UNIVERSITY OF DELHI_______ SCHEME OF EXAMINATION AND COURSES OF READING FOR B.Sc. INDUSTRIAL CHEMISTRY Syllabus applicable for the students seeking admission to the B.Sc. Industrial Chemistry Course in the academic year 2011-12 and onwards Page 1 of 80 B.Sc. Industrial Chemistry The course on B.Sc. Industrial Chemistry was introduced in the University of Delhi in 1984 and since then this course has undergone many changes and has become more comprehensive and relevant. The importance of industrial chemistry hardly needs any emphasis. It basically deals with the development, optimisation and monitoring of various chemical processes used in industry for transforming raw materials etc., into useful commercial products for society. Industrial chemistry as an applied science plays a vital role in diverse areas that influence human society. The course in the present form focuses on industrial processes used in the production of major bulk chemicals and their secondary commercial products (dyes, pesticides, drugs, polymers etc.) besides covering the traditional areas of chemistry. In this three year course spread over six semesters, there are 12 papers of chemistry including 6 papers of industrial chemistry; 3 papers each of mathematics and physics and one paper each of intellectual property rights, biochemistry and environmental chemistry, technical writing and communication in English, computational skills. In the last two semesters of this course, there is a provision for two elective papers out of four papers, namely, green chemistry, polymer science, biotechnology, forensic science. It is hoped that the students will find this course very interesting as it will equip them for job opportunities in industries in both private and public sectors such as manufacturing and processing industries, industries related to petroleum, chemical, ceramic, polymer, food, electronics, the environmental, mining, pharmaceuticals and health-related industries, agriculture industries, government agencies, including forensic science and patents, defence, education and research, and areas related to biotechnology. The degree also allows them to pursue postgraduate studies in chemistry and related areas. Page 2 of 80 Course Structure All theory papers will have 5 periods per week, including 1 period for assignments, discussion, presentations, etc. There shall be 6 practical classes per week for Chemistry and Industrial Chemistry. In addition, there shall be one qualifying paper in self-learning mode called Environmental Studies. Each Theory Paper shall be of 100 marks and Practical Paper shall be of 50 marks. Total Number of Papers : 24 Year I Semester-1 Paper 1 Paper 2 Paper 3 Paper 4 Paper No. CHPT-101 PHPT-101 ICPT-101 ENAT-101/ CSAT-101 Paper Name Chemistry-I * Physics-1: Mechanics * Industrial Chemistry-I * Technical writing and Communication in English / Computational skills* Duration (Hrs.) 3 3 3 3 Maximum Marks 100 100 100 100 * With Practicals Page 3 of 80 Semester-2 Paper 5 Paper 6 Paper 7 Paper 8 Paper No. CHPT-202 MAPT-101 ICPT-202 ENAT-101/ CSAT-101 Paper Name Chemistry-II* Calculus and Matrices Industrial Chemistry-II* Technical writing and Communication in English / Computational skills* Duration (Hrs.) 3 3 3 3 Maximum Marks 100 100 100 100 * With Practicals Year II Semester-3 Paper 9 Paper 10 Paper 11 Paper 12 Paper No. CHPT-303 MAPT-303 ICPT-303 Paper-602 (of B.Sc (H) Chemistry) Paper Name Chemistry-III* Algebra Industrial Chemistry-III* Biochemistry and Environmental Chemistry* Duration Maximum (Hrs.) Marks 3 100 3 100 3 3 100 100 * With Practicals Semester-4 Paper 13 Paper 14 Paper 15 Paper 16 * With Practicals Paper No. CHPT 404 PHPT-303 ICPT-404 EL310 (vi) Paper Name Chemistry-IV* Physics-II : Wave and Optics* Industrial Chemistry-IV* Intellectual Property Rights Duration Maximum (Hrs.) Marks 3 100 3 3 3 100 100 100 Page 4 of 80 Year III Semester-5 Paper 17 Paper 18 Paper 19 Paper No.) 3 3 3 Maximum Marks 100 100 100 Paper 24 Elective-2: Any one out of (i) Green Chemistry EL 310 (i) or (ii) Polymer Science EL 310 (ii) or (iii) Biotechnology EL 310 (iii) or (iv) Forensic Science EL 310 (iv) which has been not opted in Semester 5 3 100 * With Practicals Page 5 of 80 . CHPT 606 MAPT 404 ICPT-606 Paper Name Chemistry-VI* Differential Equations Industrial Chemistry-VI* Duration (Hrs. Magnetism and Electromagnetic Theory* Industrial Chemistry-V* Elective-I: Any one out of (i) Green Chemistry (ii) Polymer Science (iii) Biotechnology (iv) Forensic Science Duration (Hrs. CHPT 505 PHPT-404 ICPT-505 EL 310 (i) or EL 310 (ii) or EL 310 (iii) or EL 310 (iv) Paper Name Chemistry-V* Physics-III :Electricity.) 3 3 3 Maximum Marks 100 100 100 Paper 20 3 100 * With Practicals Semester-6 Paper 21 Paper 22 Paper 23 Paper No. SEMESTER I Page 6 of 80 . Anomalous electronic configurations. Radial and angular parts of the hydogenic wavefunctions (atomic orbitals) and their variations for 1s. ionic character in covalent compounds.f). polarizing power and polarizability. BONDING. dipole moment and percentage ionic character. Discovery of spin.PAPER-1 CHPT-101: CHEMISTRY-1 (ATOMIC STRUCTURE. Schrodinger equation for hydrogen atom in Cartesian coordinates (x.y. Page 7 of 80 . Born-Haber cycle and its applications. GENERAL ORGANIC CHEMISTRY & ALIPHATIC HYDROCARBONS) Section A: Inorganic Chemistry-1 (30 Periods) Unit 1 Atomic Structure: Recapitulation of: Bohr s theory and its limitations. spin quantum number (s) and magnetic spin quantum number (ms).q.z). Need of polar coordinates. Significance of Y and Y2. Stability of half-filled and completely filled orbitals. dual behaviour of matter and radiation. 3s. de-Broglie s relation. Relative energies of atomic orbitals. Fajan s rules. 2s. Unit 2 Chemical Bonding and Molecular Structure Ionic Bonding :General characteristics of ionic bonding. 3p and 3d orbitals (Only graphical representation).z) into polar coordinates (r. Statement of Born-Lande equation for calculation of lattice energy. p and d atomic orbitals. lattice energy and solvation energy and their importance in the context of stability and solubility of ionic compounds. bond moment. Radial distribution functions and the concept of the most probable distances with special reference to 1s and 2s atomic orbitals. Shapes of s. Radial and angular nodes and their significance.y. nodal planes. 2p. Need of a new approach to Atomic structure. Heisenberg Uncertainty principle. Significance of quantum numbers. What is Quantum mechanics? Time independent Schrodinger equation (H Y = EY) and meaning of various terms in it. Energy considerations in ionic bonding. concept of exchange energy. transformation of Cartesian coordinates (x. Rules for filling electrons in various orbitals. orbital angular momentum and quantum numbers mr and ms. Electronic configurations of the atoms. bonding and antibonding MOs and their characteristics for s-s. Newman. Sawhorse and Fischer representations. square planar. butane and cyclohexane. MO Approach : Rules for the LCAO method. Concept of chirality (upto two carbon atoms). NO and NO+. Electronic Displacements: Inductive Effect. Kolbe s synthesis. D and L. Interconversion of Wedge Formula. Reactions: Free radical Substitution: Halogenation. Carbanions and free radicals. nonbonding combination of orbitals. Wurtz reaction.r. Unit 4 Stereochemistry Conformations w. Preparation: Catalytic hydrogenation. s-p and p-p combination of atomic orbitals.Covalent bonding: VB Approach :Shapes of some inorganic molecules and ions on the basis of VSEPR and hybridization with suitable examples of linear. Reactive Intermediates: Carbocations. Strength of organic acids and bases: Comparative study with emphasis on factors affecting pK values.trans nomenclature. Section B: Organic Chemistry-1 (30 Periods) Unit 3 Fundamentals of Organic Chemistry Physical Effects. Alkenes: (Upto 5 Carbons) Preparation: Elimination reactions: Dehydration of alkenes and dehydrohalogenation of alkyl halides (Saytzeff s rule). Aromaticity: Benzenoids and Huckel s rule. Cleavage of Bonds: Homolysis and Heterolysis.t. trigonal bipyramidal and octahedral arrangements. Unit 5 Aliphatic Hydrocarbons Functional group approach for the following reactions (preparations & reactions) to be studied in context to their structure. Alkanes:(Upto 5 Carbons). ethane. cis alkenes Page 8 of 80 . Comparison of VB and MO approaches. Electromeric Effect. from Grignard reagent. MO treatment of homonuclear diatomic molecules of 1st and 2nd periods (including idea of s-p mixing) and heteronuclear diatomic molecules such as CO. Structure. shape and reactivity of organic molecules: Nucleophiles and electrophiles. tetrahedral. Diastereomerism and Meso compounds) . cis . trigonal planar. Enantiomerism. Threo and erythro. Concept of resonance and resonating structures in various inorganic and organic compounds. Resonance and Hyperconjugation. CIP Rules: R/ S (for upto 2 chiral carbon atoms) and E / Z Nomenclature (for upto two C=C systems). Configuration: Geometrical and Optical isomerism. 4. James E. Huheey. Reactions: cis-addition (alk. L. J. oxymecuration-demercuration. T. A. F. S. Ellen Keiter and Richard Keiter: Inorganic Chemistry: Principles of Structure and Reactivity. 3. Orient Longman. Ozonolysis. Saunders. Vogel. addition of bromine and alkaline KMnO4. 10.I. L. T. Textbook of Practical Organic Chemistry. B. 12. 5th edition. S. Eliel: Stereochemistry of Carbon Compounds. Bahl: Advanced Organic Chemistry. S. E. John Wiley. L. 6. Peter Sykes: A Guide Book to Mechanism in Organic Chemistry. Hydroboration-oxidation. 6th Edition. 1960. Hydration. Graham Solomon: Organic Chemistry. Morrison & R. G. Mann. 9. Orient Longman.I. I. KMnO4.(Partial catalytic hydrogenation) and trans alkenes (Birch reduction). D. 13. S. McDaniel and Alexader: Concepts and Models in Inorganic Chemistry. Douglas.I. 2. Wilkinson: Basic Inorganic Chemistry. Prentice Hall. 14. C. 7. Vogel . A. Chand 11. John Wiley and Sons. A. John Wiley. Page 9 of 80 . W. A. Tata McGraw Hill. Arun Bahl and B. SUGGESTED READINGS 1. I & II). Cotton & G. E. Alkynes: (Upto 5 Carbons) Preparation: Acetylene from CaC2 and conversion into higher alkynes. by dehalogenation of tetra halides and dehydrohalogenation of vicinal-dihalides. 8. Reactions: formation of metal acetylides. N. Practical Organic Chemistry. E L. 5. KMnO4) and trans-addition (bromine). 7th Edition. Prentice Hall. Finar: Organic Chemistry (Vol. R. ozonolysis and oxidation with hot alk. & B. Prentice Hall. Vogel. Addition of HX (Markownikoff s and anti-Markownikoff s addition). F. B. Boyd: Organic Chemistry. Lee: A new Concise Inorganic Chemistry. Vogel s Qualitative Inorganic Analysis. Vogel s Quantitative Chemical Analysis. Pearson Publication. Prentice Hall. Estimation of Cu (II) ions iodometrically using Na2S2O3. Estimation of sodium carbonate and sodium hydrogen carbonate present in a mixture. Section B: Organic Chemistry 1. S. 3. Estimation of water of crystallization in Mohr s salt by titrating with KMnO4. 2. Cl.Volumetric Analysis 1. I) in organic compounds (containing upto two extra elements) 2. aspartic acid.CHPP-101: PRACTICAL CHEMISTRY Section A: Inorganic Chemistry . Detection of extra elements (N. Page 10 of 80 . tyrosine or any other amino acid) by paper chromatography (b) Identify and separate the sugars present in the given mixture by paper chromatography. 4. glutamic acid. Estimation of oxalic acid by titrating it with KMnO4. Separation of mixtures by Chromatography: Measure the Rf value in each case (combination of two compounds to be given) (a) Identify and separate the components of a given mixture of 2 amino acids (glycine. 5. Br. Estimation of Fe (II) ions by titrating it with K2Cr2O7 using internal indicator. PAPER-2 PHPT 101: PHYSICS-1: MECHANICS Vector calculus (Total Number of Lectures=15) Differentiation of a vector with respect to a scalar. Conservation of momentum. Tata McGraw-Hill. Impulse. Moment of inertia and its calculation for rectangular. Equivalence of mass and energy. Kinetic energy of rotation. Variation of mass with velocity. Angular momentum of a particle and system of particles. Seymour Lipschutz. Linear Momentum. Motion of a particle in a central force field. Elasticity: Hook s Law. Postulates of Special theory of Relativity. Rotation about a fixed axis. Galilean invariance. Kepler s Laws (Only Statement). spherical and cylindrical bodies.By Murray Spiegel. Conservation of angular momentum. Centre of mass. Potential energy. Special Theory of Relativity (Total number of lectures=15) Constancy of speed of light. Curl and Laplacian operations and their meanings. . (2009). Idea of line surface and volume integrals gauss divergence theorem. Theorem of Addition of relativistic velocities. Stokes theorem and Greens s theorem in Plane. Strain. Michelson. Elastic Constants.Morley Experiment. Stress. 2nd Edn. Page 11 of 80 . SUGGESTED READINGS: 1. divergence. Mechanics (Total Number of lectures =30) Dynamics of a system of particles. Red shift. Gradient. conservative and non-conservative forces. Torque. Work Energy theorem. Newton s laws. Schaum s Outline of Vector Analysis. Length contraction and Time Dilation. Doppler effect. Lorentz transformations. Twisting torque on a wire. Tata McGraw-Hill2007). Mathur. 4. Q factor of a mechanical oscillator.. Determination of moment of inertia of a Fly wheel. Malvin Ruderman. 5. Determination of the acceleration due to gravity using bar pendulum. Walter Knight. Single slit diffraction using laser.2. 7. Serway. Determination of frequency of an electrically maintained tuning fork by Melde s experiment. David Halliday and Kenneth S. Carl Helmholz and Burton Moyer. 11. Determination of acceleration due to gravity using Kater s Pendulum. 10. 9. Karane. Chand & Company Ltd. 3. Verification of Malus Law.S. Mechanics Berkeley physics course: By Charles Kittel. Vol. 12. 8. Mechanics by D. 2. 2000). To Study the motion of a spring and calculate (s) spring constant and (b) the value of g. (John Wiley and Sons. Physics for Scientists and Engineers By Raymond A. Determination of the coefficient of Viscosity of water by capillary flow method ( Poiseuille s method) 6. 3. John W. Study of the condition of resonance for a series LCR circuit and determine its resonance frequency and Quality factor. Physics. 5th Edition -1992). Each college should set up ALL EXPERIMENTS. To determine the modulus of rigidity of a wire by Maxwell s needle. 5. 2. Jewett. Page 12 of 80 . Practical Exercises: 1. PHPP-101: PRACTICAL PHYSICS Note 1. 1 and Vol. (S. Jewett. 11 by Robert Resnick. 4. Jr. To determine the elastic constants of a wire by Searle s method. (Brooks/Cole-2009). John W. Each student is required to perform at least 6 practicals in each semester. References: 1. Advanced Level Practical Physics: Nelson and Ogborn: English Language Book Society. 3. London. Indu Prakash. Vol 1 and 2. Advanced Practical Physics: Worsnop and Flint. Practical Physics. Page 13 of 80 . 2. Methuen & Co. Methods of estimation of CO. pollution by SO2. Chemical Technology Basic principles of distillation. caustic soda. secondary and tertiary treatment). chrome alum. solid-liquid leaching and liquidliquid extraction. argon. uses. An introduction into the scope of different types of equipment needed in chemical technology. ion exchange). carbon monoxide. distillation columns. sulphuric acid. nitric acid. Green House effect and Global warming. chlorine. Control of particulates. dairy. Effluent treatment plants (primary.PAPER-3 ICPT-101: INDUSTRIAL CHEMISTRY-1: INDUSTRIAL CHEMICALS AND ENVIRONMENT I. separation by absorption and adsorption. helium. common salt. potassium dichromate and potassium permanganate. petroleum and petrochemicals. NOx. Industrial Gases and Inorganic Chemicals (a) Industrial Gases: Large scale production. borax. industrial water and domestic water. chlorofluorocarbons and Halogens. extruders. Industrial waste management. hydrogen. CO. Introduction to clean technology. textile. 2. Scaling up operations in chemical industry. including reactors. Page 14 of 80 . incineration of waste. nitrogen. 3. solvent extraction. potash alum. sodium thiosulphate. H2S and other foul smelling gases. sulphur dioxide and phosgene. Water quality parameters for waste water. fertilizer. (b) Inorganic Chemicals: Manufacture. (b) Water pollution and Water Quality Standards: Pollutants and their sources. Ozone depletion by oxides of nitrogen. fluorine. etc. agro. analysis and hazards in handling the following chemicals: hydrochloric acid. emulgators. hydrogen peroxide. electro dialysis. Environment (a) Air Pollution: Pollutants and their sources. application. neon. pumps. Industrial effluent from the following industries and their treatment: electroplating. SOx and control procedures. CO2. removal of sulphur from coal. Water treatment and purification (reverse osmosis. tannery. mills. NOx. acetylene. storage and hazards in handling of the following gases: oxygen. Sludge disposal. bleaching powder. III Industrial Metallurgy Preparation of metals (ferrous and nonferrous) and ultra pure metals for semiconductor technology. (AgNO3 and potassium chromate) 6. New Delhi. Determination of dissolved oxygen in water. J. M. R. 7. Rousseau: Elementary Principles of Chemical Processes. S. De. 3. Estimation of SPM in air samples. Estimation of total alkalinity of water samples (CO3. Dara: A Textbook of Engineering Chemistry. A. 6. 10. R. A. Determination of Chemical Oxygen Demand (COD) 3. Wiley Publishers. S. Study of some of the common bio-indicators of pollution. Measurement of dissolved CO2. 5. 2. K. Suggested Readings 1. 9. New Delhi. Determination of Biological Oxygen Demand (BOD) 4. New Delhi. 8. New Delhi. Kent: Riegel s Handbook of Industrial Chemistry. 5.W.ICPP-101: PRACTICAL INDUSTRIAL CHEMISTRY 1. Khopkar. Vol-I.M. Percentage of available chlorine in bleaching powder. Environmental Pollution Analysis: Wiley Eastern Ltd. Stocchi: Industrial Chemistry. 2. New Delhi. Ltd. Preparation of borax/ boric acid. sulphate and salinity of water samples by simple titration method. Measurement of chloride. S. CBS Publishers. Felder. Ellis Horwood Ltd. E. Environmental Chemistry: New Age International Pvt. Page 15 of 80 . S. Chand & Company Ltd. UK. 4. HCO3) using double titration method. 3. Svartik: A comprehensive grammar of the English language. notices. Riordan. introductory. transitional and concluding paragraphs. SUGGESTED READINGS 1. Scot Ober. G. Unit 3 Technical Writing: Scientific and technical subjects. Unit 2 Writing Skills. Page 16 of 80 . L. A course in written English. minutes. Additional Reference Books 5. Leech and J. Hamp-Lyons and B. Panley: Technical Report Writing Today Biztaantra. Heasely: Study Writing. Pauley. 8th Edition (2004). Cambridge Univ. Prentice Hall Reagents. formal and informal writings. common errors to be avoided. 5th Edition (2004). Biztantra. manuals. For academic and professional purposes. coherence and cohesion. expository and argumentative writing. descriptive. Riordan & Steven A. distinct features of speech. Frank. 4. Biztantra: Technical Report Writing Today. Writing as thinking: A guided process approach. Steven E.101: TECHNICAL WRITING AND COMMUNICATION IN ENGLSH Unit 1 Communication: Language and communication. thesis statement. Daniel G. Contemporary Business Communication. Selection of topic. Daniel G. Englewood Cliffs. Press. Greenbaum. developing the thesis. linguistic unity. developmental. formal writings/reports. 2. Longman. 6. narrative.PAPER-4 ENPT. letters. memorandum. S. R. M. agenda. differences between speech and writing. handbooks. London. distinct features of writing. Quirk. developing macros in spreadsheet General Awareness (4 Periods) IT Act. Elements. CPU. Fourth Edition. registers. Note: Use of Open Office/Star Offices recommended. Applications Problem Solving (10 Periods) Notion of algorithms.PAPER-4 CSPT-101 . Reservations.openffice.COMPUTATIONAL SKILLS Computer Fundamentals (12 Periods) Introduction to Computers: Characteristics of Computers. Forthcoming title in PearsonEducation. Fundamentals of Computers. Fundamentals of Computers. router. Types and generations of Computers Basic Computer Organization . Addition and subtraction of binary numbers. Reference manual for Open Office available at: http://www. ALU. ASCII. I/O devices User Interface with the Operating System. Banking? SUGGESTED READINGS : [1] V. switch. Unicode. stepwise methodology of developing an algorithm. 2's Complement. as they are freely downloadable. [2] Anita Goel. BCD. server-client architecture Multimedia (4 Periods) Introduction. Uses of computers.)? I-Tax. System Tools Data Representation (8 Periods) Binary representation of integers and real numbers. PHI. Rajaraman. Characteristics. 1's Complement. memory hierarchy. System Security (virus/firewall etc.Units of a computer. Networks terminology (4 Periods) Types of networks.org Page 17 of 80 . PRACTICAL COMPUTATIONAL SKILLS 1. Networking Configuration. creating charts. 4. basic functions and formulas. entering and formatting information. Working with worksheets. Control Panel. Presentation Software. Familiarizing with the Operating System.CSPP-101. Document Preparation. 3. Firewall setting. Defined projects will be done by the students and evaluated by the instructor. tables and graphs. Spreadsheet Handling. 2. 5. Creating a spreadsheet. Page 18 of 80 . SEMESTER II Page 19 of 80 . Chemical Equilibrium Free energy change in a chemical reaction.PAPER-5 CHPT-202: CHEMISTRY-2 (THERMODYNAMICS. Statement of Third Law of thermodynamics and calculation of absolute entropies of substances. Calculation of bond energy. Maxwell s relations. Gibbs Helmholtz equation. state variables. Calculation of work (w). various types of systems and processes. thermodynamic properties. integral and differential enthalpies of solution and dilution. q. U and H for processes involving changes in physical states. calculations of entropy change and free energy change for reversible and irreversible processes under isothermal and adiabatic conditions. Important principles and definitions of thermochemistry. bond dissociation energy and resonance energy from thermochemical data. changes in internal energy ( U) and enthalpy ( H) for expansion or compression of ideal gases under isothermal and adiabatic conditions for both reversible and irreversible processes. Various statements of Second Law of thermodynamics. concept of heat and work. Criteria of spontaneity. Le Chatelier s principle. heat (q). Thermodynamic derivation of the law of chemical equilibrium. Concept of standard state and standard enthalpies of formations. EQUILIBRIA & FUNCTIONAL GROUP ORGANIC CHEMISTRY-1) Section A: Physical Chemistry-1 (30 Lectures) Unit 1 Chemical Thermodynamics What is thermodynamics? State of a system. concept of entropy. First Law of thermodynamics. thermodynamic equilibrium. Unit 2. Relationships between Kp. Variation of enthalpy of a reaction with temperature Kirchhoff s equation. Gibbs free energy and Helmholtz energy. Page 20 of 80 . Calculation of w. intensive and extensive variables. Kc and Kx for reactions involving ideal gases. Distinction between G and Go. moderate and weak electrolytes. Unit 5. nitrite & nitro formation. common ion effect. Aromatic hydrocarbons Preparation (Case benzene): from phenol. degree of ionization. Aryl Halides Preparation: (Chloro. halogenation and sulphonation. Ionization of weak acids and bases. HNO3). Alcohols. vinyl and aryl halides. Buffer solutions. by decarboxylation. Reactions: With sodium. Reactivity and Relative strength of C-Halogen bond in alkyl. carboxylic acid and esters. factors affecting degree of ionization. ketones. acidic dichromate. Reactions : (Case benzene) : Electrophilic substitution: nitration. degree of hydrolysis and pH for different salts. Alkyl and Aryl Halides Alkyl Halides (Upto 5 Carbons) Types of Nucleophilic Substitution (SN1. Benzyne Mechanism: KNH2/NH3 (or NaNH2/NH3). Oppeneauer oxidation Diols: (Upto 6 Carbons) oxidation of diols. Side chain oxidation of alkyl benzenes (upto 4 carbons on benzene). pH scale. allyl. SN2 and SNi) reactions. Sandmeyer & Gattermann reactions. conc. HX (Lucas test). alk. Ester hydrolysis. Solubility and solubility product of sparingly soluble salts applications of solubility product principle. Williamson s ether synthesis: Elimination vs substitution. Unit 4. oxidation (with PCC. esterification. 2 and 3 alcohols: using Grignard reagent. Page 21 of 80 . Salt hydrolysis-calculation of hydrolysis constant. benzyl. Reduction of aldehydes. from acetylene. Phenols and Ethers (Upto 5 Carbons) Alcohols: Preparation: Preparation of 1 . Reactions (Chlorobenzene): Aromatic nucleophilic substitution (replacement by OH group) and effect of nitro substituent. Friedel-Craft s reaction (alkylation and acylation) (upto 4 carbons on benzene). from benzene sulphonic acid. KMnO4. ionization constant and ionic product of water. Unit 6. Section B: Organic Chemistry-2 (30 Lectures) Functional group approach for the following reactions (preparations & reactions) to be studied in context to their structure.Unit 3. Preparation: from alkenes and alcohols. bromo and iodo-benzene case): from phenol. Pinacol-Pinacolone rearrangement. Reactions: hydrolysis. Ionic Equilibria Strong. nitrile & iso-nitrile formation. S. Page 22 of 80 . 10. Practical Organic Chemistry. J. 5. Kotz. 3. Mahan: University Chemistry 3rd Ed. S.: New York (1985). 2.L. 6. Mann & B. R. Wittig reaction. F. New Delhi (2009). L. SUGGESTED READINGS 1.Khosla. ROH. M. Houben Hoesch Condensation. 5th edition. Finar: Organic Chemistry (Vol. NH2-G derivatives. Schotten Baumann Reaction.Phenols: (Phenol case) Preparation: Cumene hydroperoxide method. G. H. Aldol Condensation. Reactions: Electrophilic substitution: Nitration. Macmillan Publishing Co. T. Narosa (1998). 7. G. Arun Bahl and B. R. B. from diazonium salts. C.Tiemann Reaction. Boyd: Organic Chemistry. Saunders. acetone and benzaldehyde) Preparation: from acid chlorides and from nitriles. P. I. 12. H. W. Chand. Morrison & R. Gattermann-Koch Reaction. Prentice Hall. Benzoin condensation. Barrow: Physical Chemistry Tata McGraw Hill (2007). Treichel & J. Reactions Reaction with HCN. 8. 4. 13. Ltd. Vogel: Textbook of Practical Organic Chemistry.. Clemensen reduction and Wolff Kishner reduction. Orient Longman. Petrucci: General Chemistry 5th Ed. W. Unit 7. I & II). Prentice Hall. Reimer . Chand & Co. S. A. Aldehydes and ketones (aliphatic and aromatic): (Formaldehye. G. B. E. MeerweinPondorff Verley reduction. 11. NaHSO3. M. Graham Solomons : Organic Chemistry. T. Ethers (aliphatic and aromatic): Cleavage of ethers with HI. R. John Wiley and Sons. Orient Longman (1960). Bahl: Advanced Organic Chemistry. Cannizzaro s reaction. Townsend: General Chemistry Cengage Lening India Pvt.I. N. Peter Sykes: A Guide Book to Mechanism in Organic Chemistry. Iodoform test. R. acetaldehyde . Narosa (2004). halogenation and sulphonation. B. C.D. Senior Practical Physical Chemistry. Castellan: Physical Chemistry 4th Edn. 9. 2. Determination of heat capacity of calorimeter for different volumes. 6.CHPP-202: PRACTICAL CHEMISTRY Section A: Physical Chemistry Thermochemistry 1. 4. NH4Cl). 5. Determination of integral enthalpy of solution of salts (KNO3. Determination of enthalpy of ionization of acetic acid. Study of the solubility of benzoic acid in water and determination of DH. Determination of enthalpy of hydration of copper sulphate. Section B: Organic Chemistry 1) Purification of organic compounds by crystallization (from water and alcohol) and distillation. 3) Preparations: Mechanism of various reactions involved to be discussed. Recrystallisation. Determination of enthalpy of neutralization of hydrochloric acid with sodium hydroxide.4 dinitrophenylhydrazone of aldehyde/ketone Page 23 of 80 . (a) Bromination of Phenol/Aniline (b) Benzoylation of amines/phenols (c) Oxime and 2. determination of melting point and calculation of quantitative yields to be done. 3. 2) Criteria of Purity: Determination of melting and boiling points. their use in polynomial approximation and error estimation. Reflection in a point. Matrices in diagonal form.101: CALCULUS AND MATRICES Unit I MATRICES (20 L) R1. Computation of matrix inverses using elementary row operations. cos x. For instance the sequence arising from Tower of Hanoi game. Rotation. Reduction to diagonal form upto matrices of order 3. Radioactive decay. trigonometric. Function of two variables. administration of medicine and cell division.PAPER-6 MAPT. Illustration of proof of convergence of some simple sequences such as (-1)n/n. followed by concepts of recursion and difference equations. Illustrative examples of above concepts from Geometry. sin n/n. Formation and solution of differential equations arising in population growth. Concept of Linar Independence and examples of different bases. Graphs of simple concrete functions such as polynomial. CALCULUS (34 L) Sequences to be introduced through the examples arising in Science beginning with finite sequences. Solutions of a system of linar equations using matrices. Recursion formulae for higher derivative. R3 as vector spaces over R. Chemistry. Log (1+x). Graphs and Level Curves of functions of two variables. Convergence of a sequence and algebra or convergent sequences. Rank of Matrix. sin (2x). matrix form a basic geometric transformations. Combinations and Statistics. Dilation. inverse trigonometric. Partial differentiation upto second order. l/n2. Computation of Taylor s Maclaurin s series of functions such as ex. Physics. Leibnitz theorem. Interpretation of eigenvalues and eigen vectors for such transformations and eigen spaces as invariant subspaces. R3. Subspaces of R2. logarithmic and hyperbolic functions arising in problems or chemical reaction. (1+1/n)n. Successive differentiation. xn with y I. Standard basis for each of them. radioactive decay temperature cooling/heating problem and biological rhythms. Unit II. Page 24 of 80 . R2. the Fibonacci sequence arising from branching habit of trees and breeding habit of rabbits. line and plane. exponential. Translation. simple pendulum. Page 25 of 80 . Using computer aided software for example.L.Unit III.. Springer Verlag (1984). rank. 3. 2. subtraction. determinant. 1. discs in terms of complex variables. George B. T.M Apostal: Calculus. inverse of a matrix. De Moivre s theorem for rational indices and its simple applications. solution of system of equations. Plotting of complex numbers matrices. Suggested Readings: 1.Finney: Calculus and Analytic Geometry. Thomas JR. Ross L. eigenvector. half planes. Kostrikin: Introduction to Algebra. Vol. circles. John Wiley and Sons (Asia) (2002). (L 14) Geometrical representation of addition. eigenvalue. multiplication and division of complex numbers. Lines. A. Operations of matrices. Matlab/ Mathematica/ Maple/ MuPad/ wxMaxima for operations of complex numbers. Statement of the Fundamental Theorem of Algebra and its consequences. Pearson Education (Singapore) (2001). uses of coal tar bases chemicals. Properties of lubricants (viscosity index. its composition. 3. (b) Petroleum and Petrochemical Industry: Composition of crude petroleum. 2. artificial sweetners. Coal liquefaction and Solvent Refining. cloud point. synthetic lubricants. Propylene oxide. Fractional Distillation (Principle and process). Reforming Petroleum and non-petroleum fuels (LPG.Coal gas. iodine number. Food additives A general study of food flavours. CLEANSING AGENTS AND FOOD ADDITIVES 1. Soap and Synthetic Detergent. Butadiene. acid value. bio-gas.PAPER-7 ICPT-202: INDUSTRIAL CHEMISTRY-2: FOSSIL FUELS. Fractionation of coal tar. Coal gasification (Hydro Gasification and Catalytic gasification). hydrogenation of oils. Classification of fuels and their calorific value. LNG. rancidity. different types of soap and their composition. Fuel Chemistry Review of energy sources (renewable and non-renewable). pore point) and their determination. Refining and different types of petroleum products and their applications. carbonization of coal. LABS). colours and preservatives. (c) Lubricants: Classification of lubricants. producer gas and water gas composition and uses. distillation of completely miscible and nonmiscible oils. Petrochemicals: Vinyl acetate. Oils and Fats Classification of oils. saponification value. lubricating oils (conducting and non-conducting) Solid and semisolid lubricants. preparation of soap and detergent. CNG. clean fuels. Isoprene. detergent binders and builders. requisites of a good metallurgical coke. ABS. Cracking (Thermal and catalytic cracking). (a) Coal: Uses of coal (fuel and non fuel ) in various industries. fat splitting. fuels derived from biomass). surfactants (LAS. Page 26 of 80 . fuel from waste. synthetic fuels (gaseous and liquids). Toluene and its derivatives Xylene. O. 3.. R. milk and mustard oil for adulterants. Sharma: Engineering Chemistry. saponification value. Estimation of glucose in food samples. Determination of alkali in water samples and soaps. D. Venkappayya. Estimation of hardness of water by titration with soap solution. 8. Gopalan. Dhanpat Rai & Sons. New Delhi. Separation of essential oils by soxhlet extractor. Testing of turmeric powder. Ltd. Goel Publishing House. Analysis of oils and fats (iodine value. 2. 4. C. 9. New Delhi. P. acid value). K. CBS Publishers. Vikas Publications. 6. Preparation of soap. S. B. 5. S. Extraction of natural coloring and flavoring agent from flowers and fruits 7. I & II. 5. P. Delhi. New Delhi. M. 3. Narula: Industrial Chemistry.ICPP-202: PRACTICAL INDUSTRIAL CHEMISTRY 1. Bhatia: Chemical Process Industries. Page 27 of 80 . 4. K. Meerut. Jain: Engineering Chemistry. Jain. Vermani. A. Nagarajan: Engineering Chemistry. Estimation of Available Oxygen in Hydrogen Peroxide. C. Vol. 2. Galgotia Publications Pvt. Suggested Readings 1. handbooks. A course in written English. Daniel G. transitional and concluding paragraphs. Press. G. 6. common errors to be avoided. formal writings/reports. Additional Reference Books 5. Riordan & Steven A. SUGGESTED READINGS 1. Biztantra. Cambridge Univ. Englewood Cliffs. thesis statement. Pauley. S. Greenbaum. Longman. Unit 3 Technical Writing: Scientific and technical subjects. Writing as thinking: A guided process approach. formal and informal writings. London. R. Svartik: A comprehensive grammar of the English language. M. developmental. differences between speech and writing. Panley: Technical Report Writing Today Biztaantra. distinct features of speech. Heasely: Study Writing. introductory. agenda. Leech and J. developing the thesis. 5th Edition (2004). Daniel G.PAPER-8 ENPT-101: TECHNICAL WRITING AND COMMUNICATION IN ENGLSH Unit 1 Communication: Language and communication. 4. notices. coherence and cohesion. Riordan. descriptive. Biztantra: Technical Report Writing Today. distinct features of writing. 2. Quirk. L. memorandum. expository and argumentative writing. narrative. Unit 2 Writing Skills. linguistic unity. Prentice Hall Reagents. For academic and professional purposes. Selection of topic. Frank. 3. letters. Steven E. Hamp-Lyons and B. minutes. 8th Edition (2004). Scot Ober Contemporary Business Communication. Page 28 of 80 . manuals. registers. Reference manual for Open Office available at: http://www. Problem Solving (10 Periods) Notion of algorithms. memory hierarchy. Rajaraman. Forthcoming title in PearsonEducation Note: Use of Open Office/Star Office is recommended. Characteristics. stepwise methodology of developing an algorithm. Fundamentals of Computers.Units of a computer. Applications. System Security (virus/firewall etc. Reservations. [2] Anita Goel. developing macros in spreadsheet. PHI. Data Representation (8 Periods) Binary representation of integers and real numbers.openffice. ASCII. 2's Complement. Uses of computers. Elements. switch.)? I-Tax. server-client architecture. Unicode. Basic Computer Organization . Fourth Edition.PAPER-8 CSPT-101: COMPUTATIONAL SKILLS Computer Fundamentals (12 Periods) Introduction to Computers: Characteristics of Computers. Fundamentals of Computers. router. ALU. User Interface with the Operating System. BCD. Addition and subtraction of binary numbers. General Awareness (4 Periods) IT Act. Multimedia (4 Periods) Introduction. as they are freely downloadable. Banking? SUGGESTED READINGS : [1] V.org Page 29 of 80 . Networks terminology (4 Periods) Types of networks. CPU. I/O devices. 1's Complement. System Tools. Types and generations of Computers. creating charts.CSPP-101: PRACTICALS COMPUTATIONAL SKILLS 1. Page 30 of 80 . Spreadsheet Handing. 2. basic functions and formulas. tables and graphs. Working with worksheets. Creating a spreadsheet. Presentation Software 4. Familiarizing with the Operating System. entering and formatting information. Networking Configuration. Defined projects will be done by the students and evaluated by the instructor. Firewall setting 5. Control Panel. Document Preparation 3. SEMESTER III Page 31 of 80 . Partial miscibility of liquids: Critical solution temperature. Phase diagrams of one-component systems (water and sulphur) and two component systems involving eutectics. Nernst distribution law and its applications. Thermodynamics of a reversible cell. Gibbs Phase Rule and its thermodynamic derivation. Unit 4 Electrochemistry Reversible and irreversible cells.PAPER-9 CHPT-303: CHEMISTRY-3 (SOLUTIONS. effect of impurity on partial miscibility of liquids. Page 32 of 80 . equivalent and molar conductivity and their variation with dilution for weak and strong electrolytes. Measurement of EMF of a cell. congruent and incongruent melting points (lead-silver. Transference number and its experimental determination using Hittorf and Moving boundary methods. deviations from Raoult s law non-ideal solutions. Vapor pressure-composition and temperature-composition curves of ideal and non-ideal solutions. Electrochemical series. Nernst equation and its importance. CONDUCTANCE. Unit 3 Conductance Conductivity. Standard electrode potential. Unit 2 Phase Equilibrium Phases. criteria of phase equilibrium. ELECTROCHEMISTRY AND FUNCTIONAL GROUP CHEMISTRY-2) Section A: Physical Chemistry-2 (30 Lectures) Unit 1 Solutions Thermodynamics of ideal solutions: Ideal solutions and Raoult s law. hydrolysis constant of a salt. Azeotropes. Types of electrodes. solvent extraction. components and degrees of freedom of a system. FeCl3-H2O and Na-K only). Concept of EMF of a cell. solubility and solubility products of sparingly soluble salts. Derivation of Clausius Clapeyron equation and its importance in phase equilibria. Lever rule. Distillation of solutions. Kohlrausch law of independent migration of ions. Immiscibility of liquids. ionic product of water. Ionic mobility. Applications of conductance measurements: determination of degree of ionization of weak electrolyte.Principle of steam distillation. Conductometric titrations (only acid-base). Determination of configuration of Page 33 of 80 . Reactions: Comparative study of nucleophilicity of acyl derivatives. Hinsberg test. Reactions: Hell Vohlard . sulphonation. Esters and Amides from acids and their inter-conversion. Schotten Baumann Reaction. Keto-enol tautomerism. pH determination using hydrogen electrode and quinhydrone electrode. Liquid junction potential and salt bridge.Zelinsky Reaction. Hofmann Bromamide reaction. Glucose and Fructose (open chain and cyclic structure). Unit 5 Carboxylic acids and their derivatives Carboxylic acids (aliphatic and aromatic) Preparation: Acidic and Alkaline hydrolysis of Esters. Diazonium salts: Preparation: from aromatic amines. phenol.calculation of thermodynamic properties: G. Carboxylic acid derivatives (aliphatic): (Upto 5 carbons) Preparation: Acid chlorides. dyes. Unit 8. Reformatsky Reaction. Unit 7 Amines and Diazonium Salts Amines (Aliphatic and Aromatic): (Upto 5 carbons) Preparation: from alkyl halides. Reactions: Hofmann Vs Saytzeff elimination. Perkin condensation. H and S from EMF data. Concentration cells with transference and without transference. Calculation of equilibrium constant from EMF data. Potentiometric titrations -qualitative treatment (acid-base and oxidation-reduction only). Carbylamine test. Reactions: Synthetic uses of ethylacetoacetate (preparation of non-hetero molecules having upto 6 carbon). Gabriel s Phthalimide synthesis. Unit 6 Active methylene compounds: Preparation: Claisen ester condensation. and General Properties. Anhydrides. Electrophilic substitution (case aniline): nitration. Section B: Organic Chemistry-3 (30 Lectures) Functional group approach for the following reactions (preparations & reactions) to be studied in context to their structure. Carbohydrates: Classification. bromination. with HNO2. Reactions: conversion to benzene. R. P.I. L. T. fruit juices. Kotz. Khosla: Senior Practical Physical Chemistry. J. Narosa (2004). maltose. shampoos and soaps (use dilute solutions of soaps and shampoos to prevent damage to the glass electrode) using pH-meter. R. Barrow: Physical Chemistry Tata McGraw Hill (2007). J. S. CHPP-303: PRACTICAL CHEMISTRY Section A: Physical Chemistry 1. B. T. L. E. 6. 3rd Edn. Prentice Hall. Bahl: Advanced Organic Chemistry.: New Delhi (2009). Orient Longman. C. H. Finar: Organic Chemistry (Vol. H. 13. Treichel. 5th Edn.monosaccharides. Chand & Co. cellobiose. Narosa (1998). 12. John Wiley & Sons. 2. ascending and descending in monosaccharides. B. Ltd. John Wiley and Sons. b) Preparation of buffer solutions: (i) Sodium acetate-acetic acid (ii) Ammonium chloride-ammonium hydroxide Measurement of the pH of buffer solutions and comparison of the Page 34 of 80 . I & II). Saunders: Practical Organic Chemistry. C. 10. Mann & B. 8. Townsend. Prentice Hall. Chand. pH measurements a) Measurement of pH of different solutions like aerated drinks. W. General Chemistry. R. 3. G. M. G. Boyd: Organic Chemistry. Cengage Learning India Pvt. 5. Jerry March: Advanced organic Chemistry. S. General Chemistry. Macmillan Publishing Co. 1960. M.. lactose) and polysacharrides (starch and cellulose) excluding their structure elucidation. G. Structure of disacharrides (sucrose. 11. Castellan: Physical Chemistry 4th Ed. SUGGESTED READINGS 1. F. Peter Sykes: A Guide Book to Mechanism in Organic Chemistry. 4. 5th Edn. R. 7. Mahan: University Chemistry. A. 9. W. Arun Bahl and B. Vogel: Textbook of Practical Organic Chemistry. S. Petrucci. Mutarotation. Morrison & R. Orient Longman. Graham Solomon s: Organic Chemistry.D. I. absolute configuration of Glucose and Fructose. 14. N.: New York (1985). B. (f) Preparation of methyl orange. Distribution Study of the equilibrium of one of the following reactions by the distribution method: Section B: Organic Chemistry Preparations: Mechanism of various reactions involved to be discussed.values with theoretical values. Recrystallisation. (a) Nitration of Nitrobenzene (b) Preparation of carboxylic acid by alkaline hydrolysis of ester/amide. 2. Page 35 of 80 . determination of melting point and calculation of quantitative yields to be done. (c) Oxidation of alcohol/aldehydes/hydrocarbons to carboxylic acid (d) Osazone from glucose/fructose (e) Amides and anilides from carboxylic acid. groups of symmetries of (i) iso equilateral triangle. polynomial rings. order of an element. complex roots of unity. Z . Cyclic groups from number systems. examples. Q. Algebra of Linear transformations and matrix of a linear transformation Linear functional over real & vector spaces . (ii) an equilateral triangle. Matlab/ Mathematica/ Maple/ MuPad/ wxMaxima in Linear Transformations. Rings: Definition and examples of rings. the general linear group GLn (n. Cosets. R and C field of radial functions. basis. and characterization. group of symmetries. rings from number systems. the permutation groups Sym (n). Group of quaternion. invertible linear transformations (characterizations). Vector spaces: Definition and examples of vector spaces. rank. Integral domains and fields. cyclic subgroups. examples of commutative and noncommutative rings. Index of subgroup. Use of computer aided software for example. Linear Transformations on real and complex vector spaces: definition. kernel. square and permutation groups. (iii) a rectangle. Subgroups. the subgroups generated by a subset and the commutator subgroup of group. range.definition and examples. invariance of basis size dimension of vector space. examples of field. isomorphism theorems. Lagrange s theorem. nullity. examples of subgroups including the center of a group. Subrings and ideals. Subspaces and its properties. R). Z n the ring of integers modulo n ring of real quaternion rings of matrices. rectangle. Normal subgroups: their definition.PAPER-10 MAPT-303: ALGEBRA Groups: Definition and examples of groups. Linear independence. and (iv) a square. and rings of continuous functions. Page 36 of 80 . circle group. examples of abelian and non-abelian groups: the group Zn of integers under addition modulo n and the groups U(n) of units under multiplication modulo n. Quotient groups. Springer-Verlag (1991). C. Cambridge Press (1979). Linear algebra and Geometry. Page 37 of 80 . 2. Andrews: Number Theory. 4.W. Narosa (1999). Curtis.. 4th Edn. Joseph A Gallian: Contemporary Abstract Algebra. 3. George E.Recommended Books 1. Blotin. Hindustan Publishing Corporation (1984). Linear Algebra. David M. an introductory approach. toners and lakes pigments. Ferrous and Non-Ferrous alloys. quick setting cements. emulsifying agents. Working of following batteries: Pb acid. ingredients and their role. armoured glass. Fire retardant. 5. coloured glass. Silicate Industries (a) Glass: Glassy state and its properties. Dyes. Vehicle. Oil paint. Metallic coatings (electrolytic and electroless). their types and manufacture. Special paints (Heat retardant. Page 38 of 80 . Manufacture of the following fertilizers: Urea. Fillers. preliminary treatment of surface. Manufacture and processing of glass. (b) Ceramics: Important clays and feldspar. lead glass. Alloys Classification of alloys. Compound and mixed fertilizers Potassium Chloride. Fertilizers: Fertilizers: Different types of fertilizers. classification (silicate and non silicate glasses). High technology ceramics and their applications. Ammonium phosphates. Battery Primary and secondary batteries. Plastic paint). ceramic. Eco-friendly paint. 4. Solid state electrolyte battery. Specific properties of elements in alloys. classification of surface coatings. Manufacture of cement and the setting process. Polyphosphate. Manufacture of Steel (removal of silicon decarbonization. Fuel Cells. photosensitive glass. super conducting and semi conducting oxides. composition and related properties. borosilicate glass. metal spraying and anodizing. fluorosilicate. battery components and their role. safety glass. 2. fullerenes carbon nanotubes and carbon fiber. 3.PAPER-11 ICPT-303: INDUSTRIAL CHEMISTRY-3: INORGANIC MATERIALS 1. Paints and pigments-formulation. Pigments. additives. Characteristics of Battery. Surface Coatings Objectives of coatings surfaces. Potassium sulphate. Solar cell and polymer cell. Super phosphate. Enamels. Calcium ammonium nitrate. Composition and properties of the following types of glasses: Soda lime glass. Water and Oil paints. Ammonium nitrate. Li-Battery. modified oils. Wax polishing. Thinners. (c) Cements : Classification of cement. Phase transfer catalysts. 7. Composition and properties of different types of steels. nitriding. desulphurization dephosphorisation) and surface treatment (argon treatment. application of zeolites as catalysts.demanganization. heat treatment. homogenous catalysis (catalytic steps and examples) and heterogenous catalysis (catalytic steps and examples) and their industrial applications. preparation and explosive properties of lead azide. Deactivation or regeneration of catalysts. PETN. Chemical Explosive Origin of explosive properties in organic compounds. 6. Introduction of rocket propellant. carburizing). Page 39 of 80 . Catalysis General principles and properties of catalysts. cyclonite (RDX). Dhanpat Rai & Sons. 7. Jain. UK. Rousseau: Elementary Principles of Chemical Processes. E. B. New Delhi. 2. Suggested Readings 1. 5. K. 3. Preparation of pigment (zinc oxide). W. 7. W. P. R. R. Vol-I. Estimation of Calcium in Calcium ammonium nitrate fertilizer. Gopalan. Ni). 5. S. (Cu. Electroless metallic coatings on ceramic and plastic material. New Delhi. M. New Delhi. A. CBS Publishers. Wiley Publishers. Analysis of Cement. 6. R. Analysis of (Cu. D. Kent: Riegel s Handbook of Industrial Chemistry. Ellis Horwood Ltd. 4. Zn ) in alloy or synthetic samples. K. R. H. Determination of composition of dolomite (by complexometric titration). 3. 8. Bowen. Kingery. Uhlmann: Introduction to Ceramics. 2. Estimation of phosphoric acid in superphosphate fertilizer. D. Jain: Engineering Chemistry. 4. Vikas Publications. Sharma: Engineering Chemistry. Nagarajan: Engineering Chemistry. Felder. Meerut Page 40 of 80 . Delhi. C. New Delhi. . Wiley Publishers. 6. Determination of free acidity in ammonium sulphate fertilizer. J. D.ICPP-303: PRACTICAL INDUSTRIAL CHEMISTRY 1. Stocchi: Industrial Chemistry. Venkappayya. M. Goel Publishing House. Metabolism. Denaturation of proteins. sources. Environmental effects of Ozone. biological importance. Liposomes and their biological functions and underlying applications. Genetic Code. § Enzymes: Nomenclature. Lipid membrane. nitrogen and sulphur. § Proteins: classification. Biogeochemical cycles of carbon. Unit II: § Lipids: Biological importance of triglycerides and phosphoglycerides and cholesterol. § Air Pollution: Major regions of atmosphere.PAPER-12 PAPER 602: BIOCHEMISTRY AND ENVIRONMENTAL CHEMISTRY Unit I: § Carbohydrates: Biological importance of carbohydrates. Krebs cycle. Ecosystems. Unit III: § Environment and it s segments. Coenzymes and cofactors. Page 41 of 80 . Mechanism of enzyme action. Enzyme inhibitors. Major sources of Air pollution. Active site. § Structure of DNA (Watson-Crick model) and RNA. Classification. Introduction to Gene therapy. Chemical and photochemical reactions in atmosphere.pleated sheets. Glycolysis. Biological roles of DNA and RNA: Replication. particle size and chemical nature. Air pollutants: types. Alcoholic and Lactic acid fermentations. Primary and secondary and tertiary structures of proteins: -helix and . Transcription and Translation. Cellular currency of energy (ATP). Introduction to Biocatalysis: Importance in Green Chemistry and Chemical Industry. Stereospecificity of enzymes. Characteristics (mention of Ribozymes). Photochemical Smog: its constituents and photochemistry. M. W. Freeman and Co. Freeman and Co.A.M. 3.L. Principles of Biochemistry. Page 42 of 80 . Impacts of water pollution on hydrological and ecosystems. § Water Pollution: Hydrological cycle. 4. Environmental Studies. 6th Edn.H. S. Berg. Unit IV: § Energy and Enviornment: Sources of energy: Coal. Hydrogen. Murray. Nuclear Fusion / Fisson. 2. petrol and Natural gas. Brooks/Cole (2006).W.M.H. Mayes and V. Techniques for measuring water pollution. Tidal and Hydel etc. Selective and Scientific Books. Harper s Illustrated Biochemistry. Stryer. D. Recommended Texts: 1.K. J.K. water resources. Water purification methods. 5. A. Cox. Green house effect.L. § Nuclear Pollution: Disposal of nuclear waste. global warming. P. Granner. Sources and nature of water pollutants. Environmental Science 11th edition. (2009). PAPER 602: PRACTICAL BIOCHEMISTRY AND ENVIRONMENTAL CHEMISTRY 1. Climate change. Miller. Biochemistry. R. Mishra. G. J. nuclear disaster and it s management. Lehninger. W. geothermal. Determine the concentration of the unknown sample using the standard curve plotted. Environmental Chemistry. and A. Solar energy. To perform quantitative estimation of protein using Lowry s method. IV Edition. CRC Press (2005). (2006).L.E. Rodwell.T. aquatic ecosystems. Manahan. Techniques of measuring air pollutants. Tymoczko and L. New Delhi (2005). D. Controls of air pollution.§ Effects of air pollution on living organisms and vegetation. Lange medical Books/ McGrawHill (2009). 6. Nelson. XXVIII edition. 4. To study the effect of temperature. Hardness of water by EDTA titration. Study of the activity of Trypsin using fresh tissue extracts. organic solvents.2. Quantitative estimation of oxidisable organic matter in soil. Effect of inhibitor on the action of salivary amylase. 6. Page 43 of 80 . 9. 3. Coli. 11. 5. 10. Isolation of Genomic DNA from E. Qualitative analysis of the soil from different locations for pH and different water soluble cations and anions. on semi-permeable membrane. Study of the action of salivary amylase at optimum conditions. 7. Effect of temperature on the action of salivary amylase. 12. Study of pH and conductivity of tap water and polluted water. carbonate and bicarbonates by volumetry and calcium and magnesium by EDTA titration. Effect of pH on the action of salivary amylase. 8. SEMESTER IV Page 44 of 80 . Hydrometallurgy.r. Ti. Boyle temperature Page 45 of 80 . Halides and oxohalides: PCl3. Structure. and AlfredRochow scales).Block Elements Periodicity in s. Hydrides of nitrogen (NH3. van Arkel-de Boer process and Mond s process.Block Elements Hydrides and their classification (ionic. Allotropy in C. SOCl2 and SO2Cl2 Section B: Physical Chemistry-3 (30 Lectures) Unit 1 Kinetic Theory of Gases Postulates of Kinetic Theory of Gases and derivation of the kinetic gas equation. Ni. Zn): electrolytic. diagonal relationship and anomalous behaviour of first member of each group. Pb. electronic configuration.and p. and P. atomic and ionic size.block elements. oxidative refining. N2H4.t. NH2OH) Oxoacids of P. Methods of purification of metals (Al. inert pair effect. electronegativity (Pauling. ionization enthalpy. N3H. Deviation of real gases from ideal behaviour. Kroll process. acidic/basic nature of the following compounds and their applications in industrial. S and Cl. causes of deviation. PCl5. S. Cu. STATES OF MATTER AND PHASE EQUILIBRIUM) Section A: Inorganic Chemistry-2 (30 Lectures) Unit 1 General Principles of Metallurgy Chief modes of occurrence of metals based on standard electrode potentials. Mullikan. Concept of multicentre bonding (diborane).and p. Ellingham diagrams for reduction of metal oxides using carbon as reducing agent. Fe.and p. Unit 2 s. Vander Waals equation of state for real gases. covalent and interstitial). Parting process. Oxidation states with reference to elements in unusual and rare oxidation states like carbides and nitrides). compressibility factor. Unit 3 Compounds of s.block elements w. organic and environmental chemistry. structure and properties with respect to stability of hydrides of p.PAPER-13 CHPT-404: CHEMISTRY-4 (CHEMISTRY OF s & p BLOCK ELEMENTS. bonding and their important properties like oxidation/reduction. W. KCl and CsCl (qualitative treatment only). Treichel & J. Narosa (1998). first and second order reactions (both for equal and unequal concentrations of reactants). X Ray diffraction by crystals. Comparison of the two theories (qualitative treatment only). Viscosity of gases and effect of temperature and pressure on coefficient of viscosity (qualitative treatment only). 3. collision frequency. C. Order and molecularity of a reaction. Temperature dependence of these distributions. Laws of Crystallography . Critical phenomena. G. Derivation of integrated rate equations for zero. H. Bragg s law. Collision cross section. G. M. crystal systems. Townsend: General Chemistry Cengage Lening India Pvt. Unit 2 Liquids Surface tension and its determination using stalagmometer. Unit 4 Chemical Kinetics The concept of reaction rates. Law of rational indices. Mahan: University Chemistry 3rd Ed.(derivation not required). collision diameter and mean free path of molecules. Half life of a reaction. Barrow: Physical Chemistry Tata McGraw Hill (2007). Glasses and liquid crystals. Kotz. M. Effect of temperature on surface tension and coefficient of viscosity of a liquid (qualitative treatment only) Unit 3 Solids Forms of solids. Page 46 of 80 .Law of constancy of interfacial angles. Theories of Reaction Rates: Collision theory and Activated Complex theory of bimolecular reactions. Viscosity of a liquid and determination of coefficient of viscosity using Ostwald viscometer. New Delhi (2009). Miller indices. Castellan: Physical Chemistry 4th Edn. Defects in crystals. SUGGESTED READINGS 1. Symmetry elements. Effect of temperature. catalyst and other factors on reaction rates. Bravais lattice types and identification of lattice planes. P. average and root mean square velocities (no derivation). Ltd. pressure. unit cells. collision number. 4. Narosa (2004). J.. B. Maxwell Boltzmann distribution laws of molecular velocities and molecular energies (graphic representation derivation not required) and their importance. General methods for determination of order of a reaction. Structures of NaCl. critical constants and their calculation from Vander Waals equation. Most probable. Concept of activation energy and its calculation from Arrhenius equation. R. 2. Andrews isotherms of CO2. Prentice Hall. I . Pb2+. CH3COO . S2O32 . 8. Fe3+. Senior Practical Physical Chemistry. 7th Edn. 6th Edn. CHPP-404: PRACTICAL CHEMISTRY Section A: Inorganic Chemistry Semi-micro qualitative analysis using H2S of mixtures. Ag+. NO3 .I. D. F. Cl . PO43-. Ltd. A. SO32 . Sr2+. 12. Vogel.S. Cu2+. R. Chand & Co. K+ Anions : CO32 . SO42-. Co2+.I. NO3 . Qualitative Inorganic Analysis. b) Study of the variation of viscosity of an aqueous solution with concentration of solute. Atkins: Inorganic Chemistry. Bi3+. Lee: A New Concise Inorganic Chemistry. BO33-. a) Determination of the surface tension of a liquid or a dilute solution using a stalagmometer. A. Vogel. J. Macmillan Publishing Co. Prentice Hall. 7.not more than four ionic species (two anions and two cations and excluding insoluble salts) out of the following: Cations : NH4+.D. D. a) Determination of the relative and absolute viscosity of a liquid or dilute solution using an Ostwald s viscometer. B. Ca2+. Ni2+. 11. C2O42-. Br . Cr3+.L. Mn2+. Khosla. 10. F(Spot tests should be carried out wherever feasible) Section B: Physical Chemistry (I) Surface tension measurement (use of organic solvents excluded). Shriver and P. b) Study of the variation of surface tension of a detergent solution with concentration. E. (III) Phase equilibria a) Construction of the phase diagram of a binary system (simple Page 47 of 80 . Quantitative Chemical Analysis. (II) Viscosity measurement (use of organic solvents excluded). Al3+. H. Ba2+. Viva Books Pvt. Sn2+. F. Oxford University Press. S2 . Petrucci: General Chemistry 5th Ed. John Wiley. R.5. 6.A. 9. Wilkinson: Basic Inorganic Chemistry. Cotton & G.: New York (1985).B. W. Gary Wulfsberg: Inorganic Chemistry. Zn2+. Cd2+. c) Study of the variation of mutual solubility temperature with concentration for the phenol water system and determination of the critical solubility temperature. b) Determination of the critical solution temperature and composition of the phenol water system and study of the effect of impurities on it. Page 48 of 80 .eutectic) using cooling curves. Wave Motion: One dimensional plane wave. Dead beat motion.PAPER-14 PHPT-303: PHYSICS -2: WAVE AND OPTICS Oscillations and Waves (Total Number of Lectures = 30) Simple Harmonic Motion: Simple Harmonic Oscillator. Standing wave on a stretched string (both ends fixed). circular aperture (qualitative). Superposition of two SHM: (i) collinear SHM cf same frequency (ii) collinear SHM of different frequencies phenomenon of Beats (iii) SHM of same frequency but perpendicular to each other and (iv) Lissajous figures. qualify factor. position of maxima and minima). Couples oscillatory with two degrees of freedom. Damped Harmonic Motion: Equation of motion. Fraunhofer Diffraction single slit (intensity distribution. Normal modes. Division of wave front: Young s double slit experiment. Forced Oscillations: Equation of motion. Classical wave equation. Motion of simple and compound pendulum. Lightly damped system: relaxation time. Division of amplitude: Newton rings. Energy in simple harmonic motion. Wave Optics (Total Number of Lectures = 30) Interference: Essential conditions for observing interference. colour of thin films. plan diffraction grating. complete solution. Diffraction: Fresnel and Fraunhofer diffraction. Resonance. Quality factor. logarithmic decrement. Rayleigh s Page 49 of 80 . Critically damped system. General method of finding normal modes for a system of two degrees of freedom. Sharpness of resonance. Couples Oscillator: Degrees of freedom. Superposition principle. Steady state solution. Loaded spring. resolving power of grating. Tata McGraw Hill (2008). 5. Page 50 of 80 .K.Tata Mc-Graw Hill (1988). 6. 4. Francis Arthur Jenkins and Heavy Elliott White: Fundamentals of optics. B. Tata Mc-Graw Hill (1976). A.K. Thyagarajan: Contemporary optics. CBS Pub. Polarizing materials. Double refraction. Light propagation in anoxia crystals. Polarizer.K. 2. N. Bajaj: The physics of waves and oscillations. A. Khanna and Gulati: Introduction to Optics. Fresnel diffraction: half period zone. Ajoy Ghatak: Optics. Nicol Prism. & Dist. zone plate. REFERENCES 1. 7. Law of Malus. (1987). rectilinear propagation of light. Plenum Press (1978). Mathu: Optics. French: Vibrations and Waves. 3.criterion.P. Ghatak & K. Polarization: Polarization of light (plane polarized light). Analyzer. 6. To determine the Temperature Coefficient of Resistance ( ) by Platinum Resistance Thermometer (PRT). 2. New Delhi. 3. 7. Flint: Advanced Practical Physics. To study the polarization of light by the reflection and to determine the polarizing angle for air-glass interface. To determine the wavelength of Sodium light using plane diffraction grating. To draw a calibration curve for a Thermocouple using a Potentiometer. Asia Publishing House. To determine Stefan s Constant. To determine the Coefficient of Thermal Conductivity of Copper by Searle s apparatus.T. 2. 8.PHPP-303: PRACTICAL PHYSICS 1. 4. Nelson and Jon Ogborn: Practical Physics. 9. 3. B. To determine the Cauchy s constant and dispersive power of a prism using mercury light. 5.L. Worsnop and H. 10. To determine wavelength of sodium light suing Newton s rings. Kitab Mahal. Assume R_____________. Suggested Books for Reference 1. To determine the Coefficient of Thermal Conductivity of a bad conductor by Lee and Charlton s disc method. To determine wavelength of sodium light using Fresnel Biprism. Indu Prakash and Ramakrishna: A Text Book of Practical Physics. Page 51 of 80 . New Delhi. PAPER-15 ICPT-404: INDUSTRIAL CHEMISTRY-4: PHARMACEUTICALS, FERMENTATION, PESTICIDES & PERFUMES 1. Drugs and Pharmaceuticals Drug discovery, design and development; Basic Retrosynthetic approach. Synthesis of the representative drugs of the following classes: analgesics agents, antipyretic agents, anti-inflammatory agents (Aspirin, paracetamol, lbuprofen); antibiotics (Chloramphenicol); antibacterial and antifungal agents (Sulphonamides; Sulphanethoxazol, Sulphacetamide, Trimethoprim); antiviral agents (Acyclovir), Central Nervous System agents (Phenobarbital, Diazepam),Cardiovascular (Glyceryl trinitrate), antilaprosy (Dapsone), HIVAIDS related drugs (AZT- Zidovudine). 2. Cosmetics and Perfumes A general study including preparation and uses of the following: Hair dye, hair spray, Shampoo, Sun-tan lotions, face powder, lipsticks, talcum powder, nail enamel, creams (cold, vanishing and shaving creams), antiperspirants and artificial flavours. Essential oils and their importance in cosmetic industries with reference to Eugenol, Geraniol, sandalwood oil, eucalyptus, rose oil, -phenyl ethyl alcohol, Jasmone, Civetone, Muscone. 3. Pesticides General introduction to pesticides (natural and synthetic), benefits and adverse effects, changing concepts of pesticides, structure activity relationship, synthesis and technical manufacture and uses of representative pesticides in the following classes: Organochlorines (DDT, Gammexene,); Organophosphates (Malathion, Parathion ); Carbamates (Carbofuran and carbaryl); Quinones ( Chloranil) , Anilides (Alachlor and Butachlor). 4. Fermentation Industries Aerobic and anaerobic fermentation. Production of (i) Ethyl alcohol and citric acid, (ii) Antibiotics; Pencillin, Cephalosporin, Chloromycetin and Streptomycin, (iii) Lysine, Glutamic acid, Vitamine B2 Vitamine B12 and Vitamine C. Page 52 of 80 ICPP-404: PRACTICAL INDUSTRIAL CHEMISTRY 1. Preparation of talcum powder. 2. Preparation of shampoo. 3. Preparation of enamels. 4. Preparation of hair remover. 5. Preparation of face cream. 6. Preparation of Aspirin and its analysis. 7. Preparation of nail polish and nail polish remover. 8. To calculate acidity/alkalinity in given sample of pesticide formulations as per BIS specifications. 9. Preparation of simple organophosphates, phosphonates and thiophosphates 10. Preparation of Magnesium bisilicate (Antacid). Suggested Readings 1. E. Stocchi: Industrial Chemistry, Vol -I, Ellis Horwood Ltd. UK. 2. P.C. Jain, M. Jain: Engineering Chemistry, Dhanpat Rai & Sons, Delhi. 3. B.K. Sharma: Industrial Chemistry, Goel Publishing House, Meerut. 4. G.L. Patrick: Introduction to Medicinal Chemistry, Oxford University Press, UK. 5. Hakishan, V.K. Kapoor: Medicinal and Pharmaceutical Chemistry, Vallabh Prakashan, Pitampura, New Delhi. 6. R. Cremlyn: Pesticides, John Wiley. 7. William O. Foye, Thomas L., Lemke , David A. William: Principles of Medicinal Chemistry, B.I. Waverly Pvt Ltd. New Delhi. Page 53 of 80 PAPER-16 EL 310 (vi) INTELLECTUAL PROPERTY RIGHTS (IPR) In this era of liberalization and globalization, the perception about science and its practices have undergone dramatic change. The importance of protecting the scientific discoveries, with commercial potential or the intellectual property rights is being discussed at all levels statutory, administrative, and judicial. With India ratifying the WTO agreement, it has become obligatory on its part to follow a minimum acceptable standard for protection and enforcement of intellectual property rights. The purpose of this course is to apprise the students about the multifaceted dimensions of this issue. Unit I Introduction to Intellectual Property Historical Perspective, Different Types of IP, Importance of protecting IP. Copyrights Introduction, How to obtain, Differences from Patents. Trade Marks Introduction, How to obtain, Different types of marks Collective marks, certification marks, service marks, Trade names, etc. Differences from Designs. Patents Historical Perspective, Basic and associated right, WIPO, PCT system, Traditional Knowledge, Patents and Healthcare balancing promoting innovation with public health, Software patents and their importance for India. Geographical Indications Definition, rules for registration, prevention of illegal exploitation, importance to India. Industrial Designs Definition, How to obtain, features, International design registration. Page 54 of 80 Unit II Unit III Unit IV Unit V Unit VI Unit VII Unit VIII Layout design of integrated circuits Circuit Boards, Integrated Chips, Importance for electronic industry. Trade Secrets Introduction and Historical Perspectives, Scope of Protection, Risks involved and legal aspects of Trade Secret Protection. Different International agreements (a) Word Trade Organization (WTO): (i) General Agreement on Tariffs & Trade (GATT), Trade Related Intellectual Property Rights (TRIPS) agreement (ii) General Agreement on Trade related Services (GATS) (iii) Madrid Protocol (iv) Berne Convention (v) Budapest Treaty (b) Paris Convention WIPO and TRIPS, IPR and Plant Breeders Rights, IPR and Biodiversity IP Infringement issue and enforcement Role of Judiciary, Role of law enforcement agencies Police, Customs etc. Economic Value of Intellectual Property Intangible assets and their valuation, Intellectual Property in the Indian Context Various laws in India Licensing and technology transfer. Unit IX Unit X Unit XI Suggested Readings 1. N.K. Acharya: Textbook on intellectual property rights, Asia Law House (2001). 2. Manjula Guru & M.B. Rao, Understanding Trips: Managing Knowledge in Developing Countries, Sage Publications (2003). 3. P. Ganguli, Intellectual Property Rights: Unleashing the Knowledge Economy, Tata McGraw-Hill (2001). 4. Arthur Raphael Miller, Micheal H.Davis; Intellectual Property: Patents, Trademarks and Copyright in a Nutshell, West Group Publishers (2000). 5. Jayashree Watal, Intellectual property rights in the WTO and developing countries, Oxford University Press, Oxford. Page 55 of 80 SEMESTER V Page 56 of 80 . Crystal field effects for weak and strong fields. Co. Square planar coordination. Postulates of quantum mechanics. Crystal field stabilization energy (CFSE). magnetic properties. Born-Oppenheimer approximation: Separation of molecular energies into translational. QUANTUM CHEMISTRY AND SPECTROSCOPY) Section A: Inorganic Chemistry-3 (30 Lectures) Unit 1 Transition Elements (3d series) General group trends with special reference to electronic configuration. Tetragonal distortion of octahedral geometry. Spectrochemical series. vibrational and electronic components. Fe. ability to form complexes and stability of various oxidation states (Latimer diagrams) for Mn. magnetic and catalytic properties. Structural and stereoisomerism in complexes with coordination numbers 4 and 6. Jahn-Teller distortion. Comparison of CFSE for Oh and Td complexes. Fe and Cu. Quantum Chemistry & Spectroscopy Spectroscopy and its importance in chemistry. variable valency. Free particle. Ni and Cu (coordination numbers 4 and 6). Lanthanides and actinides: Electronic configurations. Electromagnetic radiation and its interaction with matter. quantum mechanical operators. Drawbacks of VBT. Wave-particle duality. IUPAC system of Nomenclature. colour. Tetrahedral symmetry. octahedral symmetry. Types of spectroscopy. colour. rotational. separation of lanthanides (ionexchange method only).PAPER-17 CHPT-505: CHEMISTRY-5 (CHEMISTRY OF d-BLOCK ELEMENTS. Unit 3. Factors affecting the magnitude of D. Oxidation states. Crystal Field Theory Crystal field effect. Particle in a 1-D box (complete solution). quantization. Link between spectroscopy and quantum chemistry. normalization Page 57 of 80 . Unit 2 Coordination Chemistry Valency Bond Theory (VBT): Inner and outer orbital complexes of Cr. Difference between atomic and molecular spectra. lanthanide contraction. Section B: Physical Chemistry-4 (30 Lectures) Unit 4. Photochemistry Laws of photochemistry. Barrow: Physical Chemistry Tata McGraw Hill (2007). Quantum efficiency and reasons for high and low quantum yields. A. Narosa (2004). R. 9. Photoelectric cells. Colour and constitution. Castellan: Physical Chemistry 4th Edn. D. R. Wilkinson: Basic Inorganic Chemistry.of wavefunctions. Petrucci: General Chemistry 5th Ed. 12. IR spectra of diatomic molecules. auxochromes. G. Group frequencies. bathochromic and hypsochromic shifts. Mahan: University Chemistry 3rd Ed. 6th Edn.I. Khosla. Townsend: General Chemistry. J.and intramolecular) and substitution on vibrational frequencies. Kotz. W.. Lambert-Beer s law. Quantization of rotational energy levels. E. 5. Quantitative Chemical Analysis. Structural information derived from vibrational spectra. Prentice Hall. New Delhi (2009). F. 8. B. 6. Cengage Lening India Pvt. P. Viva Books Pvt. Electronic Spectroscopy: Electronic excited states. Lee: A New Concise Inorganic Chemistry. F. Narosa (1998). H. Vogel. Page 58 of 80 . Quantization of vibrational energy levels. Treichel & J. 3. A. SUGGESTED READINGS 1. Cotton & G. Selection rules. Senior Practical Physical Chemistry. Rotational Motion: Schrödinger equation of a rigid rotator and brief discussion of its results (solution not required). Unit 5.B. Primary and secondary processes in photochemical reactions. Qualitative Inorganic Analysis. 10.I.S. Structural information derived from rotational spectroscopy. chromophores. Vogel. Microwave (pure rotational) spectra of diatomic molecules. R.A. Vibrational Motion: Schrödinger equation of a linear harmonic oscillator and brief discussion of its results (solution not required). Shriver and P. 4. Ltd. Gary Wulfsberg: Inorganic Chemistry. Chand & Co. John Wiley. Vibrations of polyatomic molecules. M. Ltd. concept of zero-point energy. 11. Oxford University Press. M. B. 7. Selection rules.L. Photochemical and thermal reactions. C. D. J. W.D. H. Free Electron model and its application to electronic spectra of polyenes. Macmillan Publishing Co. Prentice Hall. 2. Fluorescence and phosphorescence. Atkins: Inorganic Chemistry. 7th Edn.: New York (1985). Effect of hydrogen bonding (inter. (b) Study of the variation of molar conductivity of a strong electrolyte (KCl) and of a weak electrolyte (acetic acid) with concentration.salicylic acid complex / Fe2+ phenanthroline complex in solution by Job s method. Determination of the composition of the Fe3+ . volumetrically or conductometrically. 2. Estimation of (i) Mg2+ or (ii) Zn2+ by complexometric titrations using EDTA. Estimation of the amount of nickel present in a given solution as Bis(dimethylglyoximato) nickel(II) or aluminium as oxinate in a given solution gravimetrically. 3. (a) Determination of the cell constant. b) Iodide-persulphate reaction. Section B: Physical Chemistry (I) Potentiometric measurements (a) Strong acid with strong base (b) Weak acid with strong base (c) Mohr s salt with potassium dichromate (II) Conductometric measurements.CHPP-505: PRACTICAL CHEMISTRY Section A: Inorganic Chemistry 1.strong base (III) Kinetic studies Study of the kinetics of the following reactions by integrated rate method: a) Acid hydrolysis of methyl acetate with hydrochloric acid. 4. 6. Page 59 of 80 . To draw calibration curve (absorbance at max vs. Estimation of total hardness of a given sample of water by complexometric titration. Determination of concentration of Na+ and K+ using Flame Photometry. (c) Conductometric titrations for the following systems : (i) strong acid .strong base (ii) weak acid . concentration) for various concentrations of a given coloured compound and estimate the concentration of the same in a given solution. 5. Magnetostatics (Number of Lectures = 20) Concept of magnetic field B and magnetic flux.PAPER-18 PHPT-404: PHYSICS-3: ELECTRICITY.Concept of electric field lines and electric flux. critical damping resistance. Plane and spherical charge distributions. B due to a straight current carrying conductor. Magnetic field intensity. self and mutual induction. Biot-Savart s law. Integral form of Ampere s law. Energy stored in magnetic field.. relation between electric potential and electric field. Electromagnetic Induction and electromagnetic Waves (Number of Lectures = 25) Faraday s laws of induction (differential and integral form). Properties of B cur and divergence of B. Gauss s law (Integral and differential forms).Torque on a current loop in a uniform magnetic field. Conservative nature of electric field E. MAGNETISM AND ELECTROMAGNETIC THEORY Electrostatics (Number of Lectures = 15) Electric field: . Magnetic force between two current carrying conductors. applications of Ampere s law: field due to straight. Magnetic Energy in terms to current and inductance. current and charge sensitivity. Ballistic Galvanometer: . Force on a point charge in a magnetic field. Electric Potential: Concept of electric potential. electromagnetic damping. circular and solenoidal currents. solenoidal field.G. irrotational field. working principle of B. energy density in an electric field Calculation of potential from electric field for a spherical charge distribution. Page 60 of 80 . potential energy of a system of charges. Lenz s law. application to linear. Page 61 of 80 . Fewkes & John Yarwood: Electricity and magnetism. Kip: Fundamentals of electricity and magnetism. reflection and transmission. McGraw-Hill (1968) 2. Maxwell s equations in vacuum and dielectric medium. Purcell: Electricity and magnetism. Press (1991). Himalaya Publishing House (1988). 5. Joseph A. Vol. circular and elliptical polarization. Benjamin Cummings (1998). Brewster s angle. Arthur F. Edward M. David J. plane wave equation transverse nature of EM waves. D. displacement current. Griffiths: Introduction to Electrodynamics. boundary conditions. 1. Edminister: Electromagnetic.Continuity equation. ata Mc Graw Hill (2006). modification of Ampere s law. Polarization of EM waves.. Suggested Books 1. 2nd Edn.C. polarization.. velocity of light in vacuum and in medium. J. description of linear. Tayal: Electricity and Magnetism. Oxford Univ. McGraw-Hill Education (1986). 6.H. 3. 3rd Edn. 4. New Delhi. To determine self inductance of a coil by Rayleigh s method. Indu Prakash and Ramakrishna: A Text Book of Practical Physics. To determine the ratio of two capacitances by De Sauty s bridge. 7. (b) charge sensitivity and (c) CDR of a B. Norton. 8. New Delhi. Superposition. Flint: Advanced Practical Physics. 6. 5. Asia Publishing House. 2. To determine high resistance by leakage method.T. To verify the Thevenin. B.L. 2. To determine coefficient of Mutual inductance by absolute method. To determine self inductance of a coil by Anderson s bridge using AC. Suggested books: 1. To determine the (a) current sensitivity. Kitab Mahal. To determine a low resistance by Carey foster s bridge.G. Worshop and H. 3. Page 62 of 80 . 3. 4. and maximum power transfer theorem. Nelson and Jon Ogborn: Practical Physics.PHPP-404: PRACTICAL PHYSICS 1. silicon containing polymers. anti wrinkle and flame retardant. Rubbers (synthetic and natural) and their processing. Polymer designing: packaging. certification and process evaluation. blending. ICPP-505: PRACTICAL INDUSTRIAL CHEMISTRY 1. bismark brown. Industrial manufacture of the monomers and the following polymers. Speciality Polymers (Electro-luminescent.6:6. Industrial preparation and uses of methyl orange. Page 63 of 80 . Natural and Synthetic fibers. Polyurethanes. Conducting polymers). Preparation of Maleic Anhydride/ glyptal resin. 2. 3. Preparation of Caprolactum. indigo. alizarin. phosphorus containing polymers. Nylon (6. Classification.6:10). Polyacrylonitrile. Elastomers. Biopolymers. Dyes: General introduction and classification with special reference to textile and edible dyes and fabric brighteners. Polystyrene. Polybutadiene. Polyesters. properties and uses of boron containing polymers. Structure property relationship (Thermoplastic and Thermosetting). Polycarbonates. Preparation of Malachite Green. preparation. elastomers and resins) and sulphur containing polymers(SN)x. compounding. 2. Silicones (fluid. 2. Polyvinylidene. Polyethene. Polyamides. Polysulphones. relation between molecular structure and properties. Alkyds. Cellulosics. malachite green. Preparation of Methyl Orange.PAPER-19 ICPT-505: INDUSTRIAL CHEMISTRY-5: DYES AND POLYMERS 1. Inorganic Polymers: Classification. Polymer Processing: Moulding. Organic Polymers: Preparation. fiber processing. Properties. Polymethacrylate. Polymers 1. Polymethylmethacrylate. 4. Comparison of natural and synthetic polymers. Phenolic polyesters. Robert West. 4. Molecular weight determination of a polymer (nylon 6. Mark. 2. Suggested Readings 1.J. 8. James E. NY. John Wiley & Sons Inc.6) by end group analysis. Chapmann & Hall. 6. Preparation of Hexamethylenediamine and Adipic acid. Page 64 of 80 . Odian: Principles of Polymerization. London. 3.J. Hary Allcock. Inorganic Polymers. Flory: Principles of Polymer Chemistry. Prentice Hall Englewood. Preparation of nylon 6. Estimation of amino group. Preparation of phenol formaldehyde and urea formaldehyde. P. 10. Estimation of amino acid. 11. 7. Cornell University Press. Preparation of Polystyrene. Saunders: Organic Polymer Chemistry. G. K. 9.6.5. NY. Unit l Introduction to Green Chemistry What is Green Chemistry? Need for Green Chemistry. energy requirements for reactions . selection of appropriate auxiliary substances (solvents. green solvents. avoidance of Page 65 of 80 Unit II . Limitations/Obstacles in the pursuit of the goals of Green Chemistry. designing safer chemicals different basic approaches to do so. immobilized solvents and ionic liquids. Designing a Green Synthesis using these principles. selection of starting materials. it has become imperative to devise safer alternative materials and technology that would ensure the human sustenance. solventless processes.PAPER-20 Elective-1: Any one out of EL 310 (I) GREEN CHEMISTRY EL 310 (II) POLYMER SCIENCE EL 310 (III) BIOTECHNOLOGY EL 310 (IV) FORENSIC SCIENCE EL 310 (i) GREEN CHEMISTRY With the environmental concern and shrinking resources acquiring enormous proportions.use of microwaves. maximum incorporation of the materials used in the process into the final products (Atom Economy). prevention/minimization of hazardous/toxic products. Principles of Green Chemistry and Designing a Chemical synthesis Twelve principles of Green Chemistry with their explanations and examples. This course intends to take the students through the newer. Prevention of Waste/byproducts. ultrasonic energy. Goals of Green Chemistry. environment friendly products and procedures and incite them to take a more holistic view of different chemical processes. separation agents). Decarboxylation. methylbenzoate to benzole acid). oxidation. Diels Alder Reaction. designing of biodegradable products. Fries rearrangement. prevention of chemical accidents. Deprotection. Strecker synthesis. acetaldehyde. Microwave assisted reactions in organic solvents: Esterification. methyl methacrylate. Free Radical Bromination. benzamide. citral. catechol. Alkylations. use of catalytic reagents (wherever possible) in preference to stoichiometric reagents. reduction. substitution reactions. Orthoester Claisen Rearrangement. ibuprofen. urethane. BHT.unnecessary derivatization careful use of blocking/protecting groups.2-dihydrotriazine derivatives. Oxidation (of toluene. a nonmetallic oxidative reagent for various reactions. saponification. anhydrides from dicarboxylic acid. turtural. Reformatsky reaction. alcohols). aromatic amines (4aminodiphenylamine). 4 Selective methylation of active methylene group using dimethylcarbonate: Solid-state polymerization of amorphous polymers using diphenylcarbonate. Unit III Examples of Green Synthesis/Reactions 1 Green Synthesis of the following compounds: adipic acid. Cannizaro reaction. benzyl bromide. Biocatalysis in Organic Syntheses. reductions. Use of Clayan . 1. synthesis of nitriles from aldehydes. Page 66 of 80 . paracetamol. Role of Tellurium in Organic Syntheses. Saponification of esters. strengthening/development of analytical techniques to prevent and minimize the generation of hazardous substances in chemical processes. 2 Microwave assisted reactions in water: Hofmann Elimination. pyrimidine and pyridine derivatives. benzimidazoles. Alkylation of reactive methylene compounds. 3 Ultrasound assisted reactions: Esterification. Microwave assisted solid state reactions: Deacetylation. disodium iminodiacetate (alternative to strecker synthesis). n-phenyl benzamide. coupling reaction. Hydrolysis (of benzyl chloride. Marcel Deckkar (2001). oncovalent derivatization. Anamalaya Publishers (2005). Matlack: Introduction to Green Chemistry. Relationships between functionality. Ryan & M.K. research & development organizations and teaching institutions. Proliferation of solventless reactions. Texture of Polymers.S. 3. Functionality and its importance. M. EL 310 (ii) POLYMER SCIENCE The Primary Objective of Polymer Science course is to prepare skillful Polymer Scientists to meet the growing requirements in polymer based industry. V. 5. Criteria for synthetic polymer formation. Combinatorial green chemistry. Poly-functional systems.C. Anastes & J. University Press (1998). extent of reaction and degree of polymerization. 2. ionic chain (both cationic and anionic) and Unit II Unit III Page 67 of 80 .A. classification of polymerization processes. Washington (2002). Tinnesand. Introduction to Green Chemistry. Washington (2000). American Chemical Society. Biomimetic.Unit IV Future Trends in Green Chemistry Oxidation reagents and catalysts. Bi-functional systems. multifunctional reagents. Cann & M.T. Ahluwalia & M. 4. A. Kidwai: New Trends in Green Chemistry. P. Suggested Readings: 1. Warmer: Oxford Green Chemistry.R. Green chemistry in sustainable development. radical chain growth. Kinetics of Polymerization: Mechanism and Kinetics of step growth. Molecular forces and chemical Bonding in Polymers. Connely: Real-World cases in Green Chemistry. American Chemical Society. Government.E. Unit I Introduction and history of polymeric materials.Theory and Practical.K. Polymer nomenclature. Different Schemes of Classification of Polymers. M. Unit V Unit VI Unit VII Unit VIII Unit IX Suggested Readings 1. Fluoro Polymers. Polydienes. Poly (vinyl acetate) and related polymers. John Wiley. Conducting Polymers. Factors affecting crystalline melting point. Molecular weight distribution and its significance. etc). Unit IV and kinetics of Crystallization and Crystallinity. by end group analysis. John Wiley. Polycarbonates. F. Novalac). Billmeryer: Text Book of Polymer Science. structure. polymerization techniques. Morphology of crystalline polymers. Nature and structure of polymers-Structure Property relationships. Inc. Polydispersity index. thermal. WLF equation. Polystyrene and styrene copolymers. Free volume theory. and free energy change of mixing of polymers solutions. Page 68 of 80 . Determination of Crystalline melting point and degree of Crystallinity. Polyaniline. [Polyacetylene. Poly (p-phenylene sulphide Polypyrole. Polyurethanes. Poly (vinyl chloride) and related polymers. 2. light scattering and osmotic pressure methods.W. Properties of Polymer (Physical. Seymour Polymer Chemistry. Solubility parameter. Flow & Mechanical Properties). Glass transition temperature (Tg) and determination of Tg. Factors affecting glass transition temperature (Tg). G. Mechanism copolymerization. 3. Odian: Principles of Polymerization. properties and application of the following polymers. Marcel Dekker. enthalpy. Silicone Polymers. Polyamides and related polymers. Lower and Upper critical solution temperatures. entropy. Polymer Solution Criteria for polymer solubility. Thermodynamics of polymer solutions. FloryHuggins theory. Polyolefins. Phenol formaldehyde Resins (Bakelite. Mw. viscometry. Polythiophene)]. Brief introduction to preparation. Determination of molecular weight of polymers (Mn.coordination polymerizations. Acrylic polymers. W. feed. solvents. Unit I Unit I Biotechnology Scope and Applications. air lift. centrifugation. chromatography. vitamins. alcohol. Fermentation Different types of fermentation submerged and solid state. bio-fertilizers. fed batch and continuous. genetic engineering and transgenic plants with useful agronomic traits and products. Bioremediation. Unit III Unit IV Unit V Page 69 of 80 . food additives. methane. Overview of Tools and Techniques. Waste decomposition and conversions. a basic understanding of the principles. Lenz: Organic Chemistry of Synthetic High Polymers. selection. acid. organic acids. R. protoplast fusion. Tata Mcgraw-Hill. mixed acid and solvent. DNA technology. Industrial Microbiology Microbial resources for food. This would help the students to develop interactions/linkages with the industry and venture into Science entrepreneurship. Types of fermenters-stirred tank. product-based enzymes. 5. plant transformation-vectors and methods. single cell proteins. EL 310 (iii) BIOTECHNOLOGY The purpose of this course is to provide to the students of Science. Down stream processing filtration. Plant Biotechnology Plant tissue culture and somatic cell genetics and their applications in agriculture. Recombinant proteins Strain improvement Screening. tools and techniques. flavours. spray drying and lyophilization. extraction. agrochemicals. mutation. fixed bed and fluidized. pharmaceuticals. batch. bio-fuels.Ghosh: Polymer Science & Technology.4. recombination. and applications of the fast expanding fields of biotechnology. P. enzymes. Examinations of fingerprint. 4. Kalyani publishers. Blackwell Science (2001). Rastogi publishers (2003). Basic Principles. P.A. Pasternak: Molecular Biotechnology. EL 310 (iv) FORENSIC SCIENCE Forensic Science pertains to analysis and examination of Physical evidence recovered from a crime scene to legal proceedings. Bernard R. M. Page 70 of 80 . environmental co-concerns. Unit VII Suggested Readings: 1. Gupta: Biotechnology and Genomics. T. Singh: Biotechnology. Washington (1998). Electrophoresis (Immuno and Iso-electrofocusing) theory.. B.Unit VI Animal Biotechnology Cell culture and production of bio-products. History. hybridoma technology and immunodiagnostics. New Delhi (2003). Brown: Gene cloning and DNA analysis: An Introduction. 1998 (Reprint 2001). as well as examination of skeletal material.K. toxic substances detection of blood and other biological fluids. ASM Press. 5. vaccines. gene therapy.R. X-ray (Hard and Soft) techniques and their forensic applications. Oxford & IBH.V..K. Development and Scope of Forensic Science. principle and techniques. Unit I Unit II Unit III Definition. hair fiber etc is performed to provide scientific opinion for legal. Divisions of Forensic Science and Laboratory Set up. Razdan: Introduction to plant tissue culture. Atomic Absorption Emission and Mass) and its forensic applications. theory and application of spectroscopy (U. 3.D. gene manipulation and transgenic technology. Bio safety Physical and Biological containment. I. Click & Jack J. 2. Identification and detection of biological fluids (Blood. DNA Profiling. Forensic photography techniques and important of photography. identification of pattern types. differentiation between human and non human. developing latent fingerprints (Powder Method). sex and height from skeletal remains. Saliva and Urine) and their Medico-logical importance. Semen. Personal Identification through somatometry and Somatoscopy. Examination of skeletal remains-identification of bones. determination of age. identification and their importance in forensic science. comparison of fingerprints for establishing complete identity. Tool marks: their identification and importance in forensic science. pattern types. characteristic. spot test for blood identification. Classification of poisons. methods of processing latent/fingerprints. natural variation. Study and hair and fibers. biological basis of fingerprints.Unit IV Forensic Chemistry: Introduction. voice identification. Conventional methods of chemical analysis. comparison and forgery. handwriting. Brain fingerprinting. Forensic Odontology and Bitemarks). Somatoscopic Page 71 of 80 Unit V Unit VI Unit VII Unit VIII Unit IX Unit X Unit XI Note. Forensic Toxicology: Introduction and General methods of chemical analysis for alcohol. Practical demonstrations are compulsory as without the demonstration the students would not be able to understand the value of the specific topics of Forensic Science. Drugs of Abuse: Introduction and classification. . Fingerprint Identification: History and development. Cyber crime. scene of crime prints. ridge characteristics. Modern Developments and their concepts (Nacre analysis. presumptive tests (colour & spot). Questioned documents: Definition. Trace evidence: Definition. Practical demonstration of procedure of taking fingerprints. 4. Gian Publishing House. estimation of height from long bones. Nath: Personal Identification through Fingerprints.R.observations.K. Bhasin: A Laboratory Manual of Biological Anthropology. Page 72 of 80 . Saferstein: Criminalistics. Shree Publisher & Distributors. K. S. W. R. Singh and M. Eckert: Introduction of Forensic Science. Enterprises. Suggested Readings 1. Nath: An Introduction to Forensic Anthropology.G. I. 6. 2. New Delhi (2006).R. N. Age and Sex determination from skull. N. CRE Press. hair morphology. S. Allahabad (2003). Delhi (1989). 3. Bock Raton (1997). Central Law Agency. Prentice Hall (1998). tests for fiber identification. B. 5. Sharma: Forensic Science in Criminal Investigation and Trials. Delhi (2005).P. SEMESTER VI Page 73 of 80 . Peroxo compounds of Cr. Zeiss salt and ferrocene. Co. Ni and Co. Unit 2 Organometallic Compounds Definition and Classification with appropriate examples based on nature of metalcarbon bond (ionic. KMnO4. K+ and Mg2+ ions: Na/K pump. sodium nitroprusside. Anthracene . bonding and properties of mononuclear and polynuclear carbonyls of 3d metals. [Co(NH3)6]Cl3 . stabilization of protein structures and structural role (bones). Pyrrole. Peptides and Proteins: Preparation of Amino Acids: Strecker synthesis using Gabriel s phthalimide synthesis. Isoelectric point and Electrophoresis.acceptorbehaviour of carbon monoxide. Role of Ca2+ in blood clotting. Role of Mg2+ ions in energy production and chlorophyll. p and multicentre bonds). p . BIO-INORGANIC CHEMISTRY. Furan. K2Cr2O7. Synergic effects (VB approach). Unit 2. Zwitter ion. Role of metal ions present in biological systems with special reference to Na+. Unit 3 Bio-Inorganic Chemistry A brief introduction to bio-inorganic chemistry. s. Amino Acids. Thiophene. Section B: Organic Chemistry-4 (30 Lectures) Unit 1 Polynuclear and Heteronuclear aromatic compounds: Properties of the following compounds with reference to electrophilic and nucleophilic substitution: Naphthalene.(MO diagram of CO can be referred to for synergic effect to IR frequencies). PROTEINS AND UV-IR SPECTROSCOPY) Section A: Inorganic Chemistry-4 (30 Lectures) Unit 1Chemistry of 3d metals Oxidation states displayed by Cr. Fe. Structures of methyl lithium. A study of the following compounds (including preparation and important properties). structure. and Pyridine.PAPER-21 CHPT-606: CHEMISTRY-6 (ORGANOMETALLICS. Preparation. K4[Fe(CN)6]. EAN rule as applied to carbonyls. Na3[Co(NO2)6]. Page 74 of 80 . 11. bathochromic and hypsochromic shifts.L.N. Pearson Publication. R. ketones.S. 10. L.C. Dyer: Applications of Absorption Spectroscopy of Organic Compounds. Synthesis of simple peptides (upto dipeptides) by Nprotection (t-butyloxycarbonyl and phthaloyl) & C-activating groups and Merrifield solid-phase synthesis. 5th Edn. ultraviolet and Infrared spectroscopy in organic molecules. E. Tarr: Inorganic Chemistry. 12. auxochrome.A. Prentice Hall.Reactions of Amino acids: ester of COOH group.L. Ellen Keiter & Richard Keiter: Inorganic Chemistry: Principles of Structure and Reactivity. Unit 3. A.b unsaturated compounds. G. Lee: A New Concise Inorganic Chemistry. Orient Longman. Infrared radiations and types of molecular vibrations. 8. Boyd: Organic Chemistry.T. 7. Vogel: Quantitative Chemical Analysis.I. Application of Spectroscopy to Simple Organic Molecules Application of visible. Prentice Hall. A. S. Vogel: Textbook of Practical Organic Chemistry. I. G. Secondary. Page 75 of 80 . lmax & e max. Prentice Hall. Application of electronic spectroscopy and Woodward rules for calculating l max of conjugated dienes and a.L. A. John R. Cotton & G. Bassler & T. S.I. James E.B. Chand. Prentice Hall. Pearson Publication. 7th Edn. Bahl: Advanced Organic Chemistry. 6th Edn. Morrison & R.D. ninhydrin test. Finar: Organic Chemistry (Vol. I & II). John Wiley & Sons. E. carboxylic acids and their derivatives (effect of substitution on >C=O stretching absorptions).M. functional group and Finger print region.B. Wilkinson: Basic Inorganic Chemistry. complexation with Cu2+ ions. 2. 13. 9. 6.C. Overview of Primary. SUGGESTED READINGS 1. John Wiley & Sons. Huheey. aldehydes. Determination of Primary structure of Peptides by degradation Edmann degradation (N-terminal) and C terminal (thiohydantoin and with carboxypeptidase enzyme). J. R. F. 5. Miessler & Donald A. acetylation of NH2 group. Prentice Hall. electronic transitions . Electromagnetic radiations.I. Morrill: Spectroscopic Identification of Organic Compounds. Vogel: Qualitative Inorganic Analysis. alkenes and simple alcohols (inter and intra molecular Hydrogen bonding). IR spectra of alkanes. Tertiary and Quaternary Structure of proteins. chromophore.S. 4. Peter Sykes: A Guide Book to Mechanism in Organic Chemistry. Arun Bahl and B. 3. Silverstein. Mann & B. Mn2+ and Zn2+ 2. ketonic. Section B: Organic Chemistry Systematic Qualitative Organic Analysis of Organic Compounds possessing monofunctional groups (-COOH. Preparation of any two of the following complexes and measurement of their conductivity: (i) tetraamminecarbonatocobalt (III) nitrate (ii) tetraamminecopper (II) sulphate (iii) potassium trioxalatoferrate (III) trihydrate Compare the conductance of the complexes with that of M/1000 solution of NaCl. phenolic. aldehydic. Page 76 of 80 . MgCl2 and LiCl3.14. 1o amines) and preparation of one derivative. Saunders: Practical Organic Chemistry. Orient Longman (1960). C. Co2+. G. A13+ and Cr3+ or Paper chromatographic separation of Ni2+. nitro. CHPP-606: PRACTICAL CHEMISTRY Section A: Inorganic Chemistry 1. F. (Combination of two ions to be given) Paper chromatographic separation of Fe3+. Separation of mixtures by chromatography: Measure the Rf value in each case. amide. Charpit s method. John Wiley and Sons (1984). Partial differential Equations Order and degree of partial differential equations. Applications to traffic flow. Solving a differential equation by reducing its order. linear partial differential equation of first order. gravitational potential. Lagrange s method. resonance phenomena. Basic theory of linear differential equations.. Classification of second order partial differential equations into elliptic. Ross: Differential equations. The Cauchy. parabolic and hyperbolic through illustrations only. Concept of linear and non-linear partial differential equations. forced motion. The method of variation of parameters. Linear non-homogenous equations. Formation of first order partial differential equations. mechanics of simultaneous differential equations. Page 77 of 80 . Simultaneous differential equations. 3rd Edn. conservation laws. Sneddon: Elements of Partial differential equations. Methods for solving higher-order differential equations. electric circuit problem. Matlab/ Mathmatica/ Maple/ MuPadeharaeteristics.vibrating string vibrating membrane. free damped motion. International Edition (1967). Integrating factors. mixture problem. 2. McGraw-Hill.Euler equation.PAPER-22 MAPT 404: DIFFERENTIAL EQUATIONS First order exact differential equations. Linear homogenous equations with constant coefficients. Recommended Books 1. Shepley L. Using Computer aided software for example. total differential equations. conduction of heat in solids. rules to find an integrating factor. First order higher degree equations solvable for x y p dy dx. Wronskian and its properties. Applications of differential equations: the vibrations of a mass on a spring. Electro Analytical Techniques: Potentiometery. Gas Chromatography (GC).PAPER-23 ICPT-606: INDUSTRIAL CHEMISTRY-6: INSTRUMENTAL METHODS OF ANALYSIS 1. Spectroscopic Methods: Ultraviolet Spectrophotometery (UV). Nuclear Magnetic Resonance Spectroscopy (NMR) and Electron Spin Resonance Spectroscopy (ESR). Determination of composition of dolomite (by complexometric titration). Differential Thermal Analysis (DTA). Differential Scanning Calorimetery (DSC). Gas Liquid Chromatography (GLC). C. Thermal Mechanical Analysis (TMA). Infrared Spectrophotometery (IR). Viscosity. Flame Photometry. Molecular weight. Chromatographic separation: High Performance Liquid Chromatography (HPLC). ISO. Induced Couple Plasma Spectroscopy (ICP). Physical Characterization: Strength. E. Atomic Absorption Spectroscopy (AAS). B. Voltametry. ICPP-606: PRACTICAL INDUSTRIAL CHEMISTRY 1. Coulometry and Conductometry. extraction and separation). Atomic Fluorescence Spectroscopy. 2. Rheological properties. Crystallization. Visible Spectro photometery. Composition Analysis: Elemental analysis both qualitative and quantitative. Thermal Characterization of the following: (Demonstration exercise) (i) (ii) Dolomite (for percentage composition by TGA) Polystyrene (for glass transition temperature by DTA) Page 78 of 80 . BTS. Ion Exchange Chromatography. Polarography. F. ASTM. Distillation (simple. Amperometry. Thermal Methods of Analysis: Thermal Gravimetric Analysis (TGA). fractional and vacuum distillation). G. STANDARDS: ISI. Purification and Separation: Sample preparation (isolation using a suitable solvent. D. EURO. Quality Control and Instrumental Methods of Analysis A. Solvent extraction. An industrial project* Suggested Readings 1. H. D. Dean.M. S. A. F. 3. 2. Willard. California.H. L. G. J. in order to promote innovativeness. Settle: Instrumental Methods of Chemical Analysis.A. Demonstration or class exercises on the use of IR. NY.3. Wadsworth Publishing Company. 4.L.Wiley Eastern Ltd. UV and NMR spectra (Demonstration exercise). John Wiley. Khopkar: Basic Concepts of Analytical Chemistry. New Delhi. under the guidance and supervision of concerned faculty of college. *Industrial Project: Every student should undergo training Programme for the preparation and characterization (chemical as well as physical) of an industrial useful chemical/ any other investigatory project. Page 79 of 80 . Christian: Analytical Chemistry. Merrit. Mass. Page 80 of 80 .PAPER-24 Elective-2: Any one out of EL 310 (I) GREEN CHEMISTRY EL 310 (II) POLYMER SCIENCE EL 310 (III) BIOTECHNOLOGY EL 310 (IV) FORENSIC SCIENCE which has been not opted in Semester 5.