Parker Hannifin CorporationSporlan Division 206 Lange Drive Washington, MO 63090 U.S.A. AB-1, AB-5, AB-55 ACTI-BRITE Page 1 of 9 MSDS Revision Date (mm/dd/yyyy): 10/16/2013 MATERIAL SAFETY DATA SHEET SECTION 1 - IDENTIFICATION Product identifier : ACTI-BRITE Product Code(s) : Product Use : Chemical Family : AB-1 (P/N 475096), AB-5 (P/N 475100), AB-55 (P/N 475102) Professional Use Only; Refrigeration coil cleaner. Mixture Supplier’s name and address: Manufacturer’s name and address: Parker Hannifin Corporation - Sporlan Division Refer to Supplier 206 Lange Drive Washington, MO, U.S.A. 63090 Information Telephone # : (636) 239-1111 24 Hr. Emergency Tel # : Chemtrec 1-800-424-9300 (Within Continental U.S.); Chemtrec 703-527-3887 (Outside U.S.). SECTION 2 - HAZARDS IDENTIFICATION Classification : Emergency Overview : WHMIS information: This product is a WHMIS Controlled Product. It meets one or more of the criteria for a controlled product provided in Part IV of the Canadian Controlled Products Regulations (CPR). WHMIS classification: Class D1A (Materials Causing Immediate and Serious Toxic Effects, Very Toxic Material); Class D2A (Materials Causing Other Toxic Effects, Very Toxic Material); Class E (Corrosive Material). OSHA: This material is classified as hazardous under OSHA regulations (29CFR 1910.1200). Hazardous classification: Acute Health Hazard; Chronic Health Hazard . Pink liquid. Pungent odour. DANGER! Corrosive to all tissues. Causes eye, skin and digestive tract burns. Health injuries may be delayed. POISON! Fatal if inhaled. May be fatal if swallowed. Severe respiratory irritant. Prolonged exposure may cause skeletal fluorsis (weakend bone structure). Contact with metals may release small amounts of flammable hydrogen gas. May be corrosive to metals. POTENTIAL HEALTH EFFECTS: Signs and symptoms of short-term (acute) exposure Inhalation : If mists are formed, may cause severe irritation to the nose, throat and respiratory tract. Symptoms may include coughing, choking and wheezing. Extremely high exposures may lead to inflammation of lung tissue (chemical pneumonitis), chemical bronchitis and accumulation of fluid in the lungs (pulmonary edema). Symptoms of pulmonary edema (chest pain, shortness of breath) may be delayed. Absorbed fluoride can cause irregular heartbeat, nausea, dizziness, vomiting and seizures. Could also cause convulsions, coma, respiratory arrest and death. Skin : Causes severe burns, symptoms may be delayed. Direct skin contact may cause corrosive skin burns, deep ulcerations and possibly permanent scarring. May be absorbed and cause symptoms similar to those for inhalation. Eyes : Causes severe burns. Symptoms may include severe pain, blurred vision, redness and corrosive damage. Could cause blindness. A. Never give anything by mouth to an unconscious person. throat and stomach. AB-55 ACTI-BRITE Page 2 of 9 MSDS Revision Date (mm/dd/yyyy): 10/16/2013 Ingestion : May cause severe irritation and corrosive damage in the mouth. Seek immediate medical attention/advice. foams. burns.1200) : Not flammable.00 127087-87-0 3. AB-1.00 .00 . Wash contaminated clothing before re-use.FIRST AID MEASURES Inhalation : Skin contact : Eye contact : Ingestion : Notes For Physician : Immediately remove person to fresh air.00 .00 Phosphoric acid 7664-38-2 1. Cover wound with sterile dressing. Have victim rinse mouth with water.Parker Hannifin Corporation Sporlan Division 206 Lange Drive Washington. Vapours are heavier than air and collect in confined and low-lying areas. Immediately flush eyes thoroughly with running water for at least 20 to 30 minutes. Symptoms may be delayed. Corrosive.COMPOSITION/INFORMATION ON INGREDIENTS CAS # Wt. Do not induce vomiting. AB-5. give oxygen by qualified medical personnel only. Treat symptomatically. Flammability classification (OSHA 29 CFR 1910. give artificial respiration. SECTION 5 . Leather and shoes that have been contaminated with the solution may need to be destroyed. perforations. Special fire-fighting procedures/equipment Suitable extinguishing media : . Section 11. then give one to two glasses of water to drink.30.S. Oxidizing properties : None.7. Protect unharmed eye.00 Ingredients Sulfonic N-95 SECTION 4 .5. Effects of long-term (chronic) exposure : Chronic skin contact with low concentrations may cause dermatitis.% Hydrofluoric acid 7664-39-3 10. Closed containers may rupture if exposed to excess heat or flame due to a build-up of internal pressure. Seek immediate medical attention/advice. tooth erosion could result. Flush affected skin with gently flowing lukewarm water for at least 20 minutes. If breathing is difficult.FIRE FIGHTING MEASURES Fire hazards/conditions of flammability : Not flammable under normal conditions of use. Potential environmental effects SECTION 3 . Seek immediate medical attention/advice. Section 12. Prolonged exposure may cause skeletal fluorsis (weakend bone structure). Symptoms may include abdominal pain. Immediate medical attention is required. Some chemical extinguishing agents may react with this material. Contact with metals may release small amounts of flammable hydrogen gas. : See ECOLOGICAL INFORMATION. Do not rub area of contact. Seek immediate medical attention/advice. Additional health hazards : See TOXICOLOGICAL INFORMATION. Remove contaminated clothing. bleeding and eventually death. Repeated or prolonged exposure may result in kidney effects. In extreme cases. carbon dioxide or dry chemical. vomiting. Explosion data: Sensitivity to mechanical impact / static discharge : Not expected to be sensitive to mechanical impact or static discharge. MO 63090 U. Carcinogenic status : See TOXICOLOGICAL INFORMATION. If breathing has stopped. Use water fog or fine spray. Section 11. Delayed treatment may result in fatality. eyes and clothing. Avoid contact with skin. sand). Remove all sources of ignition. Ensure spilled product does not enter drains. Ensure clean-up is conducted by trained personnel only.Slight 2 .Moderate 3 .Minimal Health: 4 Hazardous combustion products NFPA Rating 1 . No smoking in the area. dike well ahead of the spill to prevent runoff into drains. Individuals involved in the cleanup must wear appropriate personal protective equipment.Parker Hannifin Corporation Sporlan Division 206 Lange Drive Washington.S. well-ventilated area. AB-55 ACTI-BRITE Page 3 of 9 MSDS Revision Date (mm/dd/yyyy): 10/16/2013 : Firefighters should wear proper protective equipment and self-contained breathing apparatus with full face piece operated in positive pressure mode. or confined spaces. Move containers from fire area if safe to do so. Store in corrosion-resistant containers. SECTION 8 .ACCIDENTAL RELEASE MEASURES Personal precautions : Environmental precautions : Spill response/cleanup : Prohibited materials : Restrict access to area until completion of clean-up. Wear suitable protective equipment during handling. Avoid breathing vapour or mist. EXPOSURE CONTROLS AND PERSONAL PROTECTION. Notify the appropriate authorities as required.HANDLING AND STORAGE Safe Handling procedures : Storage requirements : Incompatible materials : Special packaging materials : Use only in well-ventilated areas. Water spray may be useful in cooling equipment exposed to heat and flame. sewers. Ventilate area of release. clear of obstruction and accessible only to trained and authorized personnel. or any natural waterway or drinking supply.EXPOSURE CONTROLS AND PERSONAL PROTECTION None. MO 63090 U. Inspect periodically for damage or leaks. Oxidizing agents. : phosphorus oxides.Serious 4 . When diluting. Store in a cool. . for additional information on acceptable personal protective equipment. AB-5. Keep containers tightly closed when not in use. always add liquid slowly to water and with constant stirring. Alkalies. Corrosive to metals. Wash thoroughly after handling. Store in corrosion-resistant containers. Metals. inert absorbent material (e. Keep away from bases. Stop the spill at source if it is safe to do so. AB-1. dry. US CERCLA Reportable quantity (RQ): See section 15. Hydrogen fluoride. Carbon oxides.A. Do not flush into surface water or sanitary sewer system. Keep away from heat and flame. Metal containers must be lined. Refer to Section 8. Storage area should be clearly identified. During preparation or dilution. Store away from incompatible materials. Contain and absorb spilled liquid with non-combustible. SECTION 7 .Severe Flammability: 0 Instability: 1 Special Hazards: SECTION 6 . formaldehyde : 0 . always add the product to water. None known. sewers. Never add water to the product. Corrosive materials should be stored in a separate safety storage cabinet or room. then place absorbent material into a container for later disposal (see Section 13). immediately notify the national response center in the United States (phone: 1-800-424-8802). metals and other incompatibles. If necessary. Reducing agents. waterways.g. Special spill response procedures : If a spill/release in excess of the EPA reportable quantity is made into the environment. Respiratory protection : Respiratory protection is required if the concentrations exceed the TLV.134) or CSA Z94. AB-1. A self contained breathing apparatus should be used in emergency situations or instances where exposure levels are not known. AB-55 ACTI-BRITE Page 4 of 9 MSDS Revision Date (mm/dd/yyyy): 10/16/2013 Exposure Limits OSHA PEL ACGIH TLV TWA Ingredients STEL PEL STEL Hydrofluoric acid 0. Advice should be sought from respiratory protection specialists. Keep working clothes separately. < 2. Ensure adequate ventilation. : N/Av Specific gravity : 1. Other protective equipment : Wear chemically protective gloves (impervious).A. and gauntlets to prevent prolonged or repeated skin contact. Advice should be sought from glove suppliers. and in accordance with OSHA (29 CFR 1910. NIOSH-approved respirators are recommended. : Avoid breathing vapour or mist. Do not eat. boots.4-02. drink or smoke when using this product. An eyewash station and safety shower should be made available in the immediate working area. especially in confined areas.) : Flame Projection Length : Viscosity : N/Ap N/Ap N/Av : N/Ap Flashback observed : N/Ap . AB-5. Upon completion of work. MO 63090 U. General hygiene considerations SECTION 9 . smoking or use of toilet facilities.0 100°C (212°F) : N/Av Coefficient of water/oil distribution : N/Av Physical state : Odour : pH : Boiling point Melting/Freezing point Vapour pressure (mmHg @ 20° C / 68° F) : N/Av Vapour density (Air = 1) : >1 Volatile organic Compounds (VOC's) : N/Av Flash point : N/Ap Flash point Method : N/Ap Lower flammable limit (% by vol. wash hands before eating. Contaminated work clothing should not be allowed out of the workplace. Respirators should be selected based on the form and concentration of contaminants in air.5 ppm (as F) N/Av 3 ppm (as F) N/Av Phosphoric acid 1 mg/m³ 3 mg/m³ 1 mg/m³ N/Av N/Av N/Av N/Av N/Av Sulfonic N-95 Ventilation and engineering measures : Use general or local exhaust ventilation to maintain air concentrations below recommended exposure limits. Eye / face protection : Chemical splash goggles must be worn when handling this material. Remove soiled clothing and wash it thoroughly before reuse. eyes and clothing.) Odour threshold : Pink liquid. drinking. aprons. A full face shield may also be necessary. Avoid contact with skin.S. Skin protection : Impervious gloves must be worn when using this product.PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Pungent odour.15 Solubility in water : Complete Evaporation rate (n-Butyl acetate = 1) :>1 Volatiles (% by weight) : 0% Auto-ignition temperature : N/Av Upper flammable limit (% by vol.Parker Hannifin Corporation Sporlan Division 206 Lange Drive Washington. SECTION 12 . Hazardous polymerization does not occur. eye and respiratory disorders. SECTION 11 . Phosphoric acid 7664-38-2 75. IARC. OSHA or NTP. See the following tables for individual ingredient ecotoxicity data.1 mg/L (Japanese ricefish) N/Av None. refer to hazardous combustion products in Section 5. Routes of exposure : Inhalation: YES : See below for individual ingredient acute toxicity data. AB-1. dermal) (Oral. May be corrosive to metals. . Contact with metals may release small amounts of flammable hydrogen gas. MO 63090 U. rat (Rabbit. Sulfonic N-95 127087-87-0 YES N/Av N/Av None. Materials To Avoid And Incompatibility : Incompatible materials (see Section 7). The product should not be allowed to enter drains or water courses. Epidemiology : Not available. Avoid heat and open flame.5 mg/L (Rainbow trout) N/Av None. Not expected to have other reproductive effects. skin.TOXICOLOGICAL INFORMATION Target organs : Eyes. Corrosive other important hazards : None known.Parker Hannifin Corporation Sporlan Division 206 Lange Drive Washington. respiratory system and digestive system. Not expected to be a teratogen. AB-5.A. Hazardous decomposition products : None known. N/Av Conditions aggravated by overexposure : Pre-existing skin. Ecotoxicity data: Toxicity to Fish Ingredients CAS No LC50 / 96h NOEC / 21 day M Factor Hydrofluoric acid 7664-39-3 107. Not expected to be mutagenic in humans. Not available. AB-55 ACTI-BRITE Page 5 of 9 MSDS Revision Date (mm/dd/yyyy): 10/16/2013 Absolute pressure of container : N/Ap SECTION 10: STABILITY AND REACTIVITIY Stability and reactivity : Hazardous polymerization : Conditions to avoid : Stable under the recommended storage and handling conditions prescribed. Toxicological data Skin Absorption: YES Skin & Eyes: LC50(4hr) Ingredients YES Ingestion: LD50 inh.ECOLOGICAL INFORMATION Ecotoxicity : No data is available on the product itself. Kidneys. Sensitization to material : Synergistic materials : Irritancy : Not expected to be a skin or respiratory sensitizer.S. rat) Hydrofluoric acid 655 ppm N/Av N/Av Phosphoric acid N/Av > 1260 mg/kg (85%) Sulfonic N-95 N/Av 4400 mg/kg (75%) 3500 mg/kg (85%) N/Av Carcinogenic status : Reproductive effects : Teratogenicity : Mutagenicity : No components are listed as carcinogens by ACGIH. Avoid contact with incompatible materials. or be deposited where it can affect ground or surface waters. acidic. acidic. No data is available on the product itself. (Hydrofluoric acid.s. as supplied. (Hydrofluoric acid.o. Additional information ICAO/IATA UN3264 Corrosive liquid. Persistence : Bioaccumulation potential : No data is available on the product itself. Phosphoric acid) 8 II 8 II This material may be shipped as a limited quantity according to 49CFR section 173. Dispose in accordance with all applicable federal.17 for Limited Quantity Exemption information. the Limited Quantity Exemption may apply for containers which hold specific quantities of the product. N/Av None. If this product. Title 40 CFR 261. (Hydrofluoric acid. state. 49CFR/DOT UN3264 Additional 49CFR/DOT Corrosive liquid.Parker Hannifin Corporation Sporlan Division 206 Lange Drive Washington.DISPOSAL CONSIDERATIONS Handling for Disposal : Methods of Disposal : RCRA : See Section 7 (Handling and Storage) for further details. n. if shipping under this exemption. Empty containers retain residue (liquid and/or vapour) and can be dangerous. SECTION 13 .A. inorganic. becomes a waste in the United States.154. Phosphoric acid 7664-38-2 376 mg/L (Daphnia magna) N/Av None. Toxicity to Algae CAS No EC50 / 96h or 72h NOEC / 96h or 72h M Factor Hydrofluoric acid 7664-39-3 N/Av N/Av None. Other Adverse Environmental effects : No data is available on the product itself. SECTION 14: TRANPORT INFORMATION Regulatory Information TDG TDG UN Number UN3264 Shipping Name CORROSIVE LIQUID. MO 63090 U. Phosphoric acid) Class Packing Group 8 II information Within Canada. N. n. N/Av 127087-87-0 Sulfonic N-95 Mobility : No data is available on the product itself. inorganic. 127087-87-0 Sulfonic N-95 Ingredients N/Av N/Av None.s. Under the TDGR.O. INORGANIC. Phosphoric acid) Label . AB-55 ACTI-BRITE Page 6 of 9 MSDS Revision Date (mm/dd/yyyy): 10/16/2013 Ingredients Toxicity to Daphnia CAS No EC50 / 48h NOEC / 21 day M Factor Hydrofluoric acid 7664-39-3 270 mg/L (Water flea) N/Av None. Phosphoric acid 7664-38-2 32 mg/L/72hr (Green algae) N/Av None. provincial and local regulations. AB-5.S. AB-1.o. it may meet the criteria of a hazardous waste as defined under RCRA.S. ACIDIC. refer to section 1. It is the responsibility of the waste generator to determine the proper waste identification and disposal method. AB-55 ACTI-BRITE Page 7 of 9 MSDS Revision Date (mm/dd/yyyy): 10/16/2013 ICAO/IATA Additional Refer to the appropriate Packing Instruction. AB-1.302): SARA TITLE III: Sec. Federal chemical lists: Ingredients CAS # CERCLA TSCA Inventory Reportable Quantity(RQ) (40 CFR 117. 313. US State Right to Know Laws: The following chemicals are specifically listed by individual States: California Proposition 65 Ingredients State "Right to Know" Lists CAS # Listed Type of Toxicity CA MA MN NJ PA RI Hydrofluoric acid 7664-39-3 No N/Ap Yes Yes Yes Yes Yes Yes Phosphoric acid 7664-38-2 No N/Ap Yes Yes Yes Yes Yes Yes 127087-87-0 No N/Ap No No No No No No Sulfonic N-95 Canadian Information: Canadian Environmental Protection Act (CEPA) information: All ingredients listed appear on the Domestic Substances List (DSL).000 pounds for all other hazardous chemicals. the EPA has established threshold quantities for the reporting of hazardous chemicals.A. Under SARA Sections 311 and 312. 40 CFR 370 Hazard Classes: Immediate (Acute) health hazard. MSDS Requirements. whichever is lower. HSR001571 (dilution) 127087-87-0 N/Av Present Present Ingredients Sulfonic N-95 Present . 40 CFR 372. International Information: Components listed below are present on the following International Inventory list: CAS # European EINECs Australia AICS Philippines PICCS Japan ENCS Korea KECI/KECL China IECSC NewZealand IOC Hydrofluoric acid 7664-39-3 231-634-8 Present Present (1)-306 KE-20198 Present HSR001537. HSR001568. 40 CFR 355: SARA TITLE III: Sec. information SECTION 15 . Refer to the Manufacturer for shipping information.REGULATORY INFORMATION US Federal Information: Components listed below are present on the following U. prior to shipping this material. for extremely hazardous substances and 10. HSR001589 (dilution) Phosphoric acid 7664-38-2 231-633-2 Present Present (1)-422 KE-27427 Present (22317) HSR001545.4 kg 100 lb TPQ Yes 1% Phosphoric acid 7664-38-2 Yes 5000 lb / 2270 kg None. 311 and 312. HSR001569. AB-5. Extremely Hazardous Substance. This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. No N/Ap 127087-87-0 Yes N/Ap N/Av No NS Sulfonic N-95 SARA TITLE III: Sec.S.S. Specific Toxic Chemical de minimus Concentration Toxic Chemical Hydrofluoric acid 7664-39-3 Yes 100 lb/ 45. 302. Chronic Health Hazard. The current thresholds are 500 pounds for the threshold planning quantity (TPQ). HSR001570.Parker Hannifin Corporation Sporlan Division 206 Lange Drive Washington. MO 63090 U. Minimal 1 . Threshold Limit Values and Biological Exposure Indices for 2013 2. MO 63090 USA (636) 239-1111 Direct all enquiries to: Parker Hannifin Corp.Sporlan Division. 5. and Liability Act of 1980 CFR: Code of Federal Regulations CSA: Canadian Standards Association DOT: Department of Transportation EPA: Environmental Protection Agency HMIS: Hazardous Materials Identification System HSDB: Hazardous Substances Data Bank IARC: International Agency for Research on Cancer Inh: Inhalation MA: Massachusetts MN: Minnesota MSHA: Mine Safety and Health Administration N/Ap: Not Applicable N/Av: Not Available NFPA: National Fire Protection Association NIOSH: National Institute of Occupational Safety and Health NJ: New Jersey NTP: National Toxicology Program OSHA: Occupational Safety and Health Administration PA: Pennsylvania PEL: Permissible exposure limit RCRA: Resource Conservation and Recovery Act RI: Rhode Island RTECS: Registry of Toxic Effects of Chemical Substances SARA: Superfund Amendments and Reauthorization Act STEL: Short Term Exposure Limit TDG: Canadian Transportation of Dangerous Goods Act & Regulations TLV: Threshold Limit Values TWA: Time Weighted Average WHMIS: Workplace Hazardous Materials Identification System 1. (2013) 4.27 September 2013 * Prepared for: Parker Hannifin Corporation . AB-5. AB-55 ACTI-BRITE Page 8 of 9 MSDS Revision Date (mm/dd/yyyy): 10/16/2013 SECTION 16 . AB-1. Compensation. searched 2013 3. California Proposition 65 List . ACGIH. US EPA Title III List of Lists .S. 0 . . International Agency for Research on Cancer Monographs.Moderate 0 3 . MO 63090 U. HSDB and RTECs). Material Safety Data Sheet from manufacturer.A.Parker Hannifin Corporation Sporlan Division 206 Lange Drive Washington.Severe 1 .October 2012 6.Serious Reactivity: 4 . Canadian Centre for Occupational Health and Safety.Sporlan Division 206 Lange Drive Washington.Chronic hazard Health: *4 Legend : References : ACGIH: American Conference of Governmental Industrial Hygienists CA: California CAS: Chemical Abstract Services CERCLA: Comprehensive Environmental Response. CCInfoWeb databases (Chempendium.Slight Flammability: 2 .OTHER INFORMATION HMIS Rating : . : 3 Revision Information : (M)SDS sections updated: 3.S.A. http://www. MO 63090 U. AB-5.thecompliancecenter. ICC The Compliance Center Inc and Parker Hannifin Corp expressly disclaim all expressed or implied warranties and assume no responsibilities for the accuracy or completeness of the data contained herein. AB-1. and Parker Hannifin Corp. Preparation Date (mm/dd/yyyy) : 08/27/2010 MSDS Revision Date (mm/dd/yyyy) : 10/16/2013 Revision No. The data in this MSDS does not apply to use with any other product or in any other process.Parker Hannifin Corporation Sporlan Division 206 Lange Drive Washington.com DISCLAIMER OF LIABILITY This Material Safety Data Sheet was prepared by ICC The Compliance Center Inc. using information provided by / obtained from Parker Hannifin Corp and CCOHS’ Web Information Service. or altered in any way without the expressed knowledge and permission of ICC The Compliance Center Inc. This Material Safety Data Sheet may not be changed. AB-55 ACTI-BRITE Page 9 of 9 MSDS Revision Date (mm/dd/yyyy): 10/16/2013 Prepared by: ICC The Compliance Center Inc. COMPOSITION/INFORMATION ON INGREDIENTS END OF DOCUMENT . The information in the Material Safety Data Sheet is offered for your consideration and guidance when exposed to this product.