / PP Resins BA.E / BA.F4.E / BA.F2.E / BA.E / BA.S BA.F2.M2.K3.E / BA.K2.S / EXP 141-92B are mainly used for extruded sheets with medium and fine cells structure respectively thermoforming applications .K2.K2.E are mainly used for sink mark removal are mainly used for extruded profiles and sheets applications with coarse or medium cells structure BA.S / BA.S are mainly used for weight reduction Engineering Resins BA.K2.EF are mainly used for sink mark removal are mainly used for extruded films and sheets with very fine cell structure.F4 / BA.EF are mainly used for weight reduction are mainly used for extruded films and sheets applications with very fine cells structure PS / ABS Resins PS Resins BA.S / BA.F4.E BA.K5.F4.M4.K5.P are mainly used for sink mark removal BA.M7.E are mainly used for weight reduction PET Resins BA.E BA.K2.F4. for thermoforming application BA. tailor-made color…) TRIBOLOGICAL COMPOUNDS – TISMO REINFORCED COMPOUNDS Especially suitable for small-size precision parts PALMAROLE BMNY BZ TL TOLL COMPOUNDING Compound highly filled with Bronze beads On various engineering plastics .ADDITIVES PREPARATIONS ADDITIVES PREPARATIONS Melt blends (MBA) and/or compacted blends (CB) of additives ADDITIVES MASTERBATCHES Both cutom-made and proprietary HIGH PERFORMANCE COMPOUNDS ORGATER® PBT based compounds (reinforced. fireproofed. 087 Benzotriazoles ADK STAB LA-502 and LA-402 XP PALMAROLE LS.UV ABSORBER HALS Absorb UV light for polymer protection or UV screening Provide very efficient light and heat protection for plastics and coatings ADK STAB LA-31RG ADK STAB LA-46 ADK STAB LA-53 ADK STAB LA-63 Extremely low volatility and especially suited for engineering plastics Triazine type of UV absorber with excellent thermostability Methylated HALS High molecular weight light stabiliser specially for use in thin section products ADK STAB LA-62 ADK STAB LA-81 Liquid.BO.141 PALMAROLE LS.080 PALMAROLE LS.BT.550 Particularly for filled and/or pigmented PP with low extractability.100 PALMAROLE LS.BO. Press at 180°C to 80µm thick film •Weathering test Sunshine weather meter at 63°C. no discoloration and excellent light stability HALS PALMAROLE HALS 77 Weatherability of LDPE film after sulfor fumigation •Formulation LDPE(100) / ADK STAB AO-60(0.BT. also for coatings New NOR-HALS Benzophenones PALMAROLE LS.BT.05) •Process Extrusion at 200°C.05) / ADK STAB 2112(0.013 PALMAROLE LS.BT. water spray PALMAROLE HALS 94 . heat stability and colour holding Used in flexible and semi-rigid films and sheets: Furniture and decorative applications. to be used with co-stabilizers for other flexible S-PVC applications for example •ADK STAB SP-96 used for food-contact pipe. special ageing and demoulding requirements . pond liners. ADK STAB RUP 190 / ADK STAB RUP 167 ET ADK STAB AC-series: Nonyl phenol-free Ba Zn stabilizers. SP-series: Liquid & solid Ca Zn stabilizers. swimming pools. colour holding and thermal ageing used in automotive.STABILIZERS AND PLASTICIZER FOR PVC For flexible PVC applications ADK STAB RUP-100 series: Ca Mg Zn stabilizers for wire & cable PVC applications Excellent electrical. building wire. ADK STAB SC-series. hoses ad sheet Custom-made stabilizer: Lead-free formulations for special PVC based automotive applications and Plastisol / E-PVC Customized recipes according to specifications and processing methods taking into account low VOC requirements. stationery films. power cable applications for example •70°C to 105°C service temperature: ADK STAB RUP 185 E/ RUP 110ET / RUP 112 •above 105°C (automotive class III). roofing membranes. civil engineering liners. to be used with co-stabilizers for calandering PVC application Excellent transparency. adhesive & marking films etc. 5 – 6 PHR •Wood Profile Composite (WPC) (corestabilizers+customized processing package) •Foamed applications ADK STAB RX-300 series fort rigid PVC injection applications Suitable for Description Dosage •Sewer fittings Ca/Mg/Zn •Pressure fittings Core stabilizers •Outdoor (gutter fittings) Or 2. plus pigments & fillers (*) customized processing packaging = lubricants plus polymer processing aid .5 – 2 PHR •Core stabilizers (ADK STAB RX-200 & RX-300 series •Polymer processing aid. OPE and specific types Suitable for Dosage All PVC rigid formulations including following ingredients 0.5 – 6 PHR •Air coolers One-packs •Other moulded accessories (corestabilizers+customized processing package*) ADK STAB RX-500 series Internal / external lubricants for ADK STAB RX-series Description Lubricants Based on balanced eszter. PE. cable ducts etc Or One-packs 2. edge bands.STABILIZERS AND PLASTICIZER FOR PVC For rigid PVC applications ADK STAB RX-200 series for rigid PVC extrusion applications Suitable for Description Dosage •Window profiles Ca/Mg/Zn •Thin coloured outdoor profiles (rain gutter) Core stabilizers •Inddor or highly filled applications: cladding. liquid / solid phospites Palmarole S. ADK STAB AO-60 hindered phenolic antioxidants ADK STAB PEP-8HT/ 135-A / TPP / HP-10 etc. NOR-HALS and Triazine Other Process & end-use additives •ADK STAB ATC-1 •ADK STAB ATC-7R •ADK STAB NPO-3 E proprietary co-additives Anti-Chalking Effect anti plate out .HX.BO series generic Benzophenone UV absorbers Palmarole LS.PBM etc.ADEKA PALMAROLE ADDITIVES & CO-STABILIZERS FOR PVC Blowing agents for rigid PVC Foamed PVC pipes 3 layers Palmarole EXP 141/95 specially for lead systems micro granules also available for CaZn and Tin stabilizers Foamed rigid PVC sheets and boards Palmarole MB.10 micro granules-endo/exo combination Palmarole BA.01 powder combination of endo/exo Palmarole EXP 141/58 powder combination of endo/exo Co-stabilizers & light stabilizers ADK STAB AO-50. tertiary).BA.BT series generic Benzotriazole UV absorbers ADK STAB LA-series HALS (secondary.SBM. Beta diketone derivates Palmarole LS. Palmarole S. C10 ADK CIZER C-79 E Linear C7-9 ADK CIZER C-79EA Linear C7-9 Wire & Cable. general purpose Others .PLASTICIZERS PRODUCT RANGE Product type Description Application Trimilitates ADK CIZER C-8 (TOTM) C-8 (2-Ethylhexyl) ADK CIZER C-8 L Linear C-8 ADK CIZER C-810 L Linear C8. Automotive Polymeric ADK CIZER PN-series Polyadipates ADK CIZER PX-series Polyadipates ADK CIZER RS-series Polymeric Rubber Experimental PX-943 proprietary Automotive Experimental PX-957 proprietary Automotive ADK CIZER LV-70 proprietary Anti-static ADL CIZER LV-838 proprietary Anti static Film. Mag.(FH) Martin BERMANN Area Sales Manager Austria & Eastern Europe ADEKA PALMAROLE 103.adeka-palmarole.68300 SAINT-LOUIS.com Web: www. rue de Strasbourg FR . France -------------------------------------------------Mobile: ++ 43 664 413 40 72 Home Office Phone: ++43 2252 251 481 Home Office Fax: ++43 2252 251 481 Mail: [email protected]: Ing.com .